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A nucleus can capture an electron when energetically allowed, converting a proton into a neutron and emitting an electron neutrino. Beryllium-7 electron capture participates in one of the proton-proton chain branches. Stellar capture rates depend on ionization, mass density and electron phase space.

A stellar equation of state supplies pressure and internal energy as functions of density, temperature and composition, together with thermodynamic derivatives needed for stability and transport. Hydrostatic equilibrium fixes the pressure gradient, but does not determine which microscopic components provide the pressure. In ordinary dense interiors local thermodynamic equilibrium is a useful starting point. A consistent mixture iswhere ions, Electrons, radiation and interaction corrections are distinguished. The classical Electron pressure and electron degeneracy pressure are two limits of the same Electron contribution, and must not be added as if they belonged to different particles. The finite-temperature electron equation of state interpolates between them.

In a fully ionized, nondegenerate, nonrelativistic gas, $P_g=\rho k_{B}T/(\mu m_u)$ and specific thermal energy is $u_g=3k_{B}T/(2\mu m_u)$. With nuclear mass fractions $X_A$, charges $Z_A$ and mass numbers $A_A$, the mean molecular weight satisfies ${\mu }^{-1}={\sum }_A{X}_A(1+Z_A)/A_A$, and ${\mu }_e^{-1}={\sum }_A{X}_A{Z}_A/A_A$ is the mean molecular weight per electron. This regime describes much of an ordinary main sequence interior. Toward cooler layers, ionization and molecular dissociation change particle numbers and consume heat. The Saha equation relates ionization to both temperature and Electron density: there is no universal horizontal ionization boundary. These regions have larger heat capacity and can have a reduced stellar adiabatic exponent. The simple fully ionized formula is then insufficient.

Equilibrium photons give radiation pressure $P_{\gamma }=a_r{T}^4/3$ and energy per volume $a_r{T}^4$, or specific energy $u_{\gamma }=a_r{T}^4/\rho$. In the nondegenerate gas regime, equality with gas pressure gives the radiation-to-gas pressure boundarya line of slope $1/3$ on a $(\log \rho ,\log T)$ plot. Higher temperatures at fixed mass density favor photon support. A monatomic gas has stellar adiabatic exponent $5/3$, while radiation alone has $4/3$; their adiabatic exponents of a monatomic gas-radiation mixture are not obtained by assuming a fixed pressure fraction during compression. Radiation support is particularly important in massive stars.

For Electrons, Pauli exclusion principle and the Fermi-Dirac distribution determine occupation numbers. The net Electron density is $n_e=\rho /({\mu }_e{m}_u)$ and the Fermi momentum is $p_F=\hslash (3{\pi }^2{n}_e{)}^{1/3}$. Define the kinetic electron Fermi temperatureFor $T\gg T_F$ the Electrons are nearly classical; for $T\ll T_F$ they are strongly degenerate and their pressure depends primarily on density. The intermediate region requires finite-temperature electron equation of state integrals, not a discontinuous switch of formulas.

The equation of state of a cold electron gas gives, in its two limits,These are respectively the $n=3/2$ and $n=3$ pressure-density powers, explaining the approximate white dwarf polytropic mass-radius relation sequence and the Chandrasekhar limit. The kinetic energy per volume is $3P_e/2$ in the nonrelativistic limit and $3P_e$ in the ultrarelativistic limit. Ions can still supply much of the heat capacity even when the Electron pressure supplies the mechanical support.

The Electron degeneracy crossover $T\sim T_F$ has slope $2/3$ at low mass density and $1/3$ at high mass density. The electron relativistic density threshold isa vertical marker where $p_F=m_{e}c$. It is different from the thermal electron relativistic threshold $k_{B}T\sim m_e{c}^2$, near $5.93\times 10^9\mathrm{K}$, a horizontal temperature scale. Hot dilute matter can have relativistic thermal Electrons without degeneracy; cold dense matter can have relativistic degenerate Electrons without reaching that temperature.

Electron degeneracy also does not automatically imply that Electrons dominate the total pressure. Comparing the cold Electron limit with radiation gives the radiation-to-degeneracy pressure boundaryIts logarithmic slopes are $5/12$ for nonrelativistic Electrons and $1/3$ for ultrarelativistic Electrons. One must compare the pressures separately from the degeneracy criterion; extrapolating the classical gas-radiation line into a degenerate region is incorrect.

The stellar equation-of-state regime diagram uses an illustrative fully ionized carbon composition, ${\mu }_e=2$, $\mu =12/7$. It displays the electron-degeneracy crossover, both radiation-pressure comparisons, and distinct thermal and density-driven relativity scales. The curves are limiting-model comparisons, not sharp phase boundaries or a calibrated complete equation of state. Partial ionization, molecular physics and interactions modify the low-temperature regions indicated on the plot.

At sufficiently high temperature, electron-positron thermal pair abundance can become important. The pair abundance depends on density and chemical potential as well as temperature; $k_{B}T=m_e{c}^2$ is not a universal onset line. In the dilute ultrarelativistic limit, both pair species together add energy density $7a_r{T}^4/4$ to the photons' $a_r{T}^4$, and have pressure one third of their energy density. While pairs are being created, thermal energy is spent on rest mass, which can reduce the stellar adiabatic exponent below $4/3$ and contribute to pair-instability supernova physics.

At high mass density and low temperature, Interactions governed by Coulomb's law invalidate the noninteracting-ion approximation. The ionic Coulomb coupling parameter $\Gamma =Z^2{e}^2/(4\pi {ϵ}_0{a}_i{k}_{B}T)$, where $a_i=(3/(4\pi n_i){)}^{1/3}$, grows as ${\rho }^{1/3}/T$. Corrections become significant when $\Gamma$ is of order one, and a sufficiently strongly coupled plasma can crystallize. At still greater mass density, electron capture alters ${\mu }_e$ and nuclear matter replaces the ideal electron-ion model; neutron star interiors require strong-interaction and relativistic equations of state. These further regimes lie beyond the simple pressure curves plotted here. A useful stellar EOS is thermodynamically consistent across the crossovers, rather than just the maximum of unrelated pressure laws.

For a slowly evolving spherical star, use a Lagrangian enclosed mass coordinate $m$. Let $u$ be specific thermal internal energy and $D/Dt$ follow a mass element. The stellar energy balance equation isThe outward luminosity is energy transported through the mass shell, ${ϵ}_{\mathrm{nuc}}$ is nuclear rest-mass energy released per unit mass and time, and ${ϵ}_{\nu }$ is escaping neutrino power per unit mass. Define the gravothermal stellar energy generation by ${ϵ}_{\mathrm{grav}}=-Du/Dt-PD(1/\rho )/Dt$. At fixed composition it is $-TDS/Dt$ by the first law of thermodynamics. During composition changes the full internal-energy derivative must use the appropriate equation of state, with nuclear rest-mass changes counted only once. If a tabulated nuclear rate already subtracts reaction-neutrino energy, that loss must not be subtracted a second time in ${ϵ}_{\nu }$.

In a nearly steady main sequence star, stellar nuclear fusion supplies most of the luminosity. Before stable hydrogen ignition, Kelvin-Helmholtz contraction releases gravitational energy. In a gas-supported hydrostatic star the stellar virial theorem gives $U\simeq -\Omega /2$, so about half the change in gravitational binding energy heats the star and half is available for radiation. The associated timescale is $G{M}^2/(RL)$. After nuclear burning ends, a white dwarf can shine by losing stored thermal energy; crystallization releases latent heat, and composition separation can add gravitational energy. These are heat and gravitational reservoirs rather than sustained hydrogen fusion.

Stellar nuclear fusion is possible because lighter nuclei can combine into products with larger nuclear binding energy. The energy per reaction is $Q=(m_{\mathrm{initial}}-m_{\mathrm{final}})c^2$, including the relevant particles consistently. Although thermal energies are below the Coulomb barrier, quantum tunnelling permits fusion. The thermonuclear reaction rate averages a cross-section over the thermal relative-speed distribution:For nonresonant charged-particle reactions the energy weighting contains $\exp [-E/(kT)-\sqrt{E_G/E}]$; the compromise between the thermal tail and penetration produces the Gamow peak. A resonance can greatly enhance the rate. Density, abundances and temperature therefore all affect the stellar energy-generation rate, and power laws such as $T^4$ or $T^{16}$ are local approximations.

For the proton–proton chain, first produce deuterium and helium-3:The initial reaction is slow because it converts a proton to a neutron through the weak interaction. It is the bottleneck that allows long hydrogen-burning lifetimes. The alternative pep reaction $p+e^{-}+p\to {}^2\mathrm{H}+{\nu }_e$ also feeds the same chain. There are three principal proton-proton chain branches. In pp I, two helium-3 nuclei terminate the chain:In pp II, helium-3 first captures an existing helium-4 nucleus, then electron capture and proton capture finish the branch:In pp III, the beryllium-7 instead captures a proton:Relative branch weights change with temperature and composition. All branches convert four protons into a net helium-4 nucleus, with two weak conversions and two neutrinos, allowing for the electron consumed in pp II. After including positron annihilation, the atomic-mass energy budget is approximately $26.7\mathrm{MeV}$ per net helium-4 nucleus, but the deposited heat is smaller by the branch-dependent escaping-neutrino energy. Near ordinary low-mass main-sequence conditions, ${ϵ}_{pp}\propto \rho X_H^2{T}^4$ is a useful local approximation.

The CNO cycle provides an alternative catalyzed hydrogen burning route in hotter cores. The CNO-I cycle, also called the CN cycle, consists ofThe carbon seed is regenerated: the net reaction again consumes four protons and produces one helium-4 nucleus, two positrons and two neutrinos. The slow ${}^{14}\mathrm{N}(p,\gamma ){}^{15}\mathrm{O}$ reaction governs the ordinary cycle and causes nitrogen-14 to accumulate. The CNO-II cycle branches through ${}^{15}\mathrm{N}(p,\gamma ){}^{16}\mathrm{O}$, ${}^{16}\mathrm{O}(p,\gamma ){}^{17}\mathrm{F}$, ${}^{17}\mathrm{F}\to {}^{17}\mathrm{O}+e^{+}+{\nu }_e$, and ${}^{17}\mathrm{O}(p,\alpha ){}^{14}\mathrm{N}$, after which the main cycle continues. Thus CNO nuclei are catalytic in the closed cycles, although their relative abundances change. A local rate is ${ϵ}_{\mathrm{CNO}}\propto \rho X_H{X}_{\mathrm{CNO}}{T}^{\eta }$ with a much steeper exponent than the PP chain; the preceding homology problem specifies $\eta =16$. The concentration of this heating near the centre favors a convective core in hotter, more massive hydrogen-burning stars.

Once hydrogen is exhausted in a core, contraction can raise its temperature enough for core helium burning. The Triple-alpha process overcomes the absence of stable mass-5 and mass-8 nuclei by maintaining a tiny transient beryllium-8 population:The Hoyle state, an excited carbon-12 resonance near the three-alpha threshold, makes the second capture efficient enough despite beryllium-8's very short lifetime. The net conversion is $3{}^4\mathrm{He}\to {}^{12}\mathrm{C}$, releasing about $7.27\mathrm{MeV}$. Because three alpha particles are required, the specific rate scales as ${\rho }^2{Y}^3$; a schematic resonant rate isIts local temperature exponent is $-3+44/T_8$, of order forty near $T_8=1$. A degenerate core cannot expand promptly to regulate this increase, giving a helium flash; in a nondegenerate core the stellar thermostat permits stable helium burning. The competing ${}^{12}\mathrm{C}(\alpha ,\gamma ){}^{16}\mathrm{O}$ reaction determines much of the eventual carbon-oxygen mixture.

If the core becomes hot enough, carbon burning follows, for example through ${}^{12}\mathrm{C}+{}^{12}\mathrm{C}\to {}^{20}\mathrm{Ne}+\alpha$ and ${}^{12}\mathrm{C}+{}^{12}\mathrm{C}\to {}^{23}\mathrm{Na}+p$. Neon burning begins with photodisintegration, ${}^{20}\mathrm{Ne}+\gamma \to {}^{16}\mathrm{O}+\alpha$, followed by alpha capture such as ${}^{20}\mathrm{Ne}+\alpha \to {}^{24}\mathrm{Mg}+\gamma$. The first step consumes heat, but the combined rearrangement can release net energy. Oxygen burning includes ${}^{16}\mathrm{O}+{}^{16}\mathrm{O}\to {}^{28}\mathrm{Si}+\alpha$ and channels producing phosphorus and other nearby nuclei. At still higher temperatures, silicon burning proceeds through photodisintegration and particle captures in a reaction network approaching quasi-statistical equilibrium, producing iron-group nuclei. It is not simply direct silicon-plus-silicon fusion; the products depend on the electron fraction and weak-interaction timescale.

The increasing nuclear binding energy per nucleon supplies progressively less energy as products approach the iron group. Further fusion past that region cannot provide sustained net heat to support a core. Massive stars can therefore end with an unstable iron-group core; lower-mass stars do not attain all these burning stages and instead leave remnants such as carbon-oxygen white dwarfs. Heavy-element neutron captures can synthesize nuclei beyond the iron group without being the principal hydrostatic power source.

Finally, stellar neutrino energy loss competes with every heat source. Reaction neutrinos accompany the proton–proton and CNO chains. Hot or dense material also emits neutrino pairs through $e^{-}+e^{+}\to \nu +\bar{\nu }$, plasmon decay, $e^{-}+\gamma \to e^{-}+\nu +\bar{\nu }$, and electron-ion bremsstrahlung. These neutrinos usually escape, unlike the photons whose transport is diffusive; neutrino trapping requires much more extreme collapse conditions. Late burning has smaller fuel-energy reservoirs and strong neutrino cooling, so its duration is much shorter than core hydrogen burning. The surface luminosity is the escaping photon power, $L=4\pi R^2\sigma T_{\mathrm{eff}}^4$, not the sum of photons and unobserved neutrino power. Radiative diffusion in a star, convection and electron conduction redistribute energy, while the energy-balance equation distinguishes true sources, losses and storage. Accretion or mass loss adds boundary energy and mechanical work when present, rather than changing the nuclear reaction budget.

The proton–proton chain first produces deuterium by a weak reaction and then helium-3 by proton capture. pp I ends with ${}^3\mathrm{He}+{}^3\mathrm{He}\to {}^4\mathrm{He}+2p$. pp II passes through beryllium-7 electron capture to lithium-7 and then proton capture. pp III passes through boron-8 beta-plus decay and beryllium-8 breakup. Each branch produces one net helium-4 nucleus from four protons, but the neutrino spectrum and deposited heat differ. In pp II the net weak reactions involve one emitted positron and one captured electron.