If you adda bit of impurities to certain materials, at low temperatures of a few Kelvin their resistivity actually starts increasing if you go below a certain critical temperature.
Most notable example: gallium arsenide, see also: gallium arsenide vs silicon.
An important class of semiconductors, e.g. there is a dedicated III-V lab at: École Polytechnique: www.3-5lab.fr/contactus.php
Experiments:
- "An introduction to superconductivity" by Alfred Leitner originally published in 1965, source: www.alfredleitner.com/
- Isotope effect on the critical temperature. hyperphysics.phy-astr.gsu.edu/hbase/Solids/coop.html mentions that:
If electrical conduction in mercury were purely electronic, there should be no dependence upon the nuclear masses. This dependence of the critical temperature for superconductivity upon isotopic mass was the first direct evidence for interaction between the electrons and the lattice. This supported the BCS Theory of lattice coupling of electron pairs.
20. Fermi gases, BEC-BCS crossover by Wolfgang Ketterle (2014)
Source. Part of the "Atomic and Optical Physics" series, uploaded by MIT OpenCourseWare.Actually goes into the equations.
Notably, youtu.be/O_zjGYvP4Ps?t=3278 describes extremely briefly an experimental setup that more directly observes pair condensation.
The Map of Superconductivity by Domain of Science
. Source. Lacking as usual, but this one is particularly good as the author used to work on the area as he mentions in the video.Lecture notes:
Transition into superconductivity can be seen as a phase transition, which happens to be a second-order phase transition.
Upside: superconducting above 92K, which is above the 77K of liquid nitrogen, and therefore much much cheaper to obtain and maintain than liquid helium.
Downside: it is brittle, so how do you make wires out of it? Still, can already be used in certain circuits, e.g. high temperature SQUID devices.
Discovered in 1988, the first high-temperature superconductor which did not contain a rare-earth element.
Main theory to explain Type I superconductors very successfully.
TODO can someone please just give the final predictions of BCS, and how they compare to experiments, first of all? Then derive them.
High level concepts:
- the wave functions of pairs of electrons (fermions) get together to form bosons. This is a phase transition effect, thus the specific sudden transition temperature.
- the pairs form a Bose-Einstein condensate
- once this new state is reached, all pairs are somehow entangled into one big wave function, and you so individual lattice imperfections can't move just one single electron off trajectory and make it lose energy
The inaugural that predicted the Josephson effect.
Published on Physics Letters, then a new journal, before they split into Physics Letters A and Physics Letters B. True Genius: The Life and Science of John Bardeen mentions that this choice was made rather than the more prestigious Physical Review Letters because they were not yet so confident about the results.
Probable observation of the Josephson superconducting tunneling effect by 
Ciro Santilli 37 Updated 2025-07-16
Ciro Santilli 37 Updated 2025-07-16Paper by Philip W. Anderson and John M. Rowell that first (?) experimentally observed the Josephson effect.
Paywalled by the American Physical Society as of 2023 at: journals.aps.org/prl/abstract/10.1103/PhysRevLett.10.230
They used tin-oxide-lead tunnel at 1.5 K. TODO oxide of what? Why two different metals? They say that both films are 200 nm thick, so maybe it is:
-----+------+------+-----
... Sn | SnO2 | PbO2 | Pb ...
-----+------+------------
100nm 100nmA reconstruction of their circuit in Ciro's ASCII art circuit diagram notation TODO:
DC---R_10---X---GThere are not details of the physical construction of course. Reproducibility lol.
It is called "AC effect" because when we apply a DC voltage, it produces an alternating current on the device.
By looking at the Josephson equations, we see that a positive constant, then just increases linearly without bound.
Wikipedia mentions that this frequency is , so it is very very high, so we are not able to view individual points of the sine curve separately with our instruments.
Also it is likely not going to be very useful for many practical applications in this mode.
An I-V curve can also be seen at: Figure "Electron microscope image of a Josephson junction its I-V curve".
I-V curve of the AC Josephson effect
. Source. Voltage is horizontal, current vertical. The vertical bar in the middle is the effect of interest: the current is going up and down very quickly between , the Josephson current of the device. Because it is too quick for the oscilloscope, we just see a solid vertical bar.
Superconducting Transition of Josephson junction by Christina Wicker (2016)
Source. Amazing video that presumably shows the screen of a digital oscilloscope doing a voltage sweep as temperature is reduced and superconductivity is reached.
I-V curve of a superconducting tunnel junction
. So it appears that there is a zero current between and . Why doesn't it show up on the oscilloscope sweeps, e.g. Video 1. "Superconducting Transition of Josephson junction by Christina Wicker (2016)"? Pinned article: Introduction to the OurBigBook Project
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