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The Fermi energy is the highest occupied one-particle energy in the ground state of a noninteracting Fermi gas at zero temperature, measured here relative to the lowest one-particle energy. The Pauli exclusion principle allows only one fermion in each complete one-particle quantum state, including its spin, so adding more particles fills progressively higher energy eigenstates. A cold gas can therefore have substantial kinetic energy even when its temperature is zero. In the thermodynamic limit, with the same energy reference, $E_F=\mu (T=0)$ where $\mu$ is the chemical potential.^[ref]

For a uniform, three-dimensional gas of noninteracting Electrons, with spin one-half, equal populations of the two spin states, no applied magnetic field, and nonrelativistic particles of mass $m=m_e$,Here $n$ is the total number density, $V$ the volume, $p_F$ the Fermi momentum, $\hslash =h/(2\pi )$ the reduced Planck constant, and $k_B$ the Boltzmann constant. The electron Fermi temperature $T_F$ expresses the same energy scale in kelvin; it is not the actual gas temperature. Strong degeneracy of a degenerate electron gas means $T\ll T_F$. The momentum formula counts states and survives changing the energy–momentum relation, whereas $E_F=p_F^2/(2m)$ requires $p_F\ll mc$.^[ref]

The reference matters: the displayed $E_F$ excludes rest energy and sets the zero at $p=0$. Including rest energy shifts both the one-particle energy and the zero-temperature chemical potential by $m{c}^2$, leaving occupations unchanged. More generally, adding a constant $C$ to every one-particle energy also adds $C$ to $\mu$; the Fermi-Dirac distribution depends only on their difference. In a finite quantum system the chemical potential at zero temperature can lie between the last occupied and first empty energy eigenstates; its equality with the filling edge is a continuum statement.

At positive temperature, $E_F$ remains the zero-temperature scale associated with the specified number density. The Fermi level $\mu (T)$ must instead satisfy the particle-number conditionwhere $g(E)$ is the extensive density of states, including both spin states. Smearing the Fermi-Dirac distribution while arbitrarily holding $\mu =E_F$ generally changes $N$. This distinction matters when interpreting electron heat capacity and any experiment that infers temperature from an occupation profile.^[ref]

The Fermi sea is the zero-temperature many-fermion quantum state with every one-particle state below the Fermi energy occupied and every state above it empty. For a uniform isotropic Fermi gas, the occupied region in momentum space is a solid sphere; its boundary is the Fermi surface. These are momenta, not positions: filling the sphere does not put the particles in a ball in ordinary space. Opposite momentum contributions cancel, so the gas at rest has zero total momentum even though its total kinetic energy is positive.

The filled states are forced upward in energy by the Pauli exclusion principle. This is different from the zero-point energy of one particle confined by a boundary. At fixed number density, the Fermi energy remains positive as the box grows to the thermodynamic limit, while the lowest box confinement energy tends to zero. Low-energy excitations move particles from occupied states near the Fermi surface into nearby empty states; deep states have no nearby available destination. This explains why only a small fraction of Electrons contribute to the low-temperature electron heat capacity.^[ref]