The material derivative follows the interfacial surfactant. The term describes dilution by tangential expansion and concentration by compression. The term accounts for changing surface area due to normal motion of a curved interface. Finally, describes surface diffusion. Together these give conservation of insoluble surfactant on a moving interface.
The relevant surface Péclet number is
Write and . Since has zero trace and , the surface divergence is
There is no normal motion. To first order in , the steady surfactant balance becomes . The traceless quadratic is a degree-two spherical harmonic, so . The mean of is zero by total surfactant conservation; consequently
The discarded advective term is smaller by . This is the quadrupolar surfactant distribution on a spherical interface.
With the unit normal directed from the bubble into the exterior, the interfacial stress balance with variable surface tension is
Using the specified first-order curvature and , together with , gives
The first term is the spherical capillary pressure; the last contains the normal tension correction and the tangential Marangoni stress.
The ambient Stokes flow has the symmetry of the symmetric traceless tensor . In the Unscaled Papkovich–Neuber representation, is harmonic and yields . The decaying vector potential must have the form , and the scalar disturbance must have the degree-two form . They are harmonic outside the bubble and have precisely the required rotational covariance. Dimensionless amplitudes may therefore be written
For a steady bubble, the no-penetration boundary condition gives . Its tangential velocity gives . The tangential stress boundary condition then yields
Hence , and . The inviscid interior supplies only the constant pressure balancing . Matching the remaining normal stress gives
Eliminating gives
As , : the Marangoni stress suppresses tangential motion and effectively immobilizes the interface. This limit must retain the small surface Péclet number and small-deformation assumptions; can grow through increasing without invalidating the linear concentration approximation.
For the stated axisymmetric flow, the diagonal components of the rate-of-strain tensor are
Their sum is , the incompressibility condition. In the leading thin-sheet approximation, vanishing tangential traction makes independent of . The normal stress boundary condition is , so the Newtonian fluid stress tensor gives
Therefore
For the small annular sector, the inner and outer radial faces contribute in the radial direction. The two azimuthal faces contribute : their hoop tractions have inward radial components. The combined radial force of the external pressure on the sloping upper and lower surfaces is .
Figure 1.
Forces on an annular viscous-sheet sector and capillary traction at a hole edge
. The left panel shows the radial and hoop tractions on the four vertical faces. The right panel shows the two surface-tension forces pulling the rounded hole edge into the sheet. The separate radial pressure force on the sloping broad surfaces is proportional to . Details.
Neglecting inertia, force balance is thus
Substituting the two stresses cancels the terms involving and gives the axisymmetric viscous-sheet stretching equations:
Finally, conservation of mass in the sector gives
Put , so . Balancing the viscous and pressure terms in the axisymmetric viscous-sheet stretching equations, together with fixed volume, suggests a similarity solution
The conservation of mass equation becomes
There is no ongoing source at the origin, so the integration constant vanishes and wherever . Thus . Substitution into radial force balance gives
A differentiable cannot have nonzero derivative on an interval while being fixed there at . Hence : the spreading sheet has uniform thickness.
At the material edge, . Since , the edge condition fixes . Fixed volume then fixes the radius. The self-similar spreading of a viscous oil slick is
The point-release idealization is singular at ; a finite initial uniform slick gives the same solution with a time shift.
Each broad face supplies surface tension pulling the rounded hole edge into the remaining sheet. Their resultant is per unit circumference. At the inner boundary the fluid's outward normal is , so the boundary traction is outward in the radial direction when . The right panel of the preceding diagram shows these two capillary pulls.
With uniform thickness and , the axisymmetric viscous-sheet stretching equations reduce to
This Euler-Cauchy equation gives . The fixed outer rim imposes , hence . Because , conservation of mass gives , independent of . Thus a uniform sheet remains uniform.
The radial stress is . Its value at the hole edge determines
The edge is material, so and
Neglecting the initially tiny hole's volume, conservation of mass gives , or with . Therefore the capillary growth of a hole in a viscous sheet obeys
For a finite initial hole , replace in the denominator by . A nonzero seed is needed: the exact initial condition gives the stationary solution of this differential equation. For a small positive seed, initially grows exponentially at rate .
Reflection in preserves the prescribed translational velocity and axial angular velocity. A force transforms as a polar vector, whereas a torque transforms as an axial vector; consequently . Reflection in reverses both imposed motions but preserves the normal force component. The linearity of Stokes flow then gives . Thus only and can be nonzero.
There is a sign inconsistency in the printed question. In right-handed coordinates, gives a rotational velocity at the sphere's lowest point. The printed shear and force formulas instead use the opposite rotational sense. Below, let be the right-handed component along ; the paper's displayed formulas are recovered by setting .
In the translating frame, the parabolic gap and leading boundary velocities are
The no-slip boundary condition and lubrication theory give
The gap is stationary in this frame, so . The Reynolds lubrication equation is therefore
Since and ,
Differentiating the velocity profile gives the leading shear stresses
The first expression becomes the printed formula after .
For the logarithmic lubrication resistance of a sphere near a wall, write . The logarithmic region is , where . Consequently
These follow from and , with a fixed small outer cutoff. The general logarithmic radial numerator is over ; the numerator in the printed integration hint appears to have a typographical error.
The force exerted on the fluid through the upper gap boundary includes pressure acting on its slope:
The pressure cancels the term, giving
Pressure exerts no torque about the centre of a sphere because its traction is radial. To logarithmic order, the shear has lever arm , so
The other components vanish by parity: involves an integral of the term, and has an integrand odd in . The combined hydrodynamic resistance matrix is
Its equal off-diagonal coefficients are required by the Lorentz reciprocal theorem for Stokes flow. It is a positive-definite matrix, as required by viscous dissipation.
In the rotational convention of the printed force formula, set and measure the scalar couple along , so . Then
For sedimentation under the buoyancy-adjusted weight , a uniform sphere is torque-free. Thus , and the force balance gives
The rotational scalar in the paper's displayed-force convention is . The sphere rolls in the right-handed sense but still slips: its lowest point has laboratory velocity . The signs and coefficients of the right-handed resistance agree with the rigid-wall terms of Bertin et al., equations (4.4)–(4.5), after reversing the forces and torques there from fluid-on-sphere to sphere-on-fluid.

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