Set and for spatial indices. The complex conjugation of the scalar supplies a minus sign, while conjugating each of the three spatial gamma matrices supplies three more. In the original order,Consequently the chirality matrix obeysNo rearrangement of the gamma matrices is needed, so no additional anticommutator sign occurs. The star is entrywise complex conjugation, not matrix transpose or Hermitian conjugation.
Assume a complete relativistically normalized basis of scalar momentum eigenstates transforms asThis states both reversal of spatial momentum and preservation of the normalization of basis quantum states. Antilinearity alone would not suffice: multiplying a conjugation operator by two gives an antilinear operator that multiplies squared norms by four.
Expand and similarly for , with . This Lorentz-invariant phase-space measure is unchanged under . The antilinearity of the quantum time-reversal operator gives conjugated expansion coefficients. Orthogonality of the momentum eigenstates and cancellation of their unit-modulus phases yieldSince momentum reversal is a bijection of the complete basis, is also onto. ThusThis proves antiunitarity, with the normalization hypothesis explicitly included. For scalar multiparticle quantum states the same argument uses the complete occupation-state basis and reverses all momenta; it is not restricted to a single-particle wave packet.
Write for , so . Under the antiunitary operator , the coefficients and exponentials in the mode expansion of a Dirac field are conjugated as well as the creation and annihilation operators being transformed. ThusRelabel and . The stated Dirac spinor identities implyAlso . Substitution reconstructs the original Dirac field at the reflected time:The minus sign comes from reversing the spin label, not from anticommuting field operators. This is the relation between the time-reversal matrix and the charge-conjugation matrix in the supplied spin phases and intrinsic phase convention. Rephasing the charge-conjugation matrix or the intrinsic time-reversal phase can change its displayed form. It proves time reversal of a Dirac field without identifying an antiunitary operator with its finite-dimensional spinor matrix.
Use without summing in individual component transformations. The Dirac current transforms asSince the coupling is real, invariance of its contraction fixes the time reversal of an electromagnetic gauge field:These equations use a compatible gauge; an additional pure gauge transformation would not change the gauge field strength.
Coordinate differentiation at introduces , because the time coordinate is reversed and the spatial coordinates are unchanged. HenceThus the electric field is even and the magnetic field is odd. The chirality matrix is even by part (a). The two tensor signs cancel in the dipole contraction, but antiunitarity conjugates its explicit . Therefore the time-reversal parity of a fermion electric dipole operator isIt is a time-reversal symmetry violating interaction, and, under the usual local relativistic quantum field theory hypotheses of the CPT theorem, it violates CP symmetry. A nonzero coefficient is absent from the renormalizable tree-level Standard Model Lagrangian: the broken-phase fermion electric dipole moment operator has mass dimension five, and its electroweak-invariant completion requires a Higgs field and has dimension six. However, it can arise as a radiatively induced effective interaction in the Standard Model, whose CKM matrix contains a CP-violating phase. It is not forbidden to all orders. An explicit primary calculation of quark dipoles is Czarnecki and Krause's Standard Model calculation.
Starting from a matter-antimatter symmetric ensemble, exact charge conjugation would pair every baryon-producing process with an equally probable antibaryon-producing process. Their contributions to the net baryon number cancel. Thus C violation is necessary. Violating charge conjugation alone is insufficient: if CP symmetry is exact, the parity-reflected conjugate channels still have equal probabilities and cancel in a CP symmetry invariant ensemble. One needs CP violation as well.
The remaining Sakharov conditions are baryon number violation and departure from thermal equilibrium. Conserving baryon number cannot turn an initially zero value into a nonzero one. In thermal equilibrium, under the usual CPT theorem hypotheses and with no imposed chemical potentials for charges odd under CPT symmetry, states and their conjugates have equal thermal weights, so the equilibrium expectation of net baryon number vanishes and thermal stationarity prevents its sustained production. A nonequilibrium history allows different forward and reverse populations to generate an asymmetry. These are the standard necessary conditions for dynamical baryogenesis from symmetric initial conditions, not a guarantee of a sufficiently large asymmetry.
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