In uniaxial extensional flow, the conformation equations give and . Their stress difference gives the displayed extensional viscosity. A stable positive steady conformation requires both denominators positive; a first pole marks loss of a bounded steady response. At zero extension rate the Trouton ratio is three relative to the zero-shear viscosity.
For uniaxial extensional flow use , so . Again put and . A steady diagonal tensor has
Set . Then
Since and , multiplication gives
This is the cubic for uniaxial extension of an affine linear PTT fluid. For , choose its physical root , continuous from at rest. The product on the left grows strictly from zero to infinity in that interval, so this root is unique. The other algebraic roots need not describe an admissible steady material state.
The extensional viscosity is the axial-minus-transverse normal stress divided by the principal extension rate. Isotropic pressure cancels, leaving
At small , and . Thus
the Trouton ratio of three relative to the zero-shear viscosity. At large with fixed , the positive cubic root remains bounded and tends to : dividing the cubic by gives . Therefore
The nonlinear relaxation prevents the divergent high-rate response of the affine Maxwell model. If , the physically stable steady branch instead has and ends at ; no finite positive high-rate limit follows. The finite plateau consequently presumes the usual positive PTT relaxation parameter, as well as .
Choose the extending direction as and write . The uniaxial extensional flow, satisfying incompressibility, has
Starting from rest, symmetry preserves . The differential pom-pom model tensor equation becomes
Put . For , the solutions are
If , both transients decay, giving
If , the axial component is instead and grows exponentially without bound, while . At the boundary , which lies between the two stated regimes, grows linearly and .
Normalization makes the molecular orientation finite even when the unnormalized conformation tensor diverges. For , direct division by gives
For , the divergent axial component dominates the matrix trace, so
The same normalized limit holds at , agreeing continuously with the limit of the subcritical expression. The limiting orientations have nonnegative eigenvalues and unit matrix trace, as required for the normalized molecular orientation.
Now set . Its limiting value is
The scalar stretch equation is . If , its coefficient is eventually bounded above by a negative constant. The variation of constants formula gives a bounded solution, converging to
If , the coefficient is eventually positive, and the positive stretch grows without bound. At equality a bounded stretch would imply , which contradicts boundedness. Thus equality is not an additional bounded steady regime.
The function is continuous and strictly increasing from zero to infinity. Consequently there is a unique critical extension rate defined by
and the molecular stretch remains bounded precisely for . This is distinct from the tensor threshold . If , for example, the normalized orientation can remain well defined and the stretch remain bounded for some rates above the tensor threshold; divergence of alone does not prove divergence of the physical stress.
In the requested doubly subcritical regime, write . The steady uniaxial extension of the differential pom-pom model has
The isotropic pressure cancels from the tensile normal-stress difference. Hence the extensional viscosity is
or
Its zero-rate limit is , recovering the Trouton ratio of three. The restrictions exclude both loss of a finite tensor steady state and loss of a finite stretch steady state; neither denominator may be continued through its singularity as a physical steady constitutive response.
Let two observers be related by , with Q a proper rotation matrix. A spatial second-rank tensor has material frame indifference if its values at corresponding events satisfy . This defines an objective second-rank tensor, and allows the observer's rotation to depend on time.
For Cauchy stress tensor, consider a material surface element with unit normal n and contact traction . A rigid observer change preserves its area and rotates both its normal and actual contact force: , . Thus for every n, proving . Fictitious body forces of an accelerated observer do not alter this transformation of physical contact traction.
To keep the vorticity convention explicit, write , and , the negative of the usual component-first spin tensor. Equivalently, with the derivative-index-first used in the paper, . Put , which is antisymmetric. The transformed velocity is , and direct differentiation gives
The additional observer spin cancels from the symmetric part, proving that the rate-of-strain tensor is objective.
Along the same material particle, differentiating gives
The two extra terms cancel those from . Moreover . Hence the complete objective time derivative satisfies
This proves covariance for every constant scalar ; changing the spin convention without changing the commutator sign would not. It is a Gordon--Schowalter derivative with the paper's slip-parameter convention.
For the Johnson-Segalman fluid, first use the standard uniaxial extensional flow , with . Here and E is diagonal. The steady conformation equation gives
with vanishing off-diagonal components on the stable steady branch. The tensile normal-stress difference is . Dividing by the extension rate gives the Johnson-Segalman extensional response:
The conformation tensor evolution in each principal direction is . Therefore a positive, attracting steady conformation requires both displayed denominators positive. For the first pole is at ; for it is at in the transverse components. At a pole the corresponding component grows linearly in time, and beyond it generically grows exponentially. The model has a finite-rate extensional catastrophe; the algebraic viscosity cannot be continued as a physical steady response past the first pole. At zero rate, , giving Trouton ratio three. For the polymer contribution to stress disappears and the response is simply Newtonian.
The question does not specify extension geometry. If a planar convention is intended instead, the same diagonal calculation gives , valid on the stable branch . The preceding boxed formula uses the standard uniaxial definition of extensional viscosity.
For simple shear flow , write , , , and . The xx, yy and xy components of the steady constitutive equation give
Substituting the first two relations into the third yields , with . Define the viscometric functions by , and , using x for flow, y for the shear gradient and z for vorticity. The Johnson-Segalman steady viscometric functions are therefore
The solvent creates no normal-stress differences in this flow. For nonzero , the fluid is shear thinning with positive first and negative second normal-stress differences.
To classify the stress curves, set and . The scaled shear stress is , and
The second term has minimum at . Thus the shear stress is monotone for and has a decreasing segment for . At equality it has a horizontal tangent but no decreasing interval. Below the threshold, its maximum and minimum occur at
with the smaller root giving the maximum. Negative-rate curves are obtained by odd reflection.
Figure 1.
Monotone, marginal and nonmonotone Johnson-Segalman shear-stress curves
. Details.
For small b, polymer stress dominates the low-rate response, while the solvent restores a positive high-rate slope. The Johnson-Segalman negative-slope shear threshold signals a constitutive instability of homogeneous shear: different local shear rates can carry the same shear stress, permitting shear banding. A stress plateau or a selected interface position cannot be inferred from the local curve alone; spatial regularization and boundary/history information matter. This limitation is illustrated in a primary diffusive Johnson-Segalman study. If , the scaling by b is inapplicable and the stress is just .
Under the plug-like extensional viscosity approximation, incompressibility gives . Symmetry about fixes . Remove the reference hydrostatic stress of the middle fluid, and write for its leading vertical normal stress. Vertical traction balance at the upper surface gives
The middle fluid's horizontal normal stress exceeds by : the horizontal strain is and the vertical strain is . Hence
At a slightly inclined upper interface, tangential traction continuity gives, to the order retained in the small-outer-viscosity extensional approximation,
The slope term is needed even though the interface is nearly horizontal: dropping it would miss the derivative of in the extensional resultant. Terms involving the outer deviatoric normal-stress difference times the slope are smaller in this approximation. Integrating horizontal force balance over the symmetric layer, or over its upper half, now gives
Substitution yields the extensional-flow equation
The full layer thickness is , so its conservation of mass is , or
This explains the factor in the extensional stress rather than the shear viscosity coefficient alone.
For a Fourier mode of wave number , set and . Neglect as stipulated. The Fourier traction map for a viscous half-space, with outer dynamic viscosity , gives . The two linear equations are
Eliminating proves the positive decay rate for relaxation of a symmetric viscous layer:
When , inner longitudinal extension dominates the viscous dissipation, and . When while the plug approximation remains valid, tangential motion of the semi-infinite outer fluids supplies the main resistance, and . The PDF's second inequality is ; the TeX converts it incorrectly to . At much larger outer viscosity the plug assumption fails, as the next calculation shows.
Setting gives the Upper-convected Maxwell model
In steady incompressible uniaxial extension of rate , its tensile and transverse stresses give
The extensional viscosity rises above the Trouton ratio value and diverges at , the ideal model's extensional catastrophe. An extensional rheometer can locate that rapid growth and estimate . More robustly, impose a small deformation, stop the flow, and fit the exponential stress decay .
For the uniaxial extensional flow
the spin tensor vanishes and
The flow is steady and homogeneous, so with the Jaumann derivative of vanishes. The structure equation yields
Writing and using
gives
Consequently
The extensional viscosity is the tensile stress difference divided by :
For this is the constant
The factor three is the Trouton ratio associated with the effective zero-rate shear viscosity.
For uniaxial extension,
The diagonal steady conformation tensor is
where physical solutions require . The extensional viscosity is
The implicit closure is
A layer of half-thickness , dynamic viscosity and density , between semi-infinite fluids of viscosity and densities , relaxes a symmetric thickness Fourier mode. In the plug-like extensional viscosity regime, mass conservation and together with the Fourier traction map for a viscous half-space give the displayed rate, where . Inner longitudinal extension dominates for ; outer tangential resistance dominates for while the plug approximation remains valid.
For extension rate and , the steady conformation tensor is . Its normalized orientation has axial component and transverse components . Stretch is finite only if , when and the displayed extensional viscosity follows. Above , the unnormalized axial tensor grows exponentially but ; then stretch remains bounded only if . Orientation normalization and stretch relaxation therefore impose different thresholds.
For uniaxial extensional flow put , and . The diagonal components are , . The identity gives the cubic equation in the title. For its physical root has and connects to at rest. Its extensional viscosity is , tending to at small and at large . At the stable steady Maxwell extension instead ends at ; the finite high-rate limit must not be extended to that degenerate case.