Blackbody radiation defeated classical equipartition because it predicts excessive short-wavelength emission. Quantized oscillator energy exchange , and ultimately the photon occupation law, gives the Planck spectrum. In the photoelectric effect, electron energy follows light frequency with a threshold, rather than simply increasing with beam intensity; individual photons supply and the maximum kinetic energy is . Intensity chiefly changes the event rate at a fixed frequency. These explain two distinct failures of a purely continuous classical wave-plus-matter model, while retaining wave propagation and interference.
Approximate helium mass by kg. Nonrelativistic momentum is , giving . A transverse width of one micrometre implies a characteristic position uncertainty of that order and a minimum momentum uncertainty of order kg m s, with factors depending on profile convention. For a uniform interval , but an exactly abrupt rectangular wavefunction actually has infinite rms momentum spread. Width alone does not uniquely specify both rms uncertainties; a smooth near-minimum-uncertainty beam is needed for a finite order-of-magnitude estimate.
Immediately after a uniformly illuminated hard slit, the normalized transmitted state is for , zero elsewhere. With Fourier convention ,
The supplied sinc integral verifies unit normalization. The first zeros occur at , but this finite central-lobe width is not the rms uncertainty: fails to have a convergent integral.
For an aligned narrower slit placed immediately after the first, uniform illumination gives transmission probability . Conditional on passage the same normalized formula applies with replaced by and central-lobe momentum scale . Position rms is , while the exact hard-edge rms is infinite. Thus the source's finite “uncertainty” can only mean a characteristic diffraction width; the rigorous Heisenberg inequality is not violated, and smoothing the edges restores finite rms moments satisfying it.
A 10 keV X-ray has nm. The ideal position-filter probability and momentum formula at fixed aperture widths are unchanged, since the Fourier transform involves and the aperture geometry. Its larger total momentum makes the angular diffraction width smaller, approximately . Real slit-material transmission and absorption are additional experimental issues.
To distinguish equal transverse bins across width , . Six bits gives one-nanometre pixels; ten gives 0.0625 nm, below the helium wavelength. In the stipulated fixed-energy freely propagating beam, the latter entails transverse diffraction momenta comparable to or exceeding the available total momentum and lies outside the paraxial aperture model. Six-bit localization is less demanding, although fine detector resolution and losses remain practical constraints. This is not a universal theorem that an atom can carry at most six bits in every encoding: accessible modes, energy, aperture, measurements and success probabilities define the channel.

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