In 1911, Louis Dunoyer de Segonzac formed a sodium beam in vacuum and collected a deposit on a surface cooled with liquid air. Its shape agreed with straight paths through the slits.[ref] A deposit tests the geometry of the surviving paths. A clock or a calibrated deflection is needed to turn their travel into a speed measurement.
Immanuel Estermann, O. C. Simpson and Otto Stern used gravitational deflection to measure atomic speeds. Stern describes scanning a hot-wire surface ionization detector through a cesium beam and recording ion electric current.[ref] Their 1947 paper reports potassium and cesium beams; a deficit of slow arrivals increased with oven pressure, supporting a source-slit collision explanation.[ref]
First consider an original point-launch model, with horizontal speed , zero initial vertical velocity, flight distance , and uniform gravitational acceleration . Downward displacement follows from flight time :
Slow particles fall farther. However, a detector scan counts arrivals per interval of height, not per interval of speed. Change of variables for probability densities supplies the Jacobian determinant:
Here denotes the effusive beam speed distribution; the unadorned constant in denotes gravitational acceleration. The integral of is one: substituting reduces it to . Its mode is . Simply mapping the most probable arrival speed into a fall distance instead gives . The peaks differ because equal height bins cover unequal speed intervals.
Figure 1.
Effusion changes the arrival speed distribution, and a detector-height scan requires another Jacobian determinant
. Original calculated distributions with chosen , , and . These are not historical measurements. Details.
For those chosen parameters, , so the detector-height probability density peaks near . A detector covering only accepts the fraction
At this is about , even before allowing for imperfect detection. Discarding the remainder changes the observed normalization.
Real slits transmit a range of launch heights and vertical velocities. Their geometrical response must be combined with the gravitational deflection and detector width; the point-launch formula is not an exact reduction of the historical apparatus. In the point-launch model, an initial vertical velocity would add to . Source collisions, detector efficiency and alignment can also distort a profile. Varying oven pressure helps distinguish such source losses from an incorrect thermal distribution; inferring a source temperature from the peak alone ignores both selection and the detector's coordinate transformation.
Otto Stern's lecture describes two co-rotating toothed wheels: transit between them must match an advance between openings. He explicitly distinguishes this method from the first historical speed measurement.[ref]
For an idealized example, let aligned wheels have equally spaced openings, separation , and rotation rate in revolutions per second. A particle with constant longitudinal speed takes between them. The second wheel advances through revolutions; transmission peaks when that advance is an integer number of opening pitches:
With chosen , and , the first two orders select and . A second transmission maximum therefore need not represent a second source temperature. Finite opening widths admit speed intervals around each order, and an additional measurement is needed to distinguish orders. The ideal expression assumes negligible acceleration and constant rotation rate during a flight, with a fixed relative phase between the wheels.