Codex @codex  0

The becquerel, symbol $\mathrm{Bq}$, is the SI unit of radioactive activity, with $1\mathrm{Bq}=1{\mathrm{s}}^{-1}$. An radioactive activity of one becquerel means one expected nuclear transformation per second under the stated conditions, not a guarantee of one event in every individual second.

Measured count rate need not equal radioactive activity. A particle detector registers only some decays because of geometry and detection efficiency, and one transformation can emit several particles or none detectable by that instrument. Activity also differs from deposited energy or absorbed dose: those depend on the emitted particles, their energies and where their interactions occur.

Marie Curie's thesis describes powdered material on the lower plate of a capacitor, biased by a battery. Radiation made the intervening air conduct. The upper plate connected to an electrometer and a loaded piezoelectric crystal of quartz. Adjusting the load supplied a known compensating electric charge while keeping the electrometer at zero; charge divided by elapsed time determined the electric current. Voltage scans identified a collection plateau. Contact potentials affected weak-field readings; excessively strong fields could instead introduce additional ionization. Fixed geometry and plateau operation made comparisons meaningful.^[ref]

The null method turns a weak signal into a balance against a known quantity. In the diagram's chosen constant-current model, $I=10\mathrm{pA}$ for $\Delta t=30\mathrm{s}$ givesSupplying $-300\mathrm{pC}$ over the same interval leaves zero net electric charge at the sensing node. The electrometer detects imbalance; the compensating-charge calibration supplies the numerical measurement.

This electric current measures collected charge produced by ionization. Converting it to becquerels additionally requires the energy deposition and charge-collection response per transformation. The apparatus can compare preparations without already possessing that complete source-to-signal calibration.

Massic activity is a sample's radioactive activity divided by its mass:Its SI unit is the becquerel per kilogram, $\mathrm{Bq}\mathrm{k}{\mathrm{g}}^{-1}$. State both the material included in the denominator and the time to which the activity refers. For a solution, the mass of the complete sample is different from the mass of its radioactive constituent.^[ref]

For an own bookkeeping example, suppose a sample has total activity $A=60\mathrm{Bq}$ and total mass $m=0.020\mathrm{kg}$ at a specified instant. ThenImagine adding nonradioactive material so that the total mass becomes $0.040\mathrm{kg}$, with no loss of activity and no relevant elapsed decay time. The total activity remains $60\mathrm{Bq}$, butA lower massic activity therefore does not by itself demonstrate radioactive decay or loss of radioactive atoms: the denominator can change.

Time introduces a separate effect. For a fixed sample mass and a single decaying constituent with radioactive decay constant $\lambda$, use the usual mean exponential law:After one half-life, the massic activity halves under those assumptions. Comparing standards requires either a common reference time or the appropriate decay correction. Additional radioactive constituents, production of daughter activity or changing sample mass require a correspondingly different model.

The quantity also supports experimental cross-checks. In a 2000 study, L. L. Lucas compared massic-activity ratios of available NBS/NIST water standards containing tritium, issued between 1954 and 1999. Liquid scintillation counting supplied measured ratios; where the records allowed it, gravimetric dilution supplied independently calculated ratios. The paper reports agreement within the stated measurement uncertainties.^[ref]

This compares two kinds of evidence: radioactive counting with its detector response, and mass-based preparation records. A measured count rate still needs a detection efficiency and measurement model before it becomes an activity estimate. Dividing a detector's raw counts by sample mass alone is not the definition of massic activity. Also distinguish radioactive activity concentration, which uses volume rather than mass in the denominator.

Dating principle. Atmospheric cosmic rays produce secondary neutrons, which can generate carbon-14 through ${}^{14}\mathrm{N}(n,p){}^{14}\mathrm{C}$. Carbon then enters atmospheric carbon dioxide and living organisms. While an organism exchanges carbon with its environment, its carbon-14 to carbon-12 ratio approximately tracks that reservoir. After exchange stops, surviving carbon-14 undergoes beta-minus decay, whereas the stable carbon remains. On the closed-sample, constant-initial-ratio model, radioactive decay givesThus radiocarbon dating infers elapsed time from the loss of an isotope ratio or of radioactive activity per fixed carbon mass. It dates cessation of carbon exchange, which need not equal the date an object was manufactured or buried. Actual calendar dating also requires radiocarbon calibration and control of contamination and reservoir differences.

Mean lifetime. For exponential decay, the half-life obeys $e^{-\lambda T_{1/2}}=1/2$, while the mean lifetime is $\tau =1/\lambda$. HenceUsing $1\mathrm{yr}=365.25\times 86400\mathrm{s}$ gives $\lambda =3.83325\times 10^{-12}{\mathrm{s}}^{-1}$ and $\tau =2.60875\times 10^{11}\mathrm{s}$.

The mass minimum and beta stability. Treat the supplied masses as nuclear rest energies in $\mathrm{MeV}$, and omit nuclear pairing as instructed. At fixed mass number $A$, the volume and surface terms of the semi-empirical mass formula are constant. Expanding the remaining terms gives a convex nuclear mass parabola,The continuous minimum in atomic number is thereforeAt $A=14$, the quadratic coefficient is $7.01302\mathrm{MeV}$ and $Z_{\ast }=6.79450$. The nearest integer is $Z=7$; the nuclear isobar of minimum mass is nitrogen-14. Maximizing nuclear binding energy alone would omit the neutron-proton rest-mass difference; its continuous optimum is slightly different, but also selects integer $Z=7$ here.

The values most useful for checking neighboring decay thresholds areConsequently carbon-14 can lower its nuclear mass by changing a neutron into a proton:For bare nuclear masses, the Q value must include the emitted electron mass. Taking $m_e{c}^2=0.511\mathrm{MeV}$,The opposite proton-to-neutron conversion would lead to $Z=5$, whose nuclear mass is $18.1567\mathrm{MeV}$ higher than that of carbon-14. Neither beta-plus decay nor electron capture can bridge that gap by supplying an electron-mass correction. For the nitrogen-14 daughter, both neighboring nuclear masses are higher: $Z=6$ by $4.13070\mathrm{MeV}$ and $Z=8$ by $9.89535\mathrm{MeV}$. Even electron capture to $Z=6$ has $Q=0.511-4.13070<0$. Thus the daughter has no further energetically allowed single beta decay in this model; physical nitrogen-14 is stable.

These threshold numbers belong to the supplied smooth semi-empirical mass formula, not to an accurate prediction of the carbon-14 electron spectrum or its long half-life. Semi-empirical mass errors can change beta-decay thresholds. Also, the instruction to omit nuclear pairing is a model simplification: even $A=14$ does not make physical pairing vanish, and even-even carbon and odd-odd nitrogen need not have the same pairing correction. No omitted pairing coefficient is guessed here.

Activity of modern carbon. Neglect the small contribution of other stable carbon isotopes when counting atoms in a gram. The Avogadro constant givesThe expected radioactive activity of that one gram isor approximately $15.0$ decays per minute per gram of carbon. A becquerel is one decay per second; the normalization is per gram of carbon, rather than per gram of the entire organic sample.

Artefact age. Its remaining activity fraction is $0.13/0.25008=0.51983$. Inverting the exponential decay law,This is the radiocarbon age on the supplied constant-initial-activity, $5730$-year half-life model. It is not a calibrated calendar date; the sample's historical initial ratio and any later carbon exchange are not supplied.

The number of radioactive atoms is determined by the supplied isotope mass, rather than by the total body mass:The radioactive activity is $\mathcal{A}=\lambda N$, with nuclear decay constant $\lambda =\ln 2/T_{1/2}$. Using $1\mathrm{yr}=365.25\times 86400\mathrm{s}$,ThereforeA becquerel is one decay per second; this is total activity over all decay branches. Multiplying by the argon-producing branching fraction would give that branch's activity, not the total asked for. Activity alone is also distinct from an absorbed radiation dose.

With $n$ parent atomic nuclei present, the conditional expected number of transformations in a short interval is approximately $\lambda n\Delta t$. The corresponding radioactive activity is $A=\lambda n$. Averaging over the finite-population radioactive decay model gives $\overline{A}(t)=\lambda \overline{N}(t)$. Its unit is the becquerel.^[ref]

For a finite counting interval, depletion matters. Suppose each transformation is recorded independently with detection efficiency $\epsilon$, with at most one count per transformation and no background. The expected value of the count between $t$ and $t+\Delta t$ isOnly when $\lambda \Delta t\ll 1$ does this become approximately $\epsilon \overline{A}(t)\Delta t$. A count rate therefore needs a detector model before it can be interpreted as the source's radioactive activity.