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An annihilation operator lowers the occupation number operator eigenvalue by one and annihilates the Fock vacuum.

A creation operator raises the occupation number operator eigenvalue of a quantum harmonic oscillator by one. Repeated application builds Fock states.

The state annihilated by every annihilation operator of the positive-frequency mode basis chosen in the asymptotic past. A Bogoliubov transformation can make it contain particles when tested by future out-mode number operators.

A number state is a normalized eigenstate of the number operator:For a single quantum harmonic oscillator, it is also an energy eigenstate with energy $\hslash \omega (n+1/2)$.

Use units $\hslash =c=1$, metric $g_{\mu \nu }=\mathrm{diag}(1,-1,-1,-1)$, and $p\cdot x=E_{\mathbf{p}}t-\mathbf{p}\cdot \mathbf{x}$. Treat the complex scalar field and its adjoint as independent variables when varying the action. Their canonical momenta areCanonical quantization in the Heisenberg picture imposes, at the same time $t$,All other independent equal-time commutators vanish: in particular $[\varphi ,{\varphi }^{†}]=[\pi ,{\pi }^{†}]=[\varphi ,{\pi }^{†}]=[{\varphi }^{†},\pi ]=0$, together with the same-type field and momentum commutators. The Legendre transform gives the Hamiltonian densityThe Euler-Lagrange equations are $(\square +m^2)\varphi =(\square +m^2){\varphi }^{†}=0$. The positive- and negative-frequency plane waves form a complete basis of solutions of the Klein-Gordon equation. Since the field is complex, their operator coefficients are independent rather than being adjoints of each other. Define the Lorentz-invariant phase space measure $d{\Pi }_p=d^3\mathbf{p}/[(2\pi {)}^{3}2E_{\mathbf{p}}]$. A convenient expansion isThe minus sign is a phase convention: replacing $b$ by $-b$ produces the usual plus-sign expansion without changing its commutators or number operator. The normalization is fixed by the canonical commutation relations. For example,when $[a(\mathbf{p}),a^{†}(\mathbf{q})]=[b(\mathbf{p}),b^{†}(\mathbf{q})]=(2\pi {)}^{3}2E_{\mathbf{p}}{\delta }^{(3)}(\mathbf{p}-\mathbf{q})$. The cross commutators vanish and the other canonical relation follows by taking adjoints with the operator order reversed. Conversely these mode commutators can be obtained by Fourier inversion of the equal-time relations. This is canonical quantization of a complex scalar field.

Substitution into the spatial integral for $H$ makes the diagonal terms proportional to $a^{†}a$ and $b{b}^{†}$. Terms creating or annihilating a pair have $\mathbf{q}=-\mathbf{p}$ and a coefficient $E_{\mathbf{p}}^2-{\mathbf{p}}^2-m^2=0$, so they cancel. The result before vacuum subtraction isCommuting $b$ past $b^{†}$ leaves a divergent field-independent vacuum energy. The displayed zero-vacuum-energy form must therefore be understood as a normal-ordered Hamiltonian:A regulator can be introduced before subtracting the constant. This is the normal-ordered Hamiltonian of a free complex scalar field; the unrenormalized Hamiltonian is not literally equal to this expression without that convention.

The scalar-field vacuum is annihilated by both annihilation operators. Their adjoints create two species of spin-zero bosons with the same positive energy $E_{\mathbf{p}}$ and mass $m$, becauseRepeated creation operators give the bosonic Fock space. The negative-frequency part does not create a negative-energy physical state; it creates the antiparticle of positive energy. The charge distinguishes the two species.

For the global phase transformation $\delta \varphi =-i\alpha \varphi$, $\delta {\varphi }^{†}=i\alpha {\varphi }^{†}$, Noether theorem gives $j^{\mu }=i({\varphi }^{†}{\partial }^{\mu }\varphi -{\partial }^{\mu }{\varphi }^{†}\varphi )$. Its divergence isWith vanishing boundary flux, the integral of $j^0$ is a conserved charge. Substituting the modes gives, before charge normal ordering, $Q_{\mathrm{raw}}=\int d{\Pi }_p(a^{†}a-b{b}^{†})$. The pair terms cancel because their frequency difference is zero when their spatial momenta sum to zero. Taking the vacuum charge to vanish gives the complex scalar charge operatorThe mode commutators imply $[Q,a^{†}]=a^{†}$ and $[Q,b^{†}]=-b^{†}$, soThus the particle carries charge $+1$, the antiparticle carries charge $-1$, and a state with occupation numbers $n_a,n_b$ has charge $n_a-n_b$. Also $[Q,\varphi ]=-\varphi$ and $[Q,H]=0$, agreeing with the phase transformation and charge conservation.

Fix a classical globally hyperbolic spacetime with metric signature $(-+++)$; in this solution take $\hslash =1$. A free real Klein-Gordon field can be specified bywhere $\mu$ is its mass, $\xi$ its curvature coupling and $\mathcal{R}$ the scalar curvature. Global hyperbolicity ensures a well-posed initial-value problem on a Cauchy hypersurface $\Sigma$ and the existence of retarded and advanced propagators. Thus compactly supported field and normal-derivative data determine a classical solution. This fixes the dynamics, but not a Fock vacuum.

For real solutions with suitable support or falloff, the symplectic form on scalar-field solutions iswith $n$ the future unit normal. The field equation makes the current conserved, so this symplectic form is independent of $\Sigma$ when boundary flux vanishes. Quantize the initial data by the canonical commutation relation: with $\pi =n^a{\nabla }_a\varphi$ and the delta function defined relative to $d\Sigma$, $[\hat{\varphi }(x),\hat{\pi }(y)]=i{\delta }_{\Sigma }(x,y)$ and the two equal-field commutators vanish. Equivalently, construct the field algebra using the causal propagator. A state on that algebra is additional input.

To construct a particle representation, complexify the classical solution space. Its conserved Klein-Gordon inner product isIt is indefinite on all complex solutions. Choose a complete positive-norm subspace and an orthonormal mode basis $u_i$ with $(u_i,u_j)={\delta }_{ij}$, $(u_i^{\ast },u_j^{\ast })=-{\delta }_{ij}$ and $(u_i,u_j^{\ast })=0$. Such a choice is encoded by a compatible complex structure on the Klein-Gordon solution space. Its positive subspace gives the one-particle Hilbert space, and the associated bosonic Fock space contains symmetrized many-particle states. The field expansion isThe creation operator $a_i^{†}$ adds a particle in mode $i$, the annihilation operator removes one, and the number operator is $N_i=a_i^{†}{a}_i$. For continuous mode labels the sums and Kronecker deltas become integrals and delta functions, or one can work with normalized wave packets.

The ambiguity is precisely that the field equation and global hyperbolicity do not select that positive subspace. A different normalized basis may mix $u_j$ and $u_j^{\ast }$ by a Bogoliubov transformation, and then its annihilation operators mix $a_j$ and $a_j^{†}$. Its Fock vacuum and number operators differ. The Hadamard condition constrains physically acceptable short-distance singularities and allows local renormalization, but it still leaves many states. Hence there is generally no observer-independent particle count on an arbitrary dynamical geometry.

In a stable strictly stationary spacetime, a globally future timelike Killing vector field $K$ gives a preferred time translation. Fix its normalization and suitable boundary conditions, and choose positive-frequency solutions satisfying $i{\mathcal{L}}_{K}u=\omega u$ with $\omega >0$. The corresponding positive spectral subspace gives the preferred vacuum state in a stationary spacetime. Unitary changes of basis within it leave the vacuum and the particle notion unchanged. This construction assumes a well-defined positive stationary generator; stationarity by itself is insufficient if $K$ becomes spacelike, as in a Kerr ergoregion, or if unstable or zero modes obstruct the ground-state construction. It selects a preferred ground state under the stated assumptions, not a unique state among all thermal and excited states.

If the geometry is suitably stationary in the asymptotic past and future, choose those preferred mode spaces separately, giving the in-vacuum and out-vacuum. Propagate the past modes through the intervening region using the field equation and compare them to the future modes using the conserved Klein-Gordon inner product. Adopt the conventionThe canonical identities for a bosonic Bogoliubov transformation read $\alpha {\alpha }^{†}-\beta {\beta }^{†}=I$ and $\alpha {\beta }^T=\beta {\alpha }^T$. Extracting the future annihilation operator with the same inner product givesIn the in-vacuum, only $⟨a_j{a}_k^{†}⟩={\delta }_{jk}$ contributes to $⟨b_i^{†}{b}_i⟩$. Therefore the particle number from Bogoliubov coefficients isNonzero $\beta$ is the production of future particles from the past vacuum. Summing over future modes gives the total expected particle number when that sum is finite. For infinitely many modes, a Hilbert-Schmidt operator $\beta$ is the condition for unitary implementability between these pure bosonic Fock space representations; finite-volume or wave-packet calculations must respect the relevant measures and convergence. Particle production is determined by the negative-frequency mixing, rather than by identifying a single instantaneous vacuum throughout the time-dependent region.

From the number operator commutator $[N,A]=-A$,so $A|n⟩$ is proportional to $|n-1⟩$. Its squared norm isWith the conventional phase choice,

In units with $\hslash =1$, the quantum harmonic oscillator Hamiltonian and number operator areThe nontrivial commutators among the creation and annihilation operators and $N$ areTheir reversed commutators have the opposite signs, while the commutator of any operator with itself is zero.

The operator $N$ is self-adjoint becauseIts eigenvalues are therefore real. Moreover, for every state $|\psi ⟩$,so every eigenvalue is nonnegative.

If $N|\nu ⟩=\nu |\nu ⟩$, the commutator with $A$ givesandRepeated application of $A$ lowers the eigenvalue by one. It must terminate before producing a negative eigenvalue. If $m$ is the last occupied rung, then $A|\nu -m⟩=0$, and the norm identity forces $\nu -m=0$. HenceThis is the integer spectrum of the number operator.

The conserved number operator isSubstitution of $\Psi =\sqrt{\rho }{e}^{-i\theta }$ into the Landau-Ginzburg theory givesThe imaginary term is a total derivative, soThus $\rho$ is the number density and is the canonical momentum conjugate to $\theta$. The canonical commutation relation is $[\theta (\mathbf{x}),\rho (\mathbf{y})]=i{\delta }^{(d)}(\mathbf{x}-\mathbf{y})$. Consequently, for ${\theta }_0=\int d^{d}x\theta$ in volume $V$,Equivalently, the averaged phase $\bar{\theta }={\theta }_0/V$ obeys $\Delta \bar{\theta }\Delta N\ge 1/2$. This number-phase conjugacy means that a state of sharp $N$ has no sharp phase, whereas a phase-selected state exhibiting spontaneous symmetry breaking must superpose different number sectors. Such sectors become effectively degenerate in the thermodynamic limit.

The number operator $N$ is self-adjoint. Alsoafter $\mathbf{q}\mapsto -\mathbf{q}$. Thus both exponents are anti-Hermitian and ${\mathcal{P}}_1,{\mathcal{P}}_2$ are unitary. Their product obeysand likewise for creation operators. Both generators annihilate the vacuum, so the product leaves it invariant. Substitution in the free-field mode expansion yieldsHence $\mathcal{P}={\mathcal{P}}_1{\mathcal{P}}_2$ implements parity with intrinsic parity ${\gamma }_p$.