For E<0, impose decay and continuity on G=Ce−κ∣x−x′∣. Its derivative jump is −2κC, so −ℏ2(G+′−G−′)/(2m)=1 requiresThere is no nonzero free solution decaying at both infinities that can be added without spoiling the derivative condition.
G(x,x′)=κℏ2me−κ∣x−x′∣,κ=−2mE/ℏ.
The full equation rearranges to Lψ=−Uψ. Since a bound state has no incoming free wave, convolution with the decaying inverse gives ψ(x)=−m∫e−κ∣x−x′∣U(x′)ψ(x′)dx′/(κℏ2). Applying L to this identity recovers the differential equation and the decay boundary conditions.
Let b=a/2, q=2m(U0−∣E∣)/ℏ and κ=2m∣E∣/ℏ. Bound levels have −U0<E<0. Up to normalization, parity givesThe respective inverse squared normalization constants are b+sin(2qb)/(2q)+cos2(qb)/κ and b−sin(2qb)/(2q)+sin2(qb)/κ. These include both exponential tails.
ψe(x)={Acos(qx),Acos(qb)e−κ(∣x∣−b),∣x∣≤b,∣x∣>b,
ψo(x)={Asin(qx),Asgn(x)sin(qb)e−κ(∣x∣−b),∣x∣≤b,∣x∣>b.
Continuity has already been built into these forms. At b, derivative continuity requires −qsin(qb)=−κcos(qb) for even parity and qcos(qb)=−κsin(qb) for odd parity. ThusUse q/κ=U0/∣E∣−1 to obtain the two printed equations. The right side is positive, so only the corresponding allowed tangent/cotangent branches can describe a bound state; squaring without retaining this sign restriction adds spurious roots.
qtan(qb)=κor−qcot(qb)=κ.
Matching ψ and ψ′ at both walls, or propagating the pair (ψ,ψ′) through the interior by the matrix (cosζa−ζsinζasinζa/ζcosζa), givesHere ζ2=k2+2mU0/ℏ2. For real positive k, taking the modulus givesThe equal exterior velocities make this also the current transmission coefficient.
t(k)=D(k)e−ika,D(k)=cos(ζa)−i2kζk2+ζ2sin(ζa).
T=[cos2ζa+4k2ζ2(k2+ζ2)2sin2ζa]−1.
For the amplitude continue to k=iκ on the decaying physical sheet. Then ζ=q and D=cos(qa)+(κ2−q2)sin(qa)/(2κq). The double-angle identity factors its zero condition into the even and odd matching conditions κ=qtan(qb) and κ=−qcot(qb). Thus physical upper-half-plane amplitude poles are exactly the bound energies.
The literal statement for the probability requires correction. The displayed real-axis expression continued algebraically is 1/[D(k)D(−k)], and includes poles of the opposite-boundary-condition amplitude too. A concrete counterexample uses ℏ2/(2m)=1, a=2, q=1, κ=cot1 and U0=1+cot21. Its continued probability denominator vanishes at k=icot1, because D(−k)=0. But neither κ=tan1 nor κ=−cot1 holds, so E=−cot21 is not a bound energy. Keeping the amplitude and the decaying boundary condition removes this spurious identification.
Rewrite the real-energy probability as T=[1+U02sin2(ζa)/(4E(E+U0))]−1. Thus Tmax=1 at ζa=jπ, namely Ej=ℏ2j2π2/(2ma2)−U0≥0, with a strictly positive resonance energy in the ordinary scattering problem. Between resonances it is less than one and its oscillations approach one as energy increases. Generically T(0+)=0; a well tuned to a zero-energy resonance instead has T(0+)=1. The original transmission plot in S1 illustrates these maxima for a chosen well, not a universal specified depth.
On the physical sheet the bound-state amplitude poles lie at k=iκj, κj>0, and map to real negative Ej=−ℏ2κj2/(2m). The square-root map has two sheets meeting at the continuum threshold. Analytic continuation can also have virtual-state poles on the negative imaginary k axis and resonance poles in the lower half-plane; these are not normalizable bound states. In the energy plane the resonances belong to the nonphysical sheet, rather than additional negative-axis bound levels.
For the algebraically continued probability, include the mirror poles contributed by D(−k) as explained in part d; the two k signs map to the same numerical energy but need not impose the same boundary condition. A sketch must label the sheet or the amplitude being plotted, rather than treating every singularity as a bound state.
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