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The central field approximation replaces the anisotropic many-electron environment by an average spherical potential, giving one-electron orbitals labelled by $n,l,m$. Screening changes the effective radial attraction and removes the pure Coulomb degeneracy between different $l$.

The Hartree method improves the potential self-consistently. For normalized occupied orbitals,Guess orbitals, construct their mean fields, solve the Hartree equations, and iterate to convergence. The $j\ne i$ sum excludes self-interaction in this product-state model. A spherical average can enforce the central-field specialization. A Hartree product state omits fermionic exchange and dynamical correlation; Hartree-Fock method adds antisymmetry and exchange through a Slater determinant. Converged orbital eigenvalues must not simply be added as the total energy, because that double counts pair interactions.^[ref]

A bosonic coherent state is an eigenstate of its annihilation operator,Its mean occupation is $|\alpha {|}^2$ and its number variance is also $|\alpha {|}^2$, giving a Poisson number distribution. It has a well-defined complex mean field but fluctuating particle number. Its overlap with another coherent state is $\exp [-(|\alpha {|}^2+|\beta {|}^2)/2+{\alpha }^{\ast }\beta ]$, so distinct amplitudes need not be orthogonal. For large occupation, a phase-space wave packet has small relative number fluctuations; this does not require an exact self-adjoint phase operator conjugate to a number bounded below.

For a bosonic field, a useful coherent-field condensate variational state isIt obeys $⟨\hat{\Psi }(\mathbf{r})⟩=\psi (\mathbf{r})$. For a contact-interacting dilute Bose gas, its normal-ordered energy expectation isMinimizing $E-\mu \bar{N}$ gives the stationary Gross–Pitaevskii equation, $[-{\hslash }^2{\nabla }^2/(2m)+V+g|\psi {|}^2]\psi =\mu \psi$. Its phase gradient determines superfluid flow, while weak-link phase differences give Josephson currents. The complex microscopic expectation supplies the order field used by a mean-field description of a bosonic superfluid.

An exactly fixed-number condensate can instead use the Hartree product state $(a_{\phi }^{†}{)}^N|0⟩/\sqrt{N!}$. Its one-point field expectation vanishes by number conservation, but its one-body density matrix has a macroscopic eigenvalue. Off-diagonal long-range order expresses that number-conserving criterion. Selecting a phase is a useful thermodynamic symmetry-broken description; it is not a claim that every finite isolated condensate literally has indefinite total number. A plain coherent product also misses interaction-induced quantum depletion, which needs correlations such as those in the Bogoliubov quasiparticle vacuum.

In a spin-singlet superconductor, the corresponding variational state is the BCS ground stateEach block superposes an empty and an occupied pair state. Where $u_{\mathbf{k}}\ne 0$, it can be rewritten as $(\prod u_{\mathbf{k}})\exp [\sum (v_{\mathbf{k}}/u_{\mathbf{k}})a_{\mathbf{k}\uparrow }^{†}{a}_{-\mathbf{k}\downarrow }^{†}]|0⟩$, treating any fully occupied blocks separately. The exponential truncates within each block because a fermionic pair cannot be created twice in the same two modes. This is a Cooper-pair pseudospin coherent state, rather than a coherent state of unrestricted ideal bosons.

The one-electron expectation remains zero in a fermion-parity-even BCS state. Its nonzero microscopic order is the BCS anomalous average $F_{\mathbf{k}}=⟨a_{-\mathbf{k}\downarrow }{a}_{\mathbf{k}\uparrow }⟩=u_{\mathbf{k}}^{\ast }{v}_{\mathbf{k}}$. For an attractive interaction written with matrix elements $V_{\mathbf{k}{\mathbf{k}}^{\prime }}$, the gap is ${\Delta }_{\mathbf{k}}=-{\sum }_{{\mathbf{k}}^{\prime }}{V}_{\mathbf{k}{\mathbf{k}}^{\prime }}{F}_{{\mathbf{k}}^{\prime }}$. Minimization yields the coherence factors and gap equation. Fermionic coherent states using Grassmann variables are valuable integration tools, but they are not ordinary complex-eigenvalue electron states replacing this physical paired wavefunction.^[ref]

Near the transition, a slowly varying pair field connects the microscopic anomalous average to Ginzburg-Landau theory of superconductivity. The phenomenological complex field has pair charge $-2e$, a phase that controls supercurrent and a magnitude whose normalization is model dependent. It is not the expectation of a single-electron field. Microscopic derivation of Ginzburg-Landau theory supplies this connection under its stated near-critical assumptions. Pair phase coherence, Josephson interference and flux quantization then become different manifestations of the same macroscopic paired order. Paired-fermion superfluids likewise use a pair order field, while bosonic atomic superfluids can use a one-particle condensate field.