Past exam of the physics A course of the University of Cambridge / 2017 / Paper 1 / Section C / C11 / c

A Hermitian operator satisfies the adjoint symmetry conditionfor vectors in its specified domain. For a finite matrix this means $A=A^{†}$. For an unbounded differential operator, boundary conditions and domains matter: symmetry on a chosen domain is not alone sufficient for self-adjointness. Physical observables require the corresponding self-adjoint operator and its spectral measure. This distinction prevents purely formal integration by parts from being mistaken for a complete operator definition.

Real eigenvalues. If $A|a⟩=a|a⟩$ with nonzero norm, Hermiticity impliesso $a=a^{\ast }$. Thus eigenvalues representing measurement outcomes are real.

Orthogonality. For eigenvectors $|a⟩,|b⟩$,Hence $(a-b)⟨b|a⟩=0$, and distinct eigenvalues have orthogonal eigenvectors. Within a degenerate eigenspace, Gram-Schmidt orthogonalization can choose an orthonormal basis. In finite dimensions the spectral theorem gives a complete orthonormal eigenbasis andwhere $P_a$ projects onto each eigenspace. In infinite dimensions a continuous spectrum may require a spectral integral rather than a normalizable eigenvector for every possible outcome; a position operator on the full line is a familiar example.

Measurements and probabilities. In the discrete case the Born rule assigns probability $⟨\psi |P_a|\psi ⟩$ to the outcome $a$. For a nondegenerate eigenbasis, $|\psi ⟩={\sum }_a{c}_a|a⟩$ gives probabilities $|c_a{|}^2$, withThe variance vanishes precisely when the state lies in an eigenspace with a single sharp outcome. A repeatable ideal projective measurement prepares the corresponding eigenspace; superpositions of different eigenvalues do not have a preassigned sharp value of that observable in this description.

Compatibility and dynamics. Commuting Hermitian matrices admit simultaneous diagonalization, permitting a common set of sharp labels. For example $L^2,L_z$ commute, whereas $L_x,L_y$ do not. In the differential-operator setting the corresponding spectral compatibility requires appropriate domain conditions. Noncommuting observables obey the Robertson uncertainty principleThe canonical commutation relation then gives $\Delta x\Delta p\ge \hslash /2$.

The Hamiltonian operator represents energy. A self-adjoint $H$ generates unitary time evolution, $U(t)=e^{-iHt/\hslash }$, preserving norm and total probability; its eigenvalues determine stationary-state phases and transition energies. Hermiticity supplies real outcomes and orthogonal eigenspaces, while self-adjointness and the spectral theorem make these measurement and evolution rules mathematically complete.