The Reststrahlen effect, or Reststrahlen band, refers to a phenomenon observed in the infrared spectrum of certain materials, particularly crystalline substances. It occurs when there are specific vibrational modes of the material's lattice that strongly absorb infrared radiation, leading to distinct spectral features. In essence, when infrared light interacts with a crystal, some wavelengths are absorbed due to the resonant frequency of the lattice vibrations (phonons), while others are reflected.
Selection rules are criteria or guidelines that dictate the allowed or forbidden transitions between quantum states in quantum mechanics and spectroscopy. These rules are used to determine which transitions can occur during processes such as electronic, vibrational, or rotational transitions in molecules, as well as transitions involving photons, such as in absorption or emission of light. In the context of quantum mechanics, selection rules are derived from the intrinsic symmetries of quantum systems and are often associated with changes in certain quantum numbers.
Singlet fission is a photophysical process in which a single excited state (singlet) of a molecule splits into two triplet states. This process can occur in certain organic molecules, particularly those that have favorable exciton interactions and molecular structures. Here’s a more detailed breakdown of the phenomenon: 1. **Initial Excitation**: When a molecule absorbs a photon, it can transition from its ground state (S0) to an excited singlet state (S1).
Spectral resolution refers to the ability of an instrument to distinguish between different wavelengths or frequencies of electromagnetic radiation. It is a critical parameter in various fields, including spectroscopy, astronomy, and remote sensing, as it determines how finely a spectrum can be resolved. Spectral resolution is commonly defined in terms of the wavelength (or frequency) at which a spectrum can be divided into distinct components.
Spectrochemistry is a branch of chemistry that studies the interaction between matter and electromagnetic radiation. It involves the use of various spectroscopic techniques to analyze the composition, structure, and properties of substances based on their absorption, emission, or scattering of light.
Spectral line ratios refer to the comparison of the strengths (or intensities) of different spectral lines that emerge from a source, often as a result of atomic or molecular transitions. These ratios provide valuable information about the physical conditions in the emitting region, such as temperature, density, chemical composition, and excitation mechanisms.
Spectroelectrochemistry is an interdisciplinary field that combines electrochemistry and spectroscopy to study the properties and behaviors of chemical species at electrochemical interfaces. It involves the simultaneous application of electrochemical techniques and spectroscopic methods to obtain detailed information about the electronic, molecular, and ionic states of species involved in redox processes.
UV-Vis absorption spectroelectrochemistry is a powerful analytical technique that combines ultraviolet-visible (UV-Vis) absorption spectroscopy with electrochemistry. This method allows researchers to study the electronic properties and behaviors of chemical species in solution as a function of their oxidation state, charge, or potential applied during electrochemical experiments. ### Key Components: 1. **UV-Vis Absorption Spectroscopy**: - UV-Vis spectroscopy measures the absorption of ultraviolet and visible light by a sample.
A transmissometer is an instrument used to measure the transmission of light through a medium, often employed in various fields such as meteorology, environmental monitoring, and telecommunications. It quantifies how much light is able to pass through a medium, which can be air, water, or other substances, and is particularly useful for assessing visibility conditions. In meteorology, for instance, transmissometers are commonly used to measure atmospheric visibility, which can be affected by factors like fog, rain, dust, and pollution.
Vapochromism is a phenomenon where certain materials change color in response to exposure to volatile organic compounds (VOCs) or various vapors. This change in color is typically due to the interaction of the vapors with the chemical structure of the material, which can involve changes in electron configuration or molecular interactions. Vapochromic materials can include certain dyes, polymers, and coordination complexes that exhibit this behavior.
Video spectroscopy is an advanced technique that combines video imaging with spectroscopic analysis to study the properties of materials and analyze dynamic processes in real time. It typically involves capturing video footage of a sample while simultaneously collecting spectral information about the light interacting with the sample. The key components of video spectroscopy include: 1. **Imaging**: High-speed cameras or video cameras capture the visual aspects of the sample, allowing for the observation of dynamic changes, movements, or reactions over time.
A Virtually Imaged Phased Array (VIPA) is an advanced optical imaging technique that enhances the capabilities of traditional phased array systems. VIPA technology is primarily used in applications like spectroscopy, imaging, and sensing, where high resolution and rapid data acquisition are essential. ### Key Features of VIPA: 1. **Optical Interference and Imaging**: VIPA utilizes the principle of optical interference to generate multiple virtual images of an object.
The Zeeman effect is a phenomenon in physics observed when the spectral lines of atoms are split into multiple components in the presence of a magnetic field. This splitting results from the interaction between the magnetic field and the magnetic dipole moment associated with the angular momentum of electrons within an atom. When an atom is placed in a magnetic field, the degeneracy of energy levels associated with electronic states is lifted due to the different orientations of the magnetic moments relative to the field direction.
Matlis duality is a concept in commutative algebra that pertains to the study of modules over a Noetherian local ring. It provides a way to relate a module to a dual module that can reflect certain properties of the original module. Specifically, Matlis duality provides an equivalence between the category of finitely generated modules over a Noetherian local ring and the category of certain finitely generated modules over its completion.
Propellant mass fraction (PMF) is a critical parameter in rocketry and space mission design that describes the ratio of the mass of propellant to the total mass of the rocket or spacecraft, including all components such as the payload, structure, and other systems. It is typically expressed as a percentage or a decimal fraction.
Classical Cepheid variables are a type of pulsating star characterized by periodic changes in brightness due to expansion and contraction of their outer layers. They are typically supergiant stars that belong to the spectral types F or G, and they have well-defined periods of variability that range from a few days to several weeks. The key features of Classical Cepheids include: 1. **Pulsation**: These stars undergo regular pulsations, caused by changes in temperature and pressure in their outer layers.
The Hayashi track is a concept in astrophysics, particularly in the study of stellar evolution and the evolution of young stars. It refers to a path on the Hertzsprung-Russell (H-R) diagram, which plots stars according to their luminosity and temperature (or color). The Hayashi track describes the evolutionary phase of pre-main-sequence stars, specifically those that are still in the process of contracting and heating up before they initiate hydrogen fusion in their cores.
The Halbert L. Dunn Award is an honor given by the American Public Health Association (APHA) to recognize individuals who have made significant contributions to the field of public health through their work in health measurement and the assessment of health status. Named after Halbert L. Dunn, a prominent figure in public health known for his emphasis on health promotion and the measurement of human health, the award is intended to appreciate efforts that advance understanding and practice in health improvements.
The Rousseeuw Prize for Statistics is an award established to recognize outstanding contributions to statistical science. Named after the Belgian statistician Peter Rousseeuw, who is known for his work in robust statistics, the prize honors individuals who have made significant advancements in the field. The award aims to promote the importance of statistical methodologies and their applications in various disciplines.
The West Black Sea Region is a geographical and statistical region in Turkey, located along the northwestern coast of the Black Sea. It is known for its lush green landscapes, mountainous terrain, and coastal areas. The region typically includes several provinces, notably: 1. **Bolu** 2. **Düzce** 3. **Zonguldak** 4. **Bartın** 5. **Karabük** 6.

Pinned article: Introduction to the OurBigBook Project

Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
We have two killer features:
  1. topics: topics group articles by different users with the same title, e.g. here is the topic for the "Fundamental Theorem of Calculus" ourbigbook.com/go/topic/fundamental-theorem-of-calculus
    Articles of different users are sorted by upvote within each article page. This feature is a bit like:
    • a Wikipedia where each user can have their own version of each article
    • a Q&A website like Stack Overflow, where multiple people can give their views on a given topic, and the best ones are sorted by upvote. Except you don't need to wait for someone to ask first, and any topic goes, no matter how narrow or broad
    This feature makes it possible for readers to find better explanations of any topic created by other writers. And it allows writers to create an explanation in a place that readers might actually find it.
    Figure 1.
    Screenshot of the "Derivative" topic page
    . View it live at: ourbigbook.com/go/topic/derivative
  2. local editing: you can store all your personal knowledge base content locally in a plaintext markup format that can be edited locally and published either:
    This way you can be sure that even if OurBigBook.com were to go down one day (which we have no plans to do as it is quite cheap to host!), your content will still be perfectly readable as a static site.
    Figure 2.
    You can publish local OurBigBook lightweight markup files to either https://OurBigBook.com or as a static website
    .
    Figure 3.
    Visual Studio Code extension installation
    .
    Figure 4.
    Visual Studio Code extension tree navigation
    .
    Figure 5.
    Web editor
    . You can also edit articles on the Web editor without installing anything locally.
    Video 3.
    Edit locally and publish demo
    . Source. This shows editing OurBigBook Markup and publishing it using the Visual Studio Code extension.
    Video 4.
    OurBigBook Visual Studio Code extension editing and navigation demo
    . Source.
  3. https://raw.githubusercontent.com/ourbigbook/ourbigbook-media/master/feature/x/hilbert-space-arrow.png
  4. Infinitely deep tables of contents:
    Figure 6.
    Dynamic article tree with infinitely deep table of contents
    .
    Descendant pages can also show up as toplevel e.g.: ourbigbook.com/cirosantilli/chordate-subclade
All our software is open source and hosted at: github.com/ourbigbook/ourbigbook
Further documentation can be found at: docs.ourbigbook.com
Feel free to reach our to us for any help or suggestions: docs.ourbigbook.com/#contact