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Conservation relations for resonant, lossless wave mixing. For sum-frequency generation with ${\omega }_3={\omega }_1+{\omega }_2$, the intensities obey $I_1^{\prime }/{\omega }_1=I_2^{\prime }/{\omega }_2=-I_3^{\prime }/{\omega }_3$. Thus $I_1/{\omega }_1+I_3/{\omega }_3$ and $I_2/{\omega }_2+I_3/{\omega }_3$ are constant. Their difference gives a third, dependent invariant. Adding the intensity derivatives yields conservation of energy.

The exchange interpretation divides each intensity by its photon energy $\hslash {\omega }_j$. One conversion removes a photon from each lower-frequency mode and adds one to the upper mode. For classical coupled-wave equations, differentiating the squared complex amplitudes gives the same common exchange rate multiplied by $({\omega }_1,{\omega }_2,-{\omega }_3)$. Loss or externally replenished pumps require corresponding source terms.

The distance over which a constant phase mismatch accumulates phase difference $\pi$. In unseeded, undepleted sum-frequency generation, the generated intensity first reaches a maximum at this length and returns to zero at $2{\ell }_c$. This length concerns relative phases of interacting waves, rather than the temporal optical coherence length of one source.

The process is sum-frequency generation, with ${\omega }_3={\omega }_1+{\omega }_2$. The same reversible three-wave mixing interaction permits the reverse conversion when the higher-frequency field supplies the pump. The second-order nonlinear polarization couples the three waves; its effective coefficient includes the crystal orientation and polarizations.

One efficiency limit is phase mismatch: contributions generated at different positions acquire different phases and can cancel. A second practical limit is spatial walk-off, which reduces the overlap of finite beams in a birefringent crystal. A beam radius $w$ and relative walk-off angle $\rho$ give an overlap length of order $w/|\tan \rho |$. Absorption and scattering provide further losses. Group-velocity mismatch matters for pulses, and pump depletion eventually invalidates an undepleted-pump calculation; none of these effects should be silently included in the ideal lossless plane-wave equations.

Define ${\kappa }_j=2d_{\mathrm{eff}}{\omega }_j/(n_{j}c)$ and hold $A_1,A_2$ constant. Direct integration of the driven equation giveswhere $\mathrm{sinc}x=\sin x/x$. The second expression has a continuous phase-matched limit. If the generated field is initially absent,For $\Delta k\ne 0$ this is proportional to ${\sin }^2(\Delta kz/2)$: the first maximum is at the nonlinear optical coherence length ${\ell }_c=\pi /|\Delta k|$, and the first subsequent zero is at $2{\ell }_c$. A seed $A_3(0)\ne 0$ adds interference with the generated amplitude and can change that pattern. At exact phase matching, the unseeded result grows as $z^2$ only while pump depletion remains negligible.

To retain depletion consistently, differentiate each intensity before inserting the coupled equations:For real $d_{\mathrm{eff}}$ in the lossless convention, put $Q=A_1{A}_2{A}_3^{\ast }{e}^{i\Delta kz}$. The result isThe signs follow the printed amplitude equations. In initial up-conversion, the newly generated $A_3$ makes $\mathrm{Im}Q<0$, so the two input intensities decrease while the sum-frequency intensity increases. Adding the derivatives gives zero because ${\omega }_1+{\omega }_2-{\omega }_3=0$. The total intensity is conserved, even though the three individual intensities change.

The Manley-Rowe relations areDividing an intensity by $\hslash {\omega }_j$ gives photon flux density. A conversion event removes one photon from each lower-frequency mode and adds one to the upper mode, or does the reverse. Therefore $C_1/\hslash$ and $C_2/\hslash$ count conserved sums of photon fluxes, while $C_3/\hslash$ counts the conserved lower-frequency difference. They are not three independent invariants: $C_3=C_2-C_1$. Energy conservation is also recovered as $I={\omega }_1{C}_2+{\omega }_2{C}_1$.

The unweighted combinations generally fail because the exchanged photons have different energies. Explicitly,The qualification “generally” matters: $D_3$ is conserved for equal lower frequencies in a distinct-mode degenerate case, and every derivative vanishes when there is no exchange. The equations establish nonconservation for generic unequal-frequency interaction, not for all special solutions.

The residual wave vector difference in a wave-conversion process. For collinear sum-frequency generation, choose $\Delta k=k_1+k_2-k_3$. Contributions separated by $z$ then differ by wave phase $\Delta kz$. At phase matching this residual is zero. The sign convention changes some amplitude phases but not the unseeded conversion factor ${\mathrm{sinc}}^2(\Delta kL/2)$.

An interaction among three waves mediated by a second-order nonlinear optical susceptibility. In sum-frequency generation, two input angular frequencies satisfy ${\omega }_3={\omega }_1+{\omega }_2$. The same coupling permits reverse conversion. Phase matching determines whether successive generated contributions reinforce; the Manley-Rowe relations express the associated lossless exchange constraints.