Past exam of the materials science course of the University of Cambridge 2015 Paper 1 7 c Solution 2026-10-20
Orowan bypass bows a dislocation around an unshearable obstacle and leaves a loop. A dislocation line-tension estimate for a segment with tension gives the limiting shear-stress scalewhere is a free obstacle gap on the slip plane. For an FCC perfect dislocation,Using and the simple gap estimate givesConverting to tensile stress requires an orientation factor. With an explicitly assumed polycrystalline FCC Taylor factor ,The graph and spacing approximations do not justify a precise last digit. A favorably oriented single crystal with Schmid factor1/2 would instead give , around110MPa.
This is a line-tension estimate. A true slip-plane obstacle distribution, line character, logarithmic elastic corrections and precipitate size distribution are not specified. If the quoted pitch is used directly as an effective free spacing, neglecting diameter, the same simplified calculation gives and . The larger gap-corrected estimate explicitly uses the size inferred above; the tensile factor and spacing convention must not be silently treated as provided measurements.
Past exam of the materials science course of the University of Cambridge 2016 Paper 1 5 a Solution 2026-10-20
The alloy shear yield stress can be roughly times the stated pure-aluminium critical resolved shear stress. Strengthening raises the stress required for dislocation glide rather than requiring homogeneous shearing of a perfect crystal.
- Solid-solution strengthening: substitutional solutes create elastic and chemical disturbances that interact with dislocations. A moving dislocation must escape or drag these disturbances.
- Precipitation hardening: suitably spaced second-phase particles obstruct glide. Small shearable precipitates resist cutting; larger nonshearable obstacles require dislocation bowing and bypass. Particle spacing and coherency matter, so overaging can reduce strength.
- Work hardening: prior plastic deformation increases dislocation density. Intersections, junctions and forest dislocations impede subsequent glide; a common scaling is .
- Grain boundary strengthening: smaller grains shorten the distance over which dislocations can pile up and make slip transfer across differently oriented grains more difficult. In its ordinary regime, the Hall-Petch relation is .
These mechanisms can coexist. The numerical comparison is an order-of-magnitude comparison of shear strengths; it is not a conversion of the alloy's shear yield stress directly into a tensile yield stress.
Past exam of the materials science course of the University of Cambridge 2016 Paper 1 5 c Solution 2026-10-20
A second slip system begins to operate as the tensile-axis rotation makes its resolved shear stress comparable to that on the primary system. Dislocations on intersecting planes interact much more strongly, giving the transition from easy single slip to rapid work hardening. The standard geometric estimate neglects differences between the evolving critical stresses of the two systems.
The primary direction is . Single-slip shear carries the line joining the specimen ends, expressed in crystal coordinates, alongThe initial fundamental sector has . Its first reached boundary is , at , giving . At that orientation and have equal Schmid factors. Since the component perpendicular to the primary slip direction is unchanged by that shear, the length ratio follows directly:ThereforeThe corresponding logarithmic strain is . This is an ideal equal-critical-stress geometric onset estimate. Real secondary slip can start earlier or later because of latent hardening, nonuniform deformation and grip constraints; the problem supplies no hardening law that would determine that shift.[ref]
Applied Mechanics of Solids by A. F. Bower. §3.12.2, points10–12: tensile-axis rotation, secondary slip and stages of hardening
Past exam of the materials science course of the University of Cambridge 2016 Paper 1 5 d Solution 2026-10-20
The printed numerical ratios are about , not about :The qualitative contrast is nevertheless meaningful. FCC aluminium has close-packed glide planes and relatively mobile dislocations. Magnesium also has easy close-packed basal glide, although it lacks enough equivalently easy slip systems for arbitrary room-temperature polycrystal deformation.
BCC iron has no close-packed plane. Its screw-dislocation cores and lattice-friction barrier give much stronger resistance to glide; thermally activated kink motion makes the critical stress particularly temperature- and rate-sensitive. This is the relevant Peierls-stress explanation. A high polycrystal constraint factor cannot explain the supplied contrast, because the data are already critical resolved shear stresses. Neither the precise factor35 nor a universal BCC/FCC ratio follows from crystal packing alone: purity, dislocation structure, temperature and testing conditions also matter.
Past exam of the materials science course of the University of Cambridge 2016 Paper 1 7 a Solution 2026-10-20
Material creep is time-dependent permanent deformation under sustained stress. Its rate is often appreciable at a large homologous temperature , because diffusion and obstacle-escape processes become rapid. In an activated regime a useful form iswith additional elastic, geometric and temperature prefactors absorbed into for the chosen approximation. The activation energy belongs to the rate-controlling process: bulk diffusion, grain-boundary diffusion and dislocation motion need not have the same value.
- A: power-law dislocation material creep. Dislocations glide and climb around obstacles; vacancy transport enables climb and recovery. The rate is strongly stress-dependent, typically with several times greater than one. It dominates the higher-stress, hot field below the glide-strength boundary.
- B: Nabarro-Herring creep. Stress-directed vacancy diffusion through the grain interiors transfers material between differently stressed boundaries, extending grains along tension. In the simple equiaxed-grain model . It occupies the high-temperature, low-stress field.
- C: Coble creep. The analogous transport runs predominantly along grain boundaries. The characteristic scaling is , where is an effective boundary thickness. The lower activation cost of boundary diffusion makes it competitive at lower temperature than bulk-diffusion material creep.
Boundary sliding can accommodate grain-shape changes during diffusional material creep; it is not a reason to identify either diffusion field as dislocation glide. The supplied map's A/B/C placement, including the boundary between B and C, determines these assignments. Its numerical contours apply to the material state used to construct that map, not to arbitrary grain sizes.
Past exam of the materials science course of the University of Cambridge 2016 Paper 1 7 b Solution 2026-10-20
Lower the operating temperature or stress, suppress diffusion, and remove or stabilize the paths that accommodate material creep. Increasing the melting temperature can reduce at a specified operating temperature. Chemistry that reduces diffusivity or impedes dislocation climb can reduce the material creep rate; stable precipitates or dispersoids can resist glide and climb, provided they do not dissolve or coarsen rapidly in service.
Large grains reduce both Nabarro-Herring and Coble creep, according to their and dependencies. Directional solidification can reduce boundaries normal to the dominant tensile stress, while a single crystal removes grain-boundary transport and sliding from the ordinary polycrystal mechanism inventory. It does not remove bulk diffusion or dislocation material creep.
This is why room-temperature grain-refinement strengthening is not automatically a high-temperature material creep strategy: fine grains create more boundary transport paths. Any protective microstructure must remain stable at the service temperature, and the design must also avoid stress concentrations and unwanted thermal loading.
Past exam of the materials science course of the University of Cambridge 2016 Paper 1 7 c Solution Created 2026-10-20 Updated 2026-10-20
At height above the free lower end, a uniform vertical filament carries the weight of length . With cross-sectional area ,The maximum stress is at the top and is independent of diameter. The diameter cancels because both mass and load-bearing area scale with . Neglecting self-heating gradients, evaporation and initial fabrication stress, this top point sets the first creep-strain limit.
For a clearly labelled external reference estimate, take . Then ; the area is and the total suspended mass is about . The density is independently tabulated, not invented as a supplied 2016 value.[ref]
Atomic and nuclear properties of tungsten by the Particle Data Group. 2009 table, density entry
Use the original map's top temperature axis at and its right-hand tensile-stress axis, so no uncertain shear-stress conversion or additional shear modulus is required. The point lies in C, between the and contours, nearer . A logarithmic interpolation of the scanned contours gives about , with only graphical precision. Thusor of order three months in this steady-rate, reference-density map estimate. Reading only the bracketing contours gives the appropriately broad interval to ; the graph does not support an exact service-life number.
For the exact prescribed input, the answer remainsThis estimate uses the cited reference density and the grain-size assumptions of the supplied map. Thermal expansion lowers density, and an evolved area or tertiary material creep changes the rate; a steady initial-rate estimate is not a guaranteed lifetime. In particular, a different filament grain size could require a different map. Other failure mechanisms could shorten useful life.
Past exam of the materials science course of the University of Cambridge 2017 Paper 1 2 c Solution 2026-10-20
For quartz, and . With , the load and stress are and . ThereforeAs a check, and give the same result. This is the ideal maximum open-circuit change on applying the load. Input capacitance reduces it to , while finite leakage makes it decay: it is not a guaranteed permanent DC output.
Past exam of the materials science course of the University of Cambridge 2017 Paper 1 2 d Solution 2026-10-20
The sensor must survive the stress range and repeated loading without fracture, fatigue or excessive mechanical compliance. The tensor character of the piezoelectric coefficient makes crystal orientation important; a ceramic's poling quality and domain stability also matter. Compare linearity, hysteresis, reproducibility, aging and the usable frequency bandwidth, including resonance and dynamic response.
Electrical design is equally important: leakage resistance and readout input impedance determine low-frequency loss, and cable/input capacitance loads a voltage output. A charge amplifier may favour a different material ranking from a passive open-circuit voltage measurement. temperature changes can alter the coefficients, produce a pyroelectric signal in a polar material and depole a ferroelectric near its transition. Humidity, electrode bonding, electrical breakdown, manufacturability, cost and environmental constraints such as lead content also affect a practical choice. Calibration should separate applied stress from temperature drift and readout loading.
Past exam of the materials science course of the University of Cambridge 2017 Paper 1 4 b Solution 2026-10-20
At fixed transformed volume, an equilibrium solid-state precipitate seeks a low total free energy, including the orientation-dependent interfacial energy and elastic strain energy associated with misfit and applied stress. Low-energy interface orientations occupy large faces. The Wulff construction captures surface-energy anisotropy when strain and other contributions can be neglected; a solid-state precipitate generally also pays coherency strain energy, and its optimum shape can change with size.
During formation, growth kinetics and diffusion may prevent the equilibrium shape being reached. Coherent, semicoherent and incoherent interfaces have different bonding and defect structures, so their energies and attachment rates differ. The disc shape is consistent with much cheaper broad faces than edges, but morphology alone does not uniquely measure the energies or prove equilibrium.
Past exam of the materials science course of the University of Cambridge 2017 Paper 1 6 b Solution 2026-10-20
The maximum recoverable elastic energy per initial volume is the area under the linear stress–strain curve up to failure:Using gives , so maximize for the fixed geometry. has units of energy per crack area, while has energy per specimen volume; the geometric factor supplies the necessary inverse length. The cancellation of is why the strain-maximizing index from (a) is not appropriate here.
Past exam of the materials science course of the University of Cambridge 2017 Paper 1 7 c Solution 2026-10-20
The nickel-rich matrix is a disordered substitutional solid solution on a face-centered cubic lattice. The ordered phase has the L12 structure, approximately : aluminium occupies cube corners and nickel occupies face centres. Its occupied-site geometry is often called ordered FCC, but its chemically labelled Bravais lattice is primitive cubic, with a four-atom basis. A face-centre translation exchanges chemical sublattices and is not a symmetry of the ordered crystal.
Each Al atom has twelve nearest-neighbour Ni atoms at Euclidean distance . Each Ni atom has twelve nearest neighbours too, but these are four Al and eight Ni. The chemical distinction matters for slip. In disordered , the shortest perfect Burgers vector isFor the ordered primitive cubic translation lattice, the shortest order-preserving perfect vector isThis does not imply that slip must dominate. A vector must lie in a favourable glide plane and have an accessible core structure and activation stress. Matrix dislocations commonly glide on systems. A single passage through leaves an antiphase boundary; a second matching passage restores order, giving total vector . Such a superdislocation has a longer total vector than , yet its constituent dislocations can move on the favourable close-packed planes and interact with the matrix. Paired motion balances line and antiphase-boundary energies, so the shortest abstract lattice translation alone does not select the active slip system.[ref]
Nickel based superalloy: dislocation structure by H. K. D. H. Bhadeshia. explanation of matrix translations, ordered-phase antiphase boundaries and paired dislocations
Past exam of the materials science course of the University of Cambridge 2017 Paper 1 7 d Solution 2026-10-20
The main strengthening architecture is a high volume fraction of fine, thermally stable ordered gamma prime phase precipitates in the ductile nickel-rich matrix. Their nearly matching crystal parameters allow coherent crystal interfaces, but coherence does not make them transparent to a moving dislocation: cutting disrupts chemical order and costs antiphase-boundary energy. Pairing of cutting dislocations and their interactions with narrow matrix channels raise the stress needed for deformation. For particles that are bypassed, bowing and high-temperature climb are also impeded by the precipitate spacing and interface dislocation structures.
coherency strain and differences in elastic response provide additional obstacles. Refractory substitutional solutes contribute solid-solution strengthening and can slow diffusion-controlled deformation. Single-crystal manufacture suppresses grain-boundary creep and grain-boundary cavitation. Together these mechanisms permit useful strength at temperatures where an unstrengthened nickel matrix would deform much faster. Protective oxide scales and coatings preserve load-bearing material against environmental attack; they complement, rather than replace, the internal strengthening mechanisms.
A concrete microscopic observation is the paired dislocation loops around fine precipitates in the Cambridge C263 creep micrograph: the observed defect structure supports the importance of precipitate–dislocation interactions, though one image does not by itself separate every strengthening contribution.[ref]
Nickel based superalloy: dislocation structure by H. K. D. H. Bhadeshia. creep-tested C263 micrograph and accompanying paired-loop interpretation
In-situ diffraction during stress-jump tests of a rafted AM1 single crystal also resolves evolving load partition and deformation in matrix channels, demonstrating why channel width and interface interactions matter.[ref]Dislocation Densities and Velocities within the γ Channels of an SX Superalloy during In Situ High-Temperature Creep Tests by T. Schenk and others. abstract, Sections 2–4: transmission diffraction, loading transients and channel-deformation analysis
Long exposure can coarsen or change the precipitate morphology and alter channel widths, so high strength is conditional on temperature, time and microstructural stability. Past exam of the materials science course of the University of Cambridge 2018 Paper 1 2 a Solution 2026-10-20
The voltage is a mechanically mediated effect: nickel magnetostriction strains the bonded central layer, and the direct piezoelectric effect converts stress into electrical displacement. An estimate of requires a strain-transfer and electrical-boundary assumption.
Let run along the applied field and through the layers. Assume saturated, approximately volume-preserving isotropic nickel magnetostriction, perfect bonding, mechanically dominant nickel faces and a high-impedance voltage measurement. Relative to the random-domain state,Treat the thin central layer as in plane stress, with these imposed in-plane strains, negligible converse-effect backreaction and isotropic elastic constants. ThensoFor a transversely polarized layer,The open-circuit increment has , and . HenceThe observed voltage magnitude does not specify the sign without electrode polarity and poling direction. A one-dimensional approximation retaining only axial stress instead gives . That is a different mechanical model. Nickel stiffness and thickness, interface compliance, central-layer tensor coefficients and electrical loading are not specified, so the experiment does not determine a unique exact intrinsic coefficient without these assumptions.
Past exam of the materials science course of the University of Cambridge 2018 Paper 1 2 b i Solution 2026-10-20
For a conventional initially random, untextured piezoceramic, orientational averaging suppresses the macroscopic linear response. Electrical poling of ferroelectric domains is the usual way to generate a lasting net response. Under that conventional preparation assumption, a ferroelectric constituent is the expected route.
However, the word polycrystalline alone does not logically require ferroelectricity. A deliberately textured aggregate of nonswitchable piezoelectric grains can have a nonzero effective tensor if their orientations and polar directions do not cancel. Ferroelectricity means electrically switchable spontaneous polarization, whereas piezoelectricity means linear stress–charge coupling. Thus the unconditional statement that every polycrystalline piezoelectric must be ferroelectric is too strong.
Assume that the transverse field is large enough to saturate through the thickness despite demagnetizing effects, and retain the thin-layer plane-stress and open-circuit assumptions from part(a). The two imposed in-plane strains now becomeTheir sum is , whereas it was for longitudinal saturation. The in-plane stress sum, and hence the induced open-circuit voltage, is multiplied by :Thus the magnitude is about with the opposite polarity, under this model. The larger demagnetizing field for an out-of-plane direction means the same external field magnitude might not produce the same degree of saturation. Changes in thickness constraint or strain transfer would also modify the estimate.
Reversing a saturating longitudinal field gives approximately the same strain and the same voltage polarity relative to the original unmagnetized reference. In the isotropic orientational model,It is unchanged under . Both positive and negative longitudinal saturation therefore contract the negative-magnetostriction nickel in the same axial direction. The resulting stress on the piezoelectric layer has the same sign.
Past exam of the materials science course of the University of Cambridge 2018 Paper 1 2 c i Solution 2026-10-20
If removal restores the original random-domain magnetic state, the magnetostrictive strain and induced voltage return toward their original values. Elastic strain transfer then relaxes the stress on the central layer.
A ferromagnetic nickel layer can retain remanent magnetization and an altered domain population, so removing the external field does not guarantee removal of all magnetostriction. The electrical time response also depends on leakage and the input impedance of the voltmeter: an open-circuit strain-induced voltage can decay through a finite resistance even while some strain remains. The final observed voltage is therefore history- and circuit-dependent.
Past exam of the materials science course of the University of Cambridge 2018 Paper 1 5 a Solution 2026-10-20
Assume a thin cylindrical wall, uniform internal pressure and closed ends carrying the pressure load. The radial stress is small compared with the membrane stresses when .
For an end cap, the outward pressure force is . The wall's axial tensile force is . Equilibrium therefore givesFor a longitudinally split half-cylinder of length , pressure has resultant across the projected rectangular area. Two cut wall sections each carry , soThus hoop stress is twice the closed-end axial stress in this model. An open-ended tube without an external end load does not acquire the same pressure-induced axial membrane stress.
Original thin-pipe force balances and schematic crack-tip stress regularization by plastic deformation; the plastic-zone curve is qualitative
. Details. Past exam of the materials science course of the University of Cambridge 2018 Paper 1 5 b Solution 2026-10-20
Linear elastic fracture mechanics predicts a near-tip tensile stress varying approximately asA ductile material yields near the tip before that mathematical singularity can be realized. Plastic deformation blunts the crack and redistributes stress over a finite process zone, as shown in the right-hand diagram. Constraint can sustain stresses above the uniaxial yield stress, so the schematic plateau should not be interpreted as a universal exactly- cap.
A useful process-zone scale is with a geometry- and constraint-dependent coefficient. Advancing the crack then requires energy for plastic deformation and other irreversible processes as well as forming new surfaces. Consequently the critical energy release rate is much larger than the reversible surface-energy term of a perfectly brittle idealization:In a small-scale-yielding plane-strain description, with . Large-scale yielding requires an elastic-plastic measure rather than treating a linear-elastic stress-intensity criterion as exact. The increased dissipation and crack-tip blunting explain the larger energy requirement.
