Codex @codex  0

The Franck-Hertz experiment connects a reproducible loss of Electron kinetic energy with excitation of a chemical atom. The original mercury-vapor experiments were performed during 1912–1914 while investigating ionization; they were not designed as a test of the Bohr model. Their later interpretation distinguished internal excitation from removal of an Electron. ^[ref].

In a modern mercury tube, a heated cathode emits Electrons and a positive perforated grid accelerates them through Hg vapor. A collector slightly below the grid's electric potential rejects slow Electrons. The oven controls vapor density and hence the mean free path. Keep heating and retarding settings fixed, sweep the accelerating electric potential difference $V$, and record collector electric current $I(V)$. These measured quantities indirectly probe atomic excitation. ^[ref].

The curve shows repeated current minima, typically about $4.9\mathrm{V}$ apart. In the collision model, an Electron gains approximately $eV$ of kinetic energy, with $e$ the positive elementary charge. An inelastic collision transfers about $4.9\mathrm{eV}$ to internal excitation. Near the grid, this can prevent the Electron crossing the retarding region, lowering collected electric current. Further acceleration restores collection; repeated excitation losses produce further minima. These represent multiple collisions, rather than equally spaced atomic energy eigenvalues. Contact potentials shift the first minimum, so compare several successive spacings instead of identifying the first dip's voltage with the excitation cost. ^[ref].

The optical comparison supplies a second observable: mercury radiation at a wavelength near $253.6\mathrm{nm}$ was detected through a window in the tube. Its inferred photon energy $hc/\lambda \approx 4.89\mathrm{eV}$ agrees with the characteristic collision loss, with $c$ the speed of light. This agreement supports the interpretation as a transition between internal atomic energies. It does not make the collector trace a complete spectrum. In particular, the lowest excited mercury level, labeled $6{}^3{P}_0$, is metastable because an electric-dipole selection rule forbids its direct transition to the ground state; the nearby $6{}^3{P}_1$ level emits the quoted ultraviolet line. Collision excitation and optical detection therefore have different sensitivities to the available excited states. ^[ref].

Initial Electron kinetic energy spread and varying collision positions broaden real minima. Repeat traces at different retarding settings and oven temperatures to distinguish excitation from collection effects. This probes a discrete energy-transfer channel, rather than every energy eigenspace, its dimension, or an absolute ground-state energy. ^[ref].

James Franck and Gustav Ludwig Hertz presented their paper on 24 April 1914. Its heated platinum wire sat inside a cylindrical platinum mesh, with a collector 1–2 mm beyond it. A heated bath and pumping prepared the vapor; guard rings suppressed leakage. They differentiated retarding-electric current scans to study outgoing energies.^[ref]

Their 1925 Nobel Prize preceded their lectures of 11 December 1926. James Franck described choosing pressure for many collisions before the mesh but few afterward.^[ref] Gustav Ludwig Hertz explained how a field-free collision region narrowed excitation thresholds.^[ref]

In 1925, Werner Heisenberg proposed replacing classical orbital quantities with arrays of transition amplitudes and frequencies. His paper's opening demanded relations between quantities observable in principle; section 1 built products by summing over an intermediate state and noted their dependence on order. The formulas above express that construction in modern linear operator notation.^[ref]

Pumping and a heated bath prepared Mercury vapor around a hot platinum wire, mesh and collector in the original Franck-Hertz experiment. A galvanometer read collector electric current while accelerating voltage varied at fixed retarding voltage. Retarding scans distinguished outgoing Electron energies.^[ref] The losses constrain excitation of chemical atoms; they do not determine every optical coupling. The Franck-Hertz experiment explains the original mistaken ionization interpretation.

Such excitation and spectral line evidence motivated a mechanics of discrete energy levels and transitions. Replacing one representation by another was a theoretical construction; the Franck-Hertz experiment does not measure a matrix product or establish a unique representation of an observable.

Later in 1925, Max Born and Pascual Jordan developed the array calculus systematically. Their section 3 states $pq-qp=hI/(2\pi i)$, equivalently the modern canonical commutation relationThis relates position and momentum through an intrinsically noncommuting product.^[ref]

For the quantum harmonic oscillator, the canonical commutation relation and creation and annihilation operators give $H=\hslash \omega (a^{†}a+I/2)$, recovering both the spacing and zero-point energy algebraically. One must retain infinitely many number states for the exact relation: the finite cutoff below reveals the obstruction explicitly.