Blackbody radiation defeated classical equipartition because it predicts excessive short-wavelength emission. Quantized oscillator energy exchange hν, and ultimately the photon occupation law, gives the Planck spectrum. In the photoelectric effect, electron energy follows light frequency with a threshold, rather than simply increasing with beam intensity; individual photons supply hν and the maximum kinetic energy is hν−W. Intensity chiefly changes the event rate at a fixed frequency. These explain two distinct failures of a purely continuous classical wave-plus-matter model, while retaining wave propagation and interference.
Approximate helium mass by 2mp+2mn≃6.69×10−27 kg. Nonrelativistic momentum is p=2mT, giving λ=h/p≃0.203 nm. A transverse width of one micrometre implies a characteristic position uncertainty of that order and a minimum momentum uncertainty of order ℏ/a∼10−28 kg m s−1, with factors depending on profile convention. For a uniform interval Δx=a/12, but an exactly abrupt rectangular wavefunction actually has infinite rms momentum spread. Width alone does not uniquely specify both rms uncertainties; a smooth near-minimum-uncertainty beam is needed for a finite order-of-magnitude estimate.
Immediately after a uniformly illuminated hard slit, the normalized transmitted state is ψ(x)=w−1/2 for ∣x∣<w/2, zero elsewhere. With Fourier convention ψ(p)=(2πℏ)−1/2∫e−ipx/ℏψ(x)dx,The supplied sinc integral verifies unit normalization. The first zeros occur at ±δpx, but this finite central-lobe width is not the rms uncertainty: px2p fails to have a convergent integral.
ψ(px)=2πℏwsinc2ℏpxw,p(px)=δpx1sinc2δpxπpx,δpx=wh.
For an aligned narrower slit placed immediately after the first, uniform illumination gives transmission probability d/w. Conditional on passage the same normalized formula applies with w replaced by d and central-lobe momentum scale h/d. Position rms is d/12, while the exact hard-edge rms Δpx is infinite. Thus the source's finite “uncertainty” can only mean a characteristic diffraction width; the rigorous Heisenberg inequality is not violated, and smoothing the edges restores finite rms moments satisfying it.
A 10 keV X-ray has λ≃0.124 nm. The ideal position-filter probability and momentum formula at fixed aperture widths are unchanged, since the Fourier transform involves h and the aperture geometry. Its larger total momentum makes the angular diffraction width smaller, approximately λ/d. Real slit-material transmission and absorption are additional experimental issues.
To distinguish 2b equal transverse bins across width w, d=w/2b. Six bits gives one-nanometre pixels; ten gives 0.0625 nm, below the helium wavelength. In the stipulated fixed-energy freely propagating beam, the latter entails transverse diffraction momenta comparable to or exceeding the available total momentum and lies outside the paraxial aperture model. Six-bit localization is less demanding, although fine detector resolution and losses remain practical constraints. This is not a universal theorem that an atom can carry at most six bits in every encoding: accessible modes, energy, aperture, measurements and success probabilities define the channel.
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