Consider the one-dimensional diffusion equation on the whole real line,
with initial value one for and zero for . This is an idealized Heaviside step function profile, not a measured material or an apparatus specification. The heat kernel gives a convolution with the initial profile:
The change of variables turns the convolution into a Gaussian integral tail. The resulting similarity variable shows that the transition width grows like : multiplying elapsed time by four doubles every fixed-profile distance from the original interface.
Figure 1.
Diffusion smooths a step while preserving its similarity profile
. Exact model curves for a unit jump with stipulated in consistent length and time units. Left: the transition broadens at , , and . Right: plotting each against collapses all three onto the same curve. No experimental measurements are plotted. Details.
At every positive time, , while as and as . For every fixed , the limit as returns the specified initial value. The value assigned at the single initial discontinuity does not change this convolution. The error function therefore explains smoothing without pretending that a discontinuous initial profile remains sharp.
Direct differentiation checks the partial differential equation. Writing gives
The model assumes constant diffusion coefficient, no advection, and no finite-domain boundary effects. For an interpretation as heat conduction, the heat equation applies to a normalized temperature difference under its own material assumptions.
The local conservation laws. The first equation is the radial Euler equation: the material acceleration is caused by the pressure gradient force per unit mass, . It neglects gravity and viscosity. The second equation is mass conservation in spherical coordinates,
The term appears because the area of a spherical surface grows as .
To obtain the third equation, let be the specific internal energy of an ideal gas with constant heat capacity ratio . The first law of thermodynamics for a smooth adiabatically moving element is
Differentiating and collecting terms gives
and hence
Thus the entropy parameter is conserved along each smooth pathline; for fixed composition, specific entropy differs from only by a constant. This is local isentropic flow behind the shock. A physical shock wave itself generates entropy and must be treated with jump conditions, rather than by applying this smooth equation across the discontinuity.
The front-radius scaling. In the self-similar blast wave approximation there is no scale set by ambient pressure, cooling, gravity, or the initial source radius. Write . Using and , dimensional analysis gives
Thus , , and
The dimensionless coefficient depends on and the resolved similarity profiles; dimensions alone do not fix it. Define the length scale , so and the front is at the fixed coordinate .
Kinetic energy. Substitute and into the volume integral. Since and ,
But , so the first of the spherical blast-wave similarity energy integrals is
The conclusion requires a fixed, integrable similarity profile, as in the finite-energy blast solution. Expansion increases the swept-up mass while reducing the characteristic squared speed, leaving this product constant.
Pressure and internal energy. The derivatives of the similarity variable are
Writing a prime for differentiation with respect to , the material acceleration becomes
The radial momentum equation therefore requires a pressure gradient on the scale . Integrating over radius gives pressure similarity in a spherical blast wave:
where
The prefactor has units , as required for pressure. Strictly, the momentum equation alone permits an additional pressure uniform in space and arbitrary in time. In the scale-free strong-blast solution, shock matching and the remaining thermodynamic equation fix that freedom with the same similarity scaling; any allowed constant of integration is included in . An independently imposed external pressure would introduce another scale and invalidate the simple dimensional ansatz.
For constant , the internal energy is consequently
If is the total excess explosion energy, its normalization is
The two constant fractions need not be equal. No explicit solution for is needed to establish their time independence.
Let increase away from the tip along the wall and point normally into the fluid. Put , for velocity components and for the outer tangential velocity. The local Cartesian momentum and pressure equations are
For a two-dimensional flat layer the usual continuity equation is . For this axisymmetric cone, however, the circumference is proportional to , so its leading continuity equation is
The circumference term is of the same order as and cannot be omitted when deriving the cone's similarity equation. Conditions at the stationary wall are ; at the layer edge .
Balance . With this gives
The choice of multiplicative constant fixes the normalization of the similarity variable. To enforce axisymmetric continuity set , , with
Then
Differentiation gives , whereas and . Consequently the conical sink boundary layer satisfies
The first condition is no penetration, the second no slip, and the last matches the inward core flow. If one instead makes a strictly planar approximation and omits the circumference term, the streamfunction is and the equation becomes . The thickness exponent is the same, but that planar equation is not the axisymmetric cone equation.
Across a cap near , the inward flux in a layer truncated at is, to leading order,
To match to the core, use the finite displacement-flux deficit rather than integrate the uniform outer flow to infinite . If , then
Conservation of the fixed total extraction rate requires an extra core flux of this order. Dividing by cap area, proportional to , proves
The correction is a relative contribution. Its angular structure requires outer matching; the requested radial power follows from the displacement flux alone. Its cap-average direction increases the inward core speed to compensate for the wall deficit.
Set the similarity variable
Then
The factors of cancel, leaving the self-similar ordinary differential equation
Let be the group parameter. The infinitesimal generator of a Lie point symmetry
has flow equations
Therefore it generates the scaling group
Here , , and . The total-derivative formulas for the second prolongation of a Lie point symmetry give
and
Thus
For the wave equation expression ,
It therefore vanishes whenever , proving that generates the simultaneous spacetime scaling symmetry of the wave equation.
The independent invariant of the scaling orbits is the similarity variable
while itself is invariant. Seek a group-invariant solution . Direct partial differentiation gives
The wave equation reduces to
Hence, on any interval avoiding ,
The diffusion length suggests the similarity variable
The Neumann solution of the Stefan problem, written using the error function, is
These expressions satisfy all four thermal boundary conditions. At the interface,
Since and , the Stefan condition becomes
The second term represents heat supplied from the warm water and therefore reduces the freezing rate.
Write , and assume these scales are nonzero. The two reference liquidus relations imply . For the similarity variable and front ,
Thus a temperature profile has and . Each heat equation becomes . The solute diffusion equation becomes , with
This Lewis number compares thermal and solutal diffusivities. Inside the mushy layer, gives . The wall and far-field conditions become and as .
At the moving phase boundary, equality of temperatures gives . Equality of concentrations gives . Therefore the dimensionless parameters with the convention used here are
Neither concentration nor temperature offsets should be dropped when enforcing continuity. In particular can be negative. If , then : this is the inverse Stefan number, although the paper calls its Stefan number.
To check every factor of two in the flux conditions, divide the thermal Stefan condition by , and the solute balance by . This gives
Finally and imply . This is marginal equilibrium at a mush-liquid boundary. Together these calculations produce all the rescaled differential equations and all three interface balances.
The transformations
form a one-parameter Lie point symmetry of . The product is a similarity variable, and a group-invariant solution satisfies