Ciro Santilli @cirosantilli 34

In simple terms, if you believe in the Schrödinger equation and its modern probabilistic interpretation as described in the Schrödinger picture, then at first it seem that there is no strict causality to the outcome of experiments.

People have then tried to recover that by assuming that there is some inner sate beyond the Schrödinger equation, but these ideas are refuted by Bell test experiments, unless we give up the principle of locality, which feels more important, especially in special relativity, where faster-than-light implies time travel, which breaks causality even more dramatically.

The de Broglie-Bohm theory is a deterministic but non-local formulation of quantum mechanics.

Proof that the probability 1 is conserved by the time evolution:

It can be derived directly from the Schrödinger equation.

Bibliography:

The Klein-Gordon equation directly uses a more naive relativistic energy guess of $p^2+m^2$ squared.

But since this is quantum mechanics, we feel like making $p$ into the "momentum operator", just like in the Schrödinger equation.

But we don't really know how to apply the momentum operator twice, because it is a gradient, so the first application goes from a scalar field to the vector field, and the second one...

So we just cheat and try to use the laplace operator instead because there's some squares on it:

But then, we have to avoid taking the square root to reach a first derivative in time, because we don't know how to take the square root of that operator expression.

So the Klein-Gordon equation just takes the approach of using this squared Hamiltonian instead.

Since it is a Hamiltonian, and comparing it to the Schrödinger equation which looks like:taking the Hamiltonian twice leads to:

We can contrast this with the Dirac equation, which instead attempts to explicitly construct an operator which squared coincides with the relativistic formula: derivation of the Dirac equation.

Adds special relativity to the Schrödinger equation, and the following conclusions come basically as a direct consequence of this!

Experiments explained:

Experiments not explained: those that quantum electrodynamics explains like:See also: Dirac equation vs quantum electrodynamics.

The Dirac equation is a set of 4 partial differential equations on 4 complex valued wave functions. The full explicit form in Planck units is shown e.g. in Video 1. "Quantum Mechanics 12a - Dirac Equation I by ViaScience (2015)" at youtu.be/OCuaBmAzqek?t=1010:Then as done at physics.stackexchange.com/questions/32422/qm-without-complex-numbers/557600#557600 from why are complex numbers used in the Schrodinger equation?, we could further split those equations up into a system of 8 equations on 8 real-valued functions.

Appears directly on Schrödinger equation! And in particular in the time-independent Schrödinger equation.

The discovery of the photon was one of the major initiators of quantum mechanics.

Light was very well known to be a wave through diffraction experiments. So how could it also be a particle???

This was a key development for people to eventually notice that the electron is also a wave.

This process "started" in 1900 with Planck's law which was based on discrete energy packets being exchanged as exposed at On the Theory of the Energy Distribution Law of the Normal Spectrum by Max Planck (1900).

This ideas was reinforced by Einstein's explanation of the photoelectric effect in 1905 in terms of photon.

In the next big development was the Bohr model in 1913, which supposed non-classical physics new quantization rules for the electron which explained the hydrogen emission spectrum. The quantization rule used made use of the Planck constant, and so served an initial link between the emerging quantized nature of light, and that of the electron.

The final phase started in 1923, when Louis de Broglie proposed that in analogy to photons, electrons might also be waves, a statement made more precise through the de Broglie relations.

This event opened the floodgates, and soon matrix mechanics was published in quantum mechanical re-interpretation of kinematic and mechanical relations by Heisenberg (1925), as the first coherent formulation of quantum mechanics.

It was followed by the Schrödinger equation in 1926, which proposed an equivalent partial differential equation formulation to matrix mechanics, a mathematical formulation that was more familiar to physicists than the matrix ideas of Heisenberg.

Inward Bound by Abraham Pais (1988) summarizes his views of the main developments of the subjectit:

Bibliography:

Allow us to determine with good approximation in a multi-electron atom which electron configuration have more energy. It is a bit like the Aufbau principle, but at a finer resolution.

Note that this is not trivial since there is no explicit solution to the Schrödinger equation for multi-electron atoms like there is for hydrogen.

For example, consider carbon which has electron configuration 1s2 2s2 2p2.

If we were to populate the 3 p-orbitals with two electrons with spins either up or down, which has more energy? E.g. of the following two:

The majority likely comes from physics:

A relativistic version of the Schrödinger equation.

Correctly describes spin 0 particles.

The most memorable version of the equation can be written as shown at Section "Klein-Gordon equation in Einstein notation" with Einstein notation and Planck units:

Has some issues which are solved by the Dirac equation:

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Originally it was likely created to study constrained mechanical systems where you want to use some "custom convenient" variables to parametrize things instead of global x, y, z. Classical examples that you must have in mind include:

When doing lagrangian mechanics, we just lump together all generalized coordinates into a single vector $\overrightarrow{q}(t):\mathbb{R}\to {\mathbb{R}}^n$ that maps time to the full state:where each component can be anything, either the x/y/z coordinates relative to the ground of different particles, or angles, or nay other crazy thing we want.

The Lagrangian is a function ${\mathbb{R}}^n\times {\mathbb{R}}^n\times \mathbb{R}\to \mathbb{R}$ that maps:to a real number.

Then, the stationary action principle says that the actual path taken obeys the Euler-Lagrange equation:This produces a system of partial differential equations with:

The mixture of so many derivatives is a bit mind mending, so we can clarify them a bit further. At:the $q_i$ is just identifying which argument of the Lagrangian we are differentiating by: the i-th according to the order of our definition of the Lagrangian. It is not the actual function, just a mnemonic.

Then at:

However, people later noticed that the Lagrangian had some nice properties related to Lie group continuous symmetries.

Basically it seems that the easiest way to come up with new quantum field theory models is to first find the Lagrangian, and then derive the equations of motion from them.

For every continuous symmetry in the system (modelled by a Lie group), there is a corresponding conservation law: local symmetries of the Lagrangian imply conserved currents.
Genius: Richard Feynman and Modern Physics by James Gleick (1994) chapter "The Best Path" mentions that Richard Feynman didn't like the Lagrangian mechanics approach when he started university at MIT, because he felt it was too magical. The reason is that the Lagrangian approach basically starts from the principle that "nature minimizes the action across time globally". This implies that things that will happen in the future are also taken into consideration when deciding what has to happen before them! Much like the lifeguard in the lifegard problem making global decisions about the future. However, chapter "Least Action in Quantum Mechanics" comments that Feynman later notice that this was indeed necessary while developping Wheeler-Feynman absorber theory into quantum electrodynamics, because they felt that it would make more sense to consider things that way while playing with ideas such as positrons are electrons travelling back in time. This is in contrast with Hamiltonian mechanics, where the idea of time moving foward is more directly present, e.g. as in the Schrödinger equation.

Furthermore, given the symmetry, we can calculate the derived conservation law, and vice versa.

And partly due to the above observations, it was noticed that the easiest way to describe the fundamental laws of particle physics and make calculations with them is to first formulate their Lagrangian somehow: why do symmetries such as SU(3), SU(2) and U(1) matter in particle physics?s.

TODO advantages:

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Published by Werner Heisenberg in 1925-07-25 as quantum mechanical re-interpretation of kinematic and mechanical relations by Heisenberg (1925), it offered the first general formulation of quantum mechanics.

It is apparently more closely related to the ladder operator method, which is a more algebraic than the more analytical Schrödinger equation.

It appears that this formulation makes the importance of the Poisson bracket clear, and explains why physicists are so obsessed with talking about position and momentum space. This point of view also apparently makes it clearer that quantum mechanics can be seen as a generalization of classical mechanics through the Hamiltonian.

QED and the men who made it: Dyson, Feynman, Schwinger, and Tomonaga by Silvan Schweber (1994) mentions however that relativistic quantum mechanics broke that analogy, because some 2x2 matrix had a different form, TODO find that again.

Inward Bound by Abraham Pais (1988) chapter 12 "Quantum mechanics, an essay" part (c) "A chronology" has some ultra brief, but worthwhile mentions of matrix mechanics and the commutator.

The first quantum mechanics theories developed.

Their most popular formulation has been the Schrödinger equation.

Currently an informal name for the Standard Model

Chronological outline of the key theories:

Proportionality factor in the Planck-Einstein relation between light energy and frequency.

And analogously for matter, appears in the de Broglie relations relating momentum and frequency. Also appears in the Schrödinger equation, basically as a consequence/cause of the de Broglie relations most likely.

Intuitively, the Planck constant determines at what length scale do quantum effects start to show up for a given energy scale. It is because the Plank constant is very small that we don't perceive quantum effects on everyday energy/length/time scales. On the ${\lim }_{h\to 0}$, quantum mechanics disappears entirely.

A very direct way of thinking about it is to think about what would happen in a double-slit experiment. TODO think more clearly what happens there.

Defined exactly in the 2019 redefinition of the SI base units to:

Used to explain the black-body radiation experiment.

Published as: On the Theory of the Energy Distribution Law of the Normal Spectrum by Max Planck (1900).

The Quantum Story by Jim Baggott (2011) page 9 mentions that Planck apparently immediately recognized that Planck constant was a new fundamental physical constant, and could have potential applications in the definition of the system of units (TODO where was that published):This was a visionary insight, and was finally realized in the 2019 redefinition of the SI base units.

TODO how can it be derived from theoretical principles alone? There is one derivation at; en.wikipedia.org/wiki/Planck%27s_law#Derivation but it does not seem to mention the Schrödinger equation at all.

In this solution of the Schrödinger equation, by the uncertainty principle, position is completely unknown (the particle could be anywhere in space), and momentum (and therefore, energy) is perfectly known.

The plane wave function appears for example in the solution of the Schrödinger equation for a free one dimensional particle. This makes sense, because when solving with the time-independent Schrödinger equation, we do separation of variable on fixed energy levels explicitly, and the plane wave solutions are exactly fixed energy level ones.

This is a quick tutorial on how a quantum computer programmer thinks about how a quantum computer works. If you know:a concrete and precise hello world operation can be understood in 30 minutes.

Although there are several types of quantum computer under development, there exists a single high level model that represents what most of those computers can do, and we are going to explain that model here. This model is the is the digital quantum computer model, which uses a quantum circuit, that is made up of many quantum gates.

Beyond that basic model, programmers only may have to consider the imperfections of their hardware, but the starting point will almost always be this basic model, and tooling that automates mapping the high level model to real hardware considering those imperfections (i.e. quantum compilers) is already getting better and better.

This model is very simple to understand, being only marginally more complex than that of a classical computer, see also: quantumcomputing.stackexchange.com/questions/6639/is-my-background-sufficient-to-start-quantum-computing/14317#14317

The situation of quantum computers today in the 2020's is somewhat analogous to that of the early days of classical circuits and computers in the 1950's and 1960's, before CPU came along and software ate the world. Even though the exact physics of a classical computer might be hard to understand and vary across different types of integrated circuits, those early hardware pioneers (and to this day modern CPU designers), can usefully view circuits from a higher level point of view, thinking only about concepts such as:as modelled at the register transfer level, and only in a separate compilation step translated into actual chips. This high level understanding of how a classical computer works is what we can call "the programmer's model of a classical computer". So we are now going to describe the quantum analogue of it.

The way quantum programmers think about a quantum computer in order to program can be described as follows:

To operate a quantum computer, you follow the step of operation of a quantum computer:

Each time you do this, you are literally conducting a physical experiment of the specific physical implementation of the computer:and each run as the above can is simply called "an experiment" or "a measurement".

The output comes out "instantly" in the sense that it is physically impossible to observe any intermediate state of the system, i.e. there are no clocks like in classical computers, further discussion at: quantum circuits vs classical circuits. Setting up, running the experiment and taking the does take some time however, and this is important because you have to run the same experiment multiple times because results are probabilistic as mentioned below.

Unlike in a classical computer, the output of a quantum computer is not deterministic however.

But the each output is not equally likely either, otherwise the computer would be useless except as random number generator!

This is because the probabilities of each output for a given input depends on the program (unitary matrix) it went through.

Therefore, what we have to do is to design the quantum circuit in a way that the right or better answers will come out more likely than the bad answers.

We then calculate the error bound for our circuit based on its design, and then determine how many times we have to run the experiment to reach the desired accuracy.

The probability of each output of a quantum computer is derived from the input and the circuit as follows.

First we take the classic input vector of dimension N of 0's and 1's and convert it to a "quantum state vector" $\overrightarrow{q_{in}}$ of dimension $2^n$:

We are after all going to multiply it by the program matrix, as you would expect, and that has dimension $2^n\times 2^n$!

Note that this initial transformation also transforms the discrete zeroes and ones into complex numbers.

For example, in a 3 qubit computer, the quantum state vector has dimension $2^3=8$ and the following shows all 8 possible conversions from the classic input to the quantum state vector:

This can be intuitively interpreted as:

Now that we finally have our quantum state vector, we just multiply it by the unitary matrix $Q$ of the quantum circuit, and obtain the $2^n$ dimensional output quantum state vector $\overrightarrow{q_{out}}$:

And at long last, the probability of each classical outcome of the measurement is proportional to the square of the length of each entry in the quantum vector, analogously to what is done in the Schrödinger equation.

For example, suppose that the 3 qubit output were:

Then, the probability of each possible outcomes would be the length of each component squared:i.e. 75% for the first, and 25% for the third outcomes, where just like for the input:

All other outcomes have probability 0 and cannot occur, e.g.: 001 is impossible.

Keep in mind that the quantum state vector can also contain complex numbers because we are doing quantum mechanics, but we just take their magnitude in that case, e.g. the following quantum state would lead to the same probabilities as the previous one:

This interpretation of the quantum state vector clarifies a few things:

Bibliography:

This paper appears to calculate the Schrödinger equation solution for the hydrogen atom.

TODO is this the original paper on the Schrödinger equation?

Published on Annalen der Physik in 1926.

Open access in German at: onlinelibrary.wiley.com/doi/10.1002/andp.19263840404 which gives volume 384, Issue 4, Pages 361-376. Kudos to Wiley for that. E.g. Nature did not have similar policies as of 2023.

This paper may have fallen into the public domain in the US in 2022! On the Internet Archive we can see scans of the journal that contains it at: ia903403.us.archive.org/29/items/sim_annalen-der-physik_1926_79_contents/sim_annalen-der-physik_1926_79_contents.pdf. Ciro Santilli extracted just the paper to: commons.wikimedia.org/w/index.php?title=File%3AQuantisierung_als_Eigenwertproblem.pdf. It is not as well processed as the Wiley one, but it is of 100% guaranteed clean public domain provenance! TODO: hmmm, it may be public domain in the USA but not Germany, where 70 years after author deaths rules, and Schrodinger died in 1961, so it may be up to 2031 in that country... messy stuff. There's also the question of wether copyright is was tranferred to AdP at publication or not.

An early English translation present at Collected Papers On Wave Mechanics by Deans (1928).

Contains formulas such as the Schrödinger equation solution for the hydrogen atom (1''):where: