For a positive-definite Hermitian matrix with spectral decomposition , the matrix logarithm is . More generally it is a branch of the inverse of the matrix exponential when such a branch exists.
On complex symmetric matrices with positive-definite real part, the determinant has a nonzero analytic square root normalized positively on real positive matrices. It is continued within this accretive domain. For , put with real eigenvalues ; then , using positive-real-part roots for each factor. The principal scalar square root of the product determinant need not equal this continued root: accumulated determinant arguments can cross the scalar branch cut. The principal matrix logarithm instead tracks all factors consistently.
For a positive-definite Hermitian operator and a unit vector , the weights form a probability distribution. Scalar logarithmic concavity bounds their average of by the logarithm of their average of . Positive semidefinite operators follow by a limiting convention. Using the eigenbasis of a density operator gives , where is the spectrum of and the diagonal of in that basis. This yields nonnegativity of quantum relative entropy without commutativity.
An invertible complex Jordan block , with , has logarithm , where . Applying this construction blockwise and conjugating back proves surjectivity of the matrix exponential on the complex general linear group. There is no globally single-valued continuous choice of logarithm.
For positive-definite Hermitian matrices , Klein's inequality gives
with equality exactly when . To prove it, let be their eigenvalues and their orthonormal eigenvectors. The weights have row and column sums one. The difference between the two sides is
by the scalar logarithm inequality . Equality requires whenever , implying . Limits extend the result to positive semidefinite matrices with the appropriate support condition. Applying it to trace-one matrices proves nonnegativity of quantum relative entropy.

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