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For a hydrogen-dominated fully ionized plasma, the line-of-sight emission measure is $\mathrm{EM}=\int n_e^{2}dl$. Its units distinguish it from a volume-integrated emission measure $\int n_e^{2}dV$. Thermal free-free optical depth is proportional to $\mathrm{EM}{T}^{-3/2}{\nu }^{-2}{\bar{g}}_{\mathrm{ff}}$ in the radio limit. Inferring density also requires depth, ionization and clumping assumptions.^[ref]

Official course and author record: science.nrao.edu/opportunities/courses/era

Chapter 4, Free–Free Radiation: www.cv.nrao.edu/~sransom/web/Ch4.html

NRAO-hosted authored text. Equations (4.57)–(4.60) define emission measure, radio optical depth and optically thick/thin observables. The course page identifies both authors and the 12 March 2016 preface date.

thermal bremsstrahlung is continuum radiation from electrons accelerated in ion electric fields. For Maxwellian electrons,At high frequency the exponential cutoff constrains $T_e$; X-ray fitting must also model foreground absorption, line emission, detector response and possible multitemperature or nonthermal components. At radio frequencies, $h\nu \ll k_B{T}_e$, an optically thin free-free spectrum is almost flat, with the weak frequency dependence set mainly by the Gaunt factor.

For pure ionized hydrogen, radio free-free opacity givesThe turnover constrains emission measure; a resolved, optically thick source has brightness temperature approaching $T_e$. An unresolved source has an unknown beam filling factor, so its observed brightness need not equal its electron temperature. Angular size and an independent distance give a geometric depth $L$; a uniform model then yields $n_e=\sqrt{\mathrm{EM}/L}$. Clumping instead measures a density-squared average, not the mean density.^[ref]

A free-free spectrum alone does not uniquely determine density and size. The density-depth degeneracy of free-free radiation is explicit: for a resolved uniform column, $n_e\mapsto q{n}_e$, $L\mapsto L/q^2$ leaves both emissivity-integrated brightness and optical depth unchanged at fixed temperature. With independent SZ information and known $T_e$, the electron column is $N_e=y{m}_e{c}^2/({\sigma }_T{k}_B{T}_e)$; thenThese equalities require consistent composition and geometry, and uniform density and temperature. Relating $L$ to angular extent can give distance; asphericity and the gas clumping factor are important limitations of this combined cluster method.

An electron accelerated in an ion's Coulomb field emits bremsstrahlung. Both electron states are unbound, giving free-free radiation rather than a discrete bound-state line. Averaging over a Maxwellian electron distribution gives an optically thin spectral emissivity with dependenceHere $C_{\mathrm{ff}}$ depends on the emissivity convention, and the Gaunt factor supplies the quantum correction. No numerical emissivity normalization is needed for these diagnostics. For a mixture, sum $Z_i^2{n}_i$ over ion species. The bolometric emissivity is proportional to $n_e\sum Z_i^2{n}_i{T}^{1/2}$ with a frequency-averaged Gaunt factor. Thermal electron speeds control the spectrum while the encounter rate supplies its density-squared dependence.

temperature can be measured from the high-energy exponential cutoff at photon energy of order $k_{B}T$, provided the spectrum spans that turnover and foreground absorption and nonthermal contamination are modelled. At radio frequencies $h\nu \ll k_{B}T$, the exponential is nearly one, so the optically thin continuum is a poor thermometer by slope alone. Kirchhoff's law, ${\alpha }_{\nu }=j_{\nu }/B_{\nu }$, and the Rayleigh-Jeans law give ${\alpha }_{\nu }\propto n_e{n}_i{T}^{-3/2}{\nu }^{-2}{\bar{g}}_{\mathrm{ff}}$ for an isothermal thermal plasma. The transfer solution isin the radio limit. A resolved optically thick region therefore measures its electron temperature through brightness temperature, if it fills the beam. The turnover between thick and thin emission constrains the line-of-sight emission measure $\mathrm{EM}=\int n_e^{2}dl$ for a hydrogen-dominated fully ionized plasma. In the thin regime $T_b\simeq T{\tau }_{\nu }$, rather than $T_b=T$. The slowly varying Gaunt factor gives a nearly flat optically thin radio flux-density spectrum, in contrast to the ${\nu }^2$ thick limit at fixed projected area.^[ref]

To obtain density, one also needs geometry. An angular extent and independent distance give a transverse size; an assumed shape provides a depth or volume. For approximately uniform emitting gas with astrophysical volume filling factor $f_V$, $L_{\mathrm{ff}}\propto n_e^2{f}_{V}V{T}^{1/2}$, so $n_e\propto [L_{\mathrm{ff}}/(f_{V}V{T}^{1/2}){]}^{1/2}$. Alternatively a measured column emission measure and assumed path length give an rms density. Clumping raises the mean squared density relative to the square of the mean: the inferred value is not automatically the mean gas density. Free-free brightness alone does not uniquely determine temperature, density and physical size. Resolved imaging, a distance, optical-depth information or an independent column-density diagnostic is needed to remove those degeneracies. Cluster SZ data are complementary because their leading signal depends on $\int n_e{T}_{e}dl$, whereas free-free emission depends on density squared. Metal lines, unresolved temperature structure, foreground absorption, synchrotron emission and background subtraction must be controlled before attributing the continuum to a single thermal component.