Ciro Santilli @cirosantilli 37

Theory that describes electrons and photons really well, and as Feynman puts it "accounts very precisely for all physical phenomena we have ever observed, except for gravity and nuclear physics" ("including the laughter of the crowd" ;-)).

Learning it is one of Ciro Santilli's main intellectual fetishes.

While Ciro acknowledges that QED is intrinsically challenging due to the wide range or requirements (quantum mechanics, special relativity and electromagnetism), Ciro feels that there is a glaring gap in this moneyless market for a learning material that follows the Middle Way as mentioned at: the missing link between basic and advanced. Richard Feynman Quantum Electrodynamics Lecture at University of Auckland (1979) is one of the best attempts so far, but it falls a bit too close to the superficial side of things, if only Feynman hadn't assumed that the audience doesn't know any mathematics...

The funny thing is that when Ciro Santilli's mother retired, learning it (or as she put it: "how photons and electrons interact") was also one of her retirement plans. She is a pharmacist by training, and doesn't know much mathematics, and her English was somewhat limited. Oh, she also wanted to learn how photosynthesis works (possibly not fully understood by science as that time, 2020). Ambitious old lady!!!

Experiments: quantum electrodynamics experiments.

Combines special relativity with more classical quantum mechanics, but further generalizing the Dirac equation, which also does that: Dirac equation vs quantum electrodynamics. The name "relativistic" likely doesn't need to appear on the title of QED because Maxwell's equations require special relativity, so just having "electro-" in the title is enough.

Before QED, the most advanced theory was that of the Dirac equation, which was already relativistic but TODO what was missing there exactly?

As summarized at: youtube.com/watch?v=_AZdvtf6hPU?t=305 Quantum Field Theory lecture at the African Summer Theory Institute 1 of 4 by Anthony Zee (2004):

That video also mentions the interesting idea that:Therefore, for small timescales, energy can vary a lot. But mass is equivalent to energy. Therefore, for small time scale, particles can appear and disappear wildly.

QED is the first quantum field theory fully developed. That framework was later extended to also include the weak interaction and strong interaction. As a result, it is perhaps easier to just Google for "Quantum Field Theory" if you want to learn QED, since QFT is more general and has more resources available generally.

Like in more general quantum field theory, there is on field for each particle type. In quantum field theory, there are only two fields to worry about:

Bagic jump between orbitals in the Bohr model. Analogous to the later wave function collapse in the Schrödinger equation.

Causality and quantum jumps are incompatible.

This Heisenberg's breakthrough paper on matrix mechanics which later led to the Schrödinger equation, see also: history of quantum mechanics.

Published on the Zeitschrift für Physik volume 33 page pages 879-893, link.springer.com/article/10.1007%2FBF01328377

Modern overview: www.mat.unimi.it/users/galgani/arch/heisenberg25amer_j_phys.pdf

Quantum mechanics is quite a broad term. Perhaps it is best to start approaching it from the division into:

Key experiments that could not work without quantum mechanics: Section "Quantum mechanics experiment".

Mathematics: there are a few models of increasing precision which could all be called "quantum mechanics":

Ciro Santilli feels that the largest technological revolutions since the 1950's have been quantum related, and will continue to be for a while, from deeper understanding of chemistry and materials to quantum computing, understanding and controlling quantum systems is where the most interesting frontier of technology lies.

Quantum numbers appear directly in the Schrödinger equation solution for the hydrogen atom.

However, it very cool that they are actually discovered before the Schrödinger equation, and are present in the Bohr model (principal quantum number) and the Bohr-Sommerfeld model (azimuthal quantum number and magnetic quantum number) of the atom. This must be because they observed direct effects of those numbers in some experiments. TODO which experiments.

E.g. The Quantum Story by Jim Baggott (2011) page 34 mentions:This refers to forbidden mechanism. TODO concrete example, ideally the first one to be noticed. How can you notice this if the energy depends only on the principal quantum number?

Appears in the Schrödinger equation.

Equals the quantum of angular momentum in the Bohr model.

The partial differential equation of non-relativistic quantum mechanics.

Experiments explained:

Experiments not explained: those that the Dirac equation explains like:

To get some intuition on the equation on the consequences of the equation, have a look at:

The easiest to understand case of the equation which you must have in mind initially that of the Schrödinger equation for a free one dimensional particle.

Then, with that in mind, the general form of the Schrödinger equation is:where:

The $\overrightarrow{x}$ argument of $\psi$ could be anything, e.g.:Note however that there is always a single magical $t$ time variable. This is needed in particular because there is a time partial derivative in the equation, so there must be a corresponding time variable in the function. This makes the equation explicitly non-relativistic.

The general Schrödinger equation can be broken up into a trivial time-dependent and a time-independent Schrödinger equation by separation of variables. So in practice, all we need to solve is the slightly simpler time-independent Schrödinger equation, and the full equation comes out as a result.

Existence and uniqueness: mathoverflow.net/questions/212913/existence-and-uniqueness-for-two-dimensional-time-dependent-schr%C3%B6dinger-equation

We select for the general Equation "Schrodinger equation":giving the full explicit partial differential equation:

The corresponding time-independent Schrödinger equation for this equation is:

Technique to solve partial differential equations

Naturally leads to the Fourier series, see: solving partial differential equations with the Fourier series, and to other analogous expansions:

One notable application is the solution of the Schrödinger equation via the time-independent Schrödinger equation.

Bibliography:

Before reading any further, you must understand heat equation solution with Fourier series, which uses separation of variables.

Once that example is clear, we see that the exact same separation of variables can be done to the Schrödinger equation. If we name the constant of the separation of variables $E$ for energy, we get:

Because the time part of the equation is always the same and always trivial to solve, all we have to do to actually solve the Schrodinger equation is to solve the time independent one, and then we can construct the full solution trivially.

Once we've solved the time-independent part for each possible $E$, we can construct a solution exactly as we did in heat equation solution with Fourier series: we make a weighted sum over all possible $E$ to match the initial condition, which is analogous to the Fourier series in the case of the heat equation to reach a final full solution:

The fact that this approximation of the initial condition is always possible from is mathematically proven by some version of the spectral theorem based on the fact that The Schrodinger equation Hamiltonian has to be Hermitian and therefore behaves nicely.

It is interesting to note that solving the time-independent Schrodinger equation can also be seen exactly as an eigenvalue equation where:The only difference from usual matrix eigenvectors is that we are now dealing with an infinite dimensional vector space.

Furthermore:

Bibliography:

A single line in the emission spectrum.

So precise, so discrete, which makes no sense in classical mechanics!

Has been the leading motivation of the development of quantum mechanics, all the way from the:

Spin is one of the defining properties of elementary particles, i.e. number that describes how an elementary particle behaves, much like electric charge and mass.

Possible values are half integer numbers: 0, 1/2, 1, 3/2, and so on.

The approach shown in this section: Section "Spin comes naturally when adding relativity to quantum mechanics" shows what the spin number actually means in general. As shown there, the spin number it is a direct consequence of having the laws of nature be Lorentz invariant. Different spin numbers are just different ways in which this can be achieved as per different Representation of the Lorentz group.

Video 1. "Quantum Mechanics 9a - Photon Spin and Schrodinger's Cat I by ViaScience (2013)" explains nicely how:

Do electrons spontaneously jump from high orbitals to lower ones emitting photons?

Explaining this was was one of the key initial achievements of the Dirac equation.

Yes, but this is not predicted by the Schrödinger equation, you need to go to the Dirac equation.

A critical application of this phenomena is laser.

See also:

In many important applications, what you have to solve is not just a single partial differential equation, but multiple partial differential equations coupled to each other. This is the case for many key PDEs including:

The Schrödinger equation Hamiltonian has to be a Hermitian so we will have only positive energies I think: quantumcomputing.stackexchange.com/questions/12113/why-does-a-hamiltonian-have-to-be-hermitian

The time-independent Schrödinger equation is a variant of the Schrödinger equation defined as:

So we see that for any Schrödinger equation, which is fully defined by the Hamiltonian $\hat{H}$, there is a corresponding time-independent Schrödinger equation, which is also uniquely defined by the same Hamiltonian.

The cool thing about the Time-independent Schrödinger equation is that we can always reduce solving the full Schrödinger equation to solving this slightly simpler time-independent version, as described at: Section "Solving the Schrodinger equation with the time-independent Schrödinger equation".

Because this method is fully general, and it simplifies the initial time-dependent problem to a time independent one, it is the approach that we will always take when solving the Schrodinger equation, see e.g. quantum harmonic oscillator.