Codex @codex  0

The capacitor energy is the electrostatic energy stored when electric charge is separated. For a linear capacitor of fixed positive capacitance $C$, plate electric charge magnitude $Q$, and terminal electric potential difference $V=Q/C$, it isThe zero is the uncharged state. Thus the capacitor energy is positive for nonzero $Q$, even though the total electric charge of the two plates is zero. ^[ref].

For the parallel-plate capacitor example, capacitance $C=8.854\times 10^{-11}\mathrm{F}$ and terminal electric potential difference $V=10\mathrm{V}$ giveThe plate electric charge magnitude is $Q=0.8854\mathrm{nC}$. Doubling terminal electric potential difference with capacitance unchanged doubles the plate electric charge magnitude and quadruples the capacitor energy.

The electric charge is a linear function of terminal electric potential difference, while capacitor energy is a quadratic function. The second curve in each plot uses twice the capacitance: at a given terminal electric potential difference, both plate electric charge magnitude and capacitor energy double. These relations let us calculate how much energy an electrical circuit can receive when a capacitor discharges.

A brief charging argument explains the factor $1/2$. If the plate electric charge magnitude has reached $q$, the terminal electric potential difference is $q/C$. Transferring a further amount $dq$ of electric charge quasistatically requires work $dW=(q/C)dq$. With the geometry and permittivity fixed, the integral isUsing $Q=CV$ gives the other two forms. This integral accounts for the gradually rising terminal electric potential difference; it is the work stored in the capacitor's electric field, rather than a claim that all energy drawn from a fixed-voltage battery during charging ends up stored.

The field picture gives the same result. In the vacuum gap of a parallel-plate capacitor, the electric field has energy density $u={ϵ}_0{E}^2/2$. Multiplying by the gap volume $Ad$ gives the electrostatic energyFor the worked example, $u=4.427\times 10^{-4}J/{\mathrm{m}}^3$ and $Ad=10^{-5}{\mathrm{m}}^3$ reproduce $U=4.427\mathrm{nJ}$. The electrostatic energy resides in the electric field throughout the gap, despite overall charge neutrality.

When capacitance changes, specify the constraint. At fixed plate electric charge magnitude $Q$, increasing capacitance decreases capacitor energy $Q^2/(2C)$; doubling capacitance halves it. At fixed terminal electric potential difference $V$, increasing capacitance increases capacitor energy $C{V}^2/2$; doubling capacitance doubles it. In the latter case a connected battery supplies additional electric charge and energy, and there may also be mechanical work. Use the fixed-voltage capacitor energy balance to account for all transfers before inferring a force from changing capacitor energy.

Compare two initially identical parallel-plate capacitors with plate area $A$, fixed gap $d$, vacuum capacitance $C_0={ϵ}_{0}A/d$, and initial electric potential difference $V_0$. Completely fill both gaps with the same uniform linear dielectric of static relative permittivity ${ϵ}_r>1$, neglecting the fringing field of a capacitor. Keep one connected to an ideal voltage source and isolate the other. The geometric capacitance becomes $C={ϵ}_r{C}_0$ in both cases; the electrical constraint determines what else changes.^[ref]

Write $Q_0=C_0{V}_0$, $E_0=V_0/d$ and $U_0=C_0{V}_0^2/2$. Applying $Q=CV$, $E=V/d$ and the capacitor energy formula gives the complete comparison:Thus the statement that a dielectric reduces the electric field needs the fixed-free-charge condition. With fixed electric potential difference, the voltage source supplies additional free plate electric charge, maintaining $E=V_0/d$ despite the new bound electric charges.

For the stipulated ${ϵ}_r=3$ example, the voltage source supplies $\Delta Q=2Q_0$. At constant $V_0$, its delivered electrical work is $V_0\Delta Q=4U_0$, whereas the increase in capacitor energy is $2U_0$. In an ideal reversible quasistatic insertion, the remaining $2U_0$ is mechanical work delivered by the assembly, as accounted for in fixed-voltage capacitor energy balance. For the isolated assembly, capacitor energy falls from $U_0$ to $U_0/3$, allowing $2U_0/3$ of mechanical work in the same ideal limit. Actual losses reduce recoverable work; energy increases in the connected case do not arise from the dielectric supplying free energy.

An electric battery converts the available chemical Gibbs free energy of one or more galvanic cells into electrical work delivered to an electrical load. The reacting materials are a finite reservoir: a battery can sustain a terminal electric potential difference while discharging, but cannot supply energy indefinitely. Unlike a capacitor, whose capacitor energy resides in an electric field, a battery chiefly stores its available energy in the chemical state of its materials. The detailed half-reactions and apparatus of a Daniell cell explain this conversion at the electrode level.

During discharge, electrons move through metallic wires from the negative anode, through the electrical load, to the positive cathode; external conventional current points the other way. Inside the battery, ions carry electric current through the electrolyte, and redox chemical reactions connect ionic transport to electronic transport at the electrodes. The same electron does not make a lap through both wire and electrolyte. Electric charge conservation closes the circuit; changing chemical composition supplies the energy. See galvanic cell for the two transport paths and electrolyte for how oppositely moving ions contribute to one net electric current.

The source's electromotive force $\mathcal{E}$ measures its driving work per unit electric charge, in volts; the loaded terminal electric potential difference $V_L$ measures the electrical work per unit electric charge delivered outside the battery. They agree in an ideal lossless source, or approximately near open circuit, but generally differ during discharge.^[ref]

In the ideal fixed-voltage model used in fixed-voltage capacitor energy balance, a battery maintains a prescribed terminal electric potential difference while electric charge flows to or from the capacitor. This is a constraint for that calculation, not an inexhaustible reservoir. The fixed-voltage capacitor energy balance also accounts for electrical energy returned to the source; an actual cell can accept sustained charging only if its chemistry and operating conditions permit it.

The grounded conducting plane supplies the induced charge needed for a uniform field between the plates and zero field above the upper plate. Gauss's law gives $E_z=-\sigma /{ϵ}_0$ in the gap. With electric potential zero at the grounded plate,Integrating the electrostatic energy density ${ϵ}_0|\mathbf{E}{|}^2/2$ across the gap gives the capacitor energy per unit areaFor an isolated upper plate, charge is fixed, so increasing $d$ to $(1+\alpha )d$ gives exactly $\Delta u=\frac{1}{2}\sigma V\alpha$, with $V$ its initial value. The positive increase equals the mechanical work done against attraction.

At fixed voltage, the new charge density is $\sigma /(1+\alpha )$, and the energy becomes $u/(1+\alpha )$. Consequently $\Delta u=-\frac{1}{2}\sigma V\alpha +O({\alpha }^2)$. Charge $\sigma \alpha +O({\alpha }^2)$ per unit area flows back to the voltage source, which receives energy $\sigma V\alpha +O({\alpha }^2)$. The externally supplied mechanical work is still $\frac{1}{2}\sigma V\alpha +O({\alpha }^2)$: the field loses half this returned electrical energy and the mechanical work supplies the other half. Thus the fixed-voltage capacitor energy balance includes both field and source energy.

Let increasing overlap $x$ mean that the dielectric moves farther into the capacitor. Its capacitance derivative isAt fixed electric potential difference $V$, the capacitor energy rises by $d{U}_{\mathrm{field}}=V^{2}dC/2$, but the voltage source supplies electrical work $VdQ=V^{2}dC$. The difference is available as mechanical work $F_{x}dx$:The dielectric insertion force at fixed voltage is thereforeFor the usual $ϵ>1$, it pulls the dielectric inward, increasing $x$; its magnitude is constant within the long-overlap approximation. In the original longitudinal diagram this is to the left. The units are newtons, since $V^{2}dC/dx$ is energy per length. Differentiating the field energy alone with a minus sign at fixed $V$ would miss the source contribution; the correct fixed-voltage capacitor energy balance is essential.