A positive electric potential difference between gate and substrate attracts Electrons towards the insulating interface and repels the mobile electron holes of the p-type semiconductor substrate. The exposed, negatively charged acceptor impurities form a depletion region; the thin mobile Electron layer at its surface is the semiconductor inversion layer. The conduction band and valence band bend downwards towards the positively biased gate, because the Electron potential energy is .
Band bending and charge separation at the conventional MOS inversion threshold
. Details. To specify the conventional MOS inversion threshold, let be the ionized acceptor density, the intrinsic carrier concentration, andIn the neutral bulk the intrinsic level lies above the semiconductor chemical potential. A positive surface potential lowers both band edges by , giving, in the nondegenerate approximation,At , the surface is intrinsic: . The usual onset of strong inversion instead meansThus the surface electron density has grown to the bulk majority-carrier density. The chemical potential need not actually enter the conduction band. The phrase “just forms” can also refer to the earlier weak-inversion crossover; the diagram uses the conventional strong-inversion threshold and labels it explicitly.
Within the depletion approximation the negative space charge is approximately over a widthwhere is the absolute semiconductor permittivity. Its outer edge is where the bands become flat and mobile electron holes recover their bulk density. The electrical insulator blocks steady carrier transport while sustaining an electric field; the metal gate supplies positive surface charge balancing depletion and inversion charge. Under gate bias, the gate and substrate electrochemical potentials are different, so a single equilibrium Fermi level should not be drawn through the whole biased stack.
For a hydrogenic donor state, dielectric screening replaces by and the electron mass by the band effective mass. The characteristic orbital radius is thereforeUsing givesA donor-state overlap estimate compares this radius with the mean dopant spacing . Taking yieldsThere is no sharp geometrical onset: hydrogenic wavefunctions have exponential tails. If “overlap” is defined by neighbouring orbital diameters touching, , the corresponding estimate is , smaller by a factor of eight. These are conventions for the onset of appreciable orbital overlap, not an exact critical density for a metal-insulator transition.
The band effective mass is determined by the second derivative of the dispersion relation:With the stated sign convention and , the band minimum is at . Expanding the cosine, or differentiating twice, givesComparison with a free Electron's kinetic energy therefore requiresThe hopping integral has units of energy. A negative would move the minimum to the edge of the Brillouin zone and give the same positive bottom-of-band effective mass with in this expression.
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