On a graph of normalized remaining thickness against , both positive photoresist curves remain near unity below and fall to zero by . Their transition widths are : decades for the lower-contrast material and decades for the higher-contrast material. The latter therefore has a much steeper transition. The curves can be aligned at a common illustrative clearing dose; their absolute horizontal placement cannot be inferred from photoresist contrast alone.
The higher-contrast material distinguishes bright and dark regions even when diffraction has reduced their intensity modulation. The lower-contrast material requires a much stronger aerial-image modulation and loses small features earlier. Finite resist thickness, standing waves, acid diffusion, development conditions and photon statistics can limit actual performance beyond this threshold model.
For a positive photoresist, let be the largest exposure preserving the initial film thickness and the clearing dose. The photoresist contrast is . An aerial image can clear its maxima while retaining its minima only ifThus and for the lower- and higher-contrast materials. Reading those levels on the supplied modulation transfer function gives maximum normalized spatial frequencies approximately and , respectively. The stated partial coherence is already represented by that curve; do not multiply the read frequencies by another coherence factor.
The unambiguous pattern dimensions are full pitch and equal line/space width , where is the read normalized frequency. To convert the paper's Rayleigh-frequency label into lengths, explicitly use the circular-pupil Rayleigh criterion and . With the ArF vacuum wavelength and the stated numerical aperture, , givingThe higher-contrast material resolves a line/space feature about two-thirds as wide. The pitch and half-pitch distinction matters: the point-separation Rayleigh criterion is not itself an equal-line/space width. If a course defines as an optical cutoff rather than , use that specified frequency in ; the normalized graph readings and their ratio are unchanged. No absolute clearing dose is provided.
Reading the straight-line extrapolation in the printed photoresist contrast curve gives approximately at unit remaining thickness and at clearing. On the logarithmic dose axis,The critical image modulation follows by requiring one exposure time to give in a bright region and in a dark region:For unit object modulation, this meansThe doses are graphical estimates, so extra significant figures would not represent greater measurement accuracy.
Read the straight-line extrapolation on the logarithmic dose axis, rather than the rounded shoulder of the measured curve. The retention and clearing intercepts are approximately and . Thus the photoresist contrast isHere the subscripts denote the two dose thresholds used in the supplied definition. The physical positive-resist curve decreases with exposure; is the higher clearing dose in that definition, not a statement that the film retains its full thickness there. Graphical intercepts justify roughly two significant figures.
For a positive photoresist, let be the largest dose retaining the nominal film and the clearing dose. With the conventional photoresist contrast definition,For a sinusoidal aerial image, the bright-to-dark dose ratio is , where is the Michelson contrast. A dose window that clears bright regions while retaining dark regions requiresThis assumes a fully modulated input pattern and that the plotted modulation transfer function gives the aerial-image contrast. It is a dose-window criterion, not a statement that the resist creates optical information absent from the image.[ref]
The two thresholds are approximatelyReading their intersections with the supplied curve gives, to graphical accuracy,for the lower- and higher-contrast resists respectively. These are the results independent of the dimensional frequency convention. Their minimum full periods are , and equal line/space widths are half those periods:An ArF excimer laser uses . A numerical length requires specifying what the caption's “Rayleigh limit” means. Taking it literally as the reciprocal of the Rayleigh criterion point separation givesIf instead the graph uses the common incoherent-cutoff normalization , the widths are and , with periods twice those values. The caption does not explicitly provide an equation for or define whether “feature size” means period or half-pitch, so these conventions must not be silently mixed. The higher-contrast resist resolves the higher normalized frequency in either convention.
