Upside: superconducting above 92K, which is above the 77K of liquid nitrogen, and therefore much much cheaper to obtain and maintain than liquid helium.
Downside: it is brittle, so how do you make wires out of it? Still, can already be used in certain circuits, e.g. high temperature SQUID devices.
Discovered in 1988, the first high-temperature superconductor which did not contain a rare-earth element.
Main theory to explain Type I superconductors very successfully.
TODO can someone please just give the final predictions of BCS, and how they compare to experiments, first of all? Then derive them.
High level concepts:
- the wave functions of pairs of electrons (fermions) get together to form bosons. This is a phase transition effect, thus the specific sudden transition temperature.
- the pairs form a Bose-Einstein condensate
- once this new state is reached, all pairs are somehow entangled into one big wave function, and you so individual lattice imperfections can't move just one single electron off trajectory and make it lose energy
The inaugural that predicted the Josephson effect.
Published on Physics Letters, then a new journal, before they split into Physics Letters A and Physics Letters B. True Genius: The Life and Science of John Bardeen mentions that this choice was made rather than the more prestigious Physical Review Letters because they were not yet so confident about the results.
Probable observation of the Josephson superconducting tunneling effect by 
Ciro Santilli 37 Updated 2025-07-16
Ciro Santilli 37 Updated 2025-07-16Paper by Philip W. Anderson and John M. Rowell that first (?) experimentally observed the Josephson effect.
Paywalled by the American Physical Society as of 2023 at: journals.aps.org/prl/abstract/10.1103/PhysRevLett.10.230
They used tin-oxide-lead tunnel at 1.5 K. TODO oxide of what? Why two different metals? They say that both films are 200 nm thick, so maybe it is:
-----+------+------+-----
... Sn | SnO2 | PbO2 | Pb ...
-----+------+------------
100nm 100nmA reconstruction of their circuit in Ciro's ASCII art circuit diagram notation TODO:
DC---R_10---X---GThere are not details of the physical construction of course. Reproducibility lol.
It is called "AC effect" because when we apply a DC voltage, it produces an alternating current on the device.
By looking at the Josephson equations, we see that a positive constant, then just increases linearly without bound.
Wikipedia mentions that this frequency is , so it is very very high, so we are not able to view individual points of the sine curve separately with our instruments.
Also it is likely not going to be very useful for many practical applications in this mode.
An I-V curve can also be seen at: Figure "Electron microscope image of a Josephson junction its I-V curve".
I-V curve of the AC Josephson effect
. Source. Voltage is horizontal, current vertical. The vertical bar in the middle is the effect of interest: the current is going up and down very quickly between , the Josephson current of the device. Because it is too quick for the oscilloscope, we just see a solid vertical bar.
Superconducting Transition of Josephson junction by Christina Wicker (2016)
Source. Amazing video that presumably shows the screen of a digital oscilloscope doing a voltage sweep as temperature is reduced and superconductivity is reached.
I-V curve of a superconducting tunnel junction
. So it appears that there is a zero current between and . Why doesn't it show up on the oscilloscope sweeps, e.g. Video 1. "Superconducting Transition of Josephson junction by Christina Wicker (2016)"?If you shine microwave radiation on a Josephson junction, it produces a fixed average voltage that depends only on the frequency of the microwave. TODO how is that done more precisely? How to you produce and inject microwaves into the thing?
The Wiki page gives the formula: en.wikipedia.org/wiki/Josephson_effect#The_inverse_AC_Josephson_effect You get several sinusoidal harmonics, so the output is not a perfect sine. But the infinite sum of the harmonics has a fixed average voltage value.
And en.wikipedia.org/wiki/Josephson_voltage_standard#Josephson_effect mentions that the effect is independent of the junction material, physical dimension or temperature.
All of the above, compounded with the fact that we are able to generate microwaves with extremely precise frequency with an atomic clock, makes this phenomenon perfect as a Volt standard, the Josephson voltage standard.
TODO understand how/why it works better.
Maximum current that can flow across a Josephson junction, as can be directly seen from the Josephson equations.
Is a fixed characteristic value of the physical construction of the junction.
It represents an internal state of the junction.
TODO is there any relationship between this and the Josephson effect?
Experimental observation published as Experimental Evidence for Quantized Flux in Superconducting Cylinders.
This appears to happen to any superconducting loop, because the superconducting wave function has to be continuous.
Video "Superconducting Qubit by NTT SCL (2015)" suggests that anything in between gets cancelled out by a superposition of current in both directions.
Experimental Evidence for Quantized Flux in Superconducting Cylinders by Ciro Santilli 37 Updated 2025-07-16
Ciro Santilli 37 Updated 2025-07-16Paywalled at: journals.aps.org/prl/abstract/10.1103/PhysRevLett.7.43
The paper that follows it in the journal is also of interest, "Theoretical Considerations Concerning Quantized Magnetic Flux In Superconducting Cylinders" by N. Byers and C. N. Yang, it starts:So there was some previous confusion about the flux quantum due to the presence of Cooper pairs or not.
In a recent experiment, the magnetic flux through a superconducting ring has been found to be quantized in units of ch/2e. Quantization in twice this unit has been briefly discussed by London' and by Onsager. ' Onsager' has also considered the possibility of quantization in units ch/2e due to pairs of electrons forming quasi-bosons.
Dumping the fitures at: archive.org/details/experimental-evidence-for-quantized-flux-in-superconducting-cylinders One day we can also dump the paper scans when it goes into the public domain in 2056! Public domain scientific paper by year.
Figure 1 of Experimental Evidence for Quantized Flux in Superconducting Cylinders
. The legend reads:(Upper) Trapped flux in cylinder No. 1 as a function of magnetic field in which the cylinder was cooled below the superconducting transition. temperature. The open circles are individual data points. The solid circles represent th, e average value of all data points at a particular value of applied field including all the points plotted and additional data which could not be plotted due to severe overlapping of points. Approximately two hundred data points are represented. The lines are drawn at multiples of hc/2e.(Lower) Net flux in cylinder No. 1 before turning off the applied field in which it was cooled as a function of the applied field. Open and solid circles have the same significance as above. The lower line is the diamagnetic calibration to which all runs have been normalized. The other lines are translated vertically by successive steps of hc/2e.
Figure 2 of Experimental Evidence for Quantized Flux in Superconducting Cylinders
. The legend reads:(Upper) Trapped flux in cylinder No. 2 as a function of magnetic field in which the cylinder was cooled below the superconducting transition temperature. The circles and triangles indicate points for oppositely directed applied fields. Lines are drawn at multiples of hc/2e.(Lower) Net flux in cylinder No. 2 before turning off the applied field as a function of the applied field. The circles and triangles are points for oppositely directed applied fields. The lower line is the diamagnetic calibration to which all runs have The other been normalized. lines are translated vertically by successive steps of hc/2e.
As mentioned in True Genius: The Life and Science of John Bardeen page 224, the idea of symmetry breaking was a major motivation in Josephson's study of the Josephson effect.
- the basis for the most promising 2019 quantum computing implementation: superconducting quantum computer
- Josephson voltage standard: the most practical/precise Volt standard, which motivated the definition of the ampere in the 2019 redefinition of the SI base units
- SQUID devices, which are:
- very precise magnetometer
- the basis for superconducting quantum computers
Superconducting Quantum Interference Device by Felipe Contipelli (2019)
Source. Good intuiotionistic video. Some points deserved a bit more detail.Mishmash of SQUID interviews and talks by Bartek Glowaki
. Source. The videos come from: www.ascg.msm.cam.ac.uk/lectures/. Vintage.
One of the segments is by John Clarke.
An experimental lab video for COVID-19 lockdown. Thanks, COVID-19. Presented by a cute and awkward Adam Stewart.
Uses a SQUID device and control system made by STAR Cryoelectronics. We can see Mr. SQUID EB-03 written on the probe and control box, that is their educational product.
As mentioned on the Mr. SQUID specs, it is a high-temperature superconductor, so liquid nitrogen is used.
He then measures the I-V curve on an Agilent Technologies oscilloscope.
Unfortunately, the video doesn't explain very well what is happening behind the scenes, e.g. with a circuit diagram. That is the curse of university laboratory videos: some of them assume that students will have material from other internal sources.
- youtu.be/ql2Yo5LgU8M?t=211 shows the classic voltage oscillations, presumably on a magnetic field sweep, and then he puts a magnet next to the device from outside the Dewar
- youtu.be/ql2Yo5LgU8M?t=253 demonstrates the formation of Shapiro steps. Inserts a Rohde & Schwarz signal generator into the Dewar to vary the flux. The result is not amazing, but they are visible somewhat.
Pinned article: Introduction to the OurBigBook Project
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Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
Intro to OurBigBook
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