A neutral superfluid can select a phase of its complex order parameter, breaking a global symmetry. A spatially uniform change of that phase costs no energy. Slowly varying changes therefore produce a gapless Goldstone mode. For a dilute weakly repulsive Bose gas, the Bogoliubov quasiparticle dispersion isso at long wavelengths, with . Density and phase fluctuations are canonically coupled components of this sound branch, rather than two independent positive-frequency modes. Superfluid helium and dilute atomic condensates supply neutral examples, although the dilute-gas formula is not quantitatively valid for strongly interacting liquid helium.
In a superconductor, the pair field is charged and its phase couples to the electromagnetic gauge field. Only combinations such as are physically meaningful. The Anderson-Higgs mechanism in a superconductor produces electromagnetic screening and removes the neutral sound mode as an independent gapless charged-density oscillation. In a homogeneous three-dimensional continuum, long-range Coulomb forces give a longitudinal plasma gap, approximately at small . The static transverse response gives the Meissner effect andwhen counts superconducting electrons of effective mass . Counting pairs instead uses density , charge and mass , giving the same stiffness. The condensate amplitude may also have a gapped Higgs mode, but that amplitude oscillation is distinct from the electromagnetic Higgs mechanism. Local gauge transformations remain a redundancy; this is not spontaneous breaking of an observable local symmetry in the same sense as the neutral global phase symmetry.
A bosonic coherent state is an annihilation-operator eigenstate,It has , a selected complex amplitude, and Poisson-distributed particle number. A coherent-field condensate variational state extends this construction to a spatial field with . Evaluating a normal-ordered interacting Bose Hamiltonian in that state gives a classical-field energy functional; its variational equation is the Gross–Pitaevskii equation. This connects a macroscopic phase to interference, quantized circulation and neutral Josephson effects. A fixed-number condensate instead has vanishing one-point field expectation; off-diagonal long-range order identifies the condensate without requiring exact number fluctuations.
The BCS ground state has the pair-coherent formIt is a product of Cooper-pair pseudospin coherent states: each paired momentum sector mixes its empty and doubly occupied configurations. The anomalous pair expectation is , while an ordinary single-electron expectation vanishes by fermion parity. Pair operators are not unrestricted canonical boson operators, so this state must not be identified with a naive oscillator coherent state of individual electrons. Number projection gives a fixed-even-number description with pair correlations. Phase differences between condensates enter the Josephson effect; in a charged condensate that phase difference must be gauge invariant.
For a one-component superfluid with nonzero order-parameter magnitude on a closed loop, the phase defines a map from the loop into the circle. Its winding number isThe fundamental group means that smooth deformations preserving nonzero amplitude cannot change this integer. With superfluid velocity , it gives quantized circulation . A vortex core permits the order parameter to vanish and carries the winding; a superfluid phase slip changes a loop's winding when a core crosses it. For paired neutral fermions, the relevant condensed-object mass is the pair mass.
For charged pairs, gauge-covariant phase rigidity gives fluxoid and flux quantization in a superconductor:The magnitude of the pair flux quantum is . Magnetic flux alone approaches an integer multiple of this value when the circulating-velocity term on a bulk contour is negligible. The topological condition is not a claim that an arbitrary finite loop has exactly quantized magnetic flux independent of its screening current.
There are also momentum-space invariants, distinct from real-space vortex winding. A fully gapped two-dimensional Bogoliubov--de Gennes Hamiltonian can have a Chern number obtained from its occupied quasiparticle bands' Berry curvature. In a chiral paired model it can protect edge modes while the bulk gap and relevant symmetry class are maintained. Such an invariant can change only when those assumptions fail, for example through a bulk gap closing. A nodal d-wave state requires a different analysis; it is not automatically a fully gapped Chern superconductor.
The t-J model approximates the low-energy sector of a repulsive Hubbard model with near one electron per site. Large on-site repulsion suppresses double occupancy. Virtual hopping out of and back into that low-energy sector produces antiferromagnetic superexchange with . One conventional effective Hamiltonian iswith projected electron operator . At half filling, nearest-neighbor hopping cannot move an electron without entering a forbidden doubly occupied state, leaving the leading spin-exchange model. Doped holes can move and couple the charge dynamics to these spin correlations. Additional terms, including three-site processes at order , are omitted in this simplified Hamiltonian.
The exchange term energetically favors a nearest-neighbor spin singlet. With in the no-double-occupancy subspace, . A square-lattice pairing ansatz can therefore use bond singlets with opposite signs along the two axes. This d-wave bond order hasIt changes sign under a quarter-turn and vanishes along the zone diagonals. It is an even-parity, spin-singlet pairing pattern, not a statement of triplet pairing or necessarily broken time reversal. Phase-sensitive interference experiments distinguish this sign structure from a merely anisotropic nonnegative gap in cuprate superconductors.[ref]
Pairing symmetry and flux quantization in a tricrystal superconducting ring by C. C. Tsuei and others. 1994 phase-sensitive tricrystal test
The model captures strong local repulsion, antiferromagnetism and mobile doped carriers. Its interacting phase diagram is not solved by writing down the Hamiltonian: a mean-field d-wave ansatz is a proposed approximation, not a proof that every parameter choice has that exact ground state or a complete microscopic explanation of every high-temperature superconductor.
A SQUID converts magnetic flux into a periodic interference response of superconducting weak links. A DC SQUID has two Josephson junctions in a loop. For equal junction critical currents and negligible loop self-inductance, their Gauge-invariant Josephson phases differ by , with . Adding and maximizing over the common phase givesThus the critical current repeats for every added flux quantum. A suitable current bias and dissipative junction dynamics convert the changing critical current into an observable voltage modulation. Junction asymmetry prevents exact zero minima, and appreciable self-inductance makes the flux include the circulating current's contribution; these require a modified response model. The Jaklevic Josephson interference experiment supplies an early experimental realization of the interference principle.
An RF SQUID instead uses one junction in a loop inductively coupled to a radio-frequency resonator. In either design, a pickup coil and flux transformer can couple a small external field into the sensor, and flux feedback can keep it near a sensitive operating point over a larger measurement range. Applications include weak-field magnetometry, measurements of magnetic susceptibility and persistent currents, geophysical surveys and precision low-current detection. Gradiometers suppress common external fields, while thermal, junction and environmental noise set practical sensitivity. The instrument measures a flux-dependent electrical response; sensitivity is not established solely by the small size of .
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