Past exam of the mathematics course of the University of Cambridge 2023 iii Paper 303 1 c Solution 2026-09-28
The stationary points obeyNonzero stationary points exist whenso they first appear at the ordered-phase spinodal point . The disordered state is locally stable for and loses that stability at .
The actual phase boundary is found by requiring a nonzero stationary point to have the same free energy as . Solving and givesThe disordered state is the global minimum for , the ordered state is the global minimum for , and they coexist at equality.
Since , the order parameter jumps from zero to at coexistence. Hence this model has no continuous phase transition as the phases exchange stability, but it does have a first-order phase transition at the displayed positive value of .