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When $m_1=m_2={\mu }^2$, the free energy has continuous symmetry $O(2)$. Its ordered minima satisfyContinuous phase fluctuations make the lower critical dimension $d_{\mathrm{l}}=2$, in agreement with the Mermin-Wagner theorem. In two dimensions write the complex order parameter as $\psi ={\rho }_0{e}^{i\theta }$. Neglecting the massive amplitude mode gives the Goldstone-mode effective free energyThe phase-difference variance isand thereforewithThus spin waves replace true long-range order by quasi-long-range order.

A vortex-antivortex pair of separation $R$ has the logarithmic energy $E_{\mathrm{pair}}\simeq 2\pi {\rho }_0^2\log (R/a)$. The number of pair separations below $R$ grows as $R^2$, giving the coarse entropy $S_{\mathrm{pair}}\simeq 2\log (R/a)$. Thusand widely separated pairs become favorable at ${\rho }_0^2\simeq 1/\pi$. Substituting the mean-field stiffness givessuggesting a Berezinskii–Kosterlitz–Thouless transition. The numerical location is only a bare-stiffness estimate: vortex-core fluctuations renormalize the stiffness near the transition.

At a critical point, a local field operator $\mathcal{O}$ has scaling dimension ${\Delta }_{\mathcal{O}}$ if $\mathcal{O}(x)\mapsto b^{-{\Delta }_{\mathcal{O}}}\mathcal{O}(x/b)$ under coarse-graining by $b$. The coupling $u$ in $\int d^{d}xu\mathcal{O}$ has renormalization-group eigenvalueA perturbation is a relevant operator when $y_u>0$, an irrelevant operator when $y_u<0$, and a marginal operator when $y_u=0$; nonlinear terms in its renormalization-group beta function decide the fate of a marginal coupling. Irrelevant microscopic interactions decay under coarse-graining, so many distinct systems approach the same fixed point and share one universality class.

Near criticality the singular free energy density is of order one per correlation volume:The heat capacity contains two derivatives with respect to temperature, soConsequently the hyperscaling relation is

Use the stable parameters $b,\kappa >0$. The bulk stationary points satisfy $f^{\prime }(\varphi )=a\varphi +b{\varphi }^3=0$. For $a<0$, $\varphi =0$ has negative curvature, while the two minima areBoth have $f(\pm {\varphi }_B)=-a^2/(4b)$ and $f^{\prime \prime }(\pm {\varphi }_B)=-2a>0$. To establish minimization at fixed total composition, writeFor mean composition $\bar{\varphi }$ with $|\bar{\varphi }|<{\varphi }_B$, a mixture of the two minima with volume fraction $\lambda =(\bar{\varphi }+{\varphi }_B)/(2{\varphi }_B)$ in the positive phase attains this lower bound in the bulk. Macroscopic slabs have only a subextensive interfacial excess free energy, so the bound is attained per unit volume in the thermodynamic limit. Thus constrained minimization gives phase coexistence in the mean-field approximation; at the endpoints only one phase is needed.

The two equilibrium conditions also follow directly by constrained optimization. Introduce a Lagrange multiplier $\mu$ for $\lambda {\varphi }_{+}+(1-\lambda ){\varphi }_{-}=\bar{\varphi }$ in the mixture's bulk free-energy density. Varying ${\varphi }_{+}$ and ${\varphi }_{-}$ gives $f^{\prime }({\varphi }_{+})=f^{\prime }({\varphi }_{-})=\mu$; varying $\lambda$ gives $f({\varphi }_{+})-\mu {\varphi }_{+}=f({\varphi }_{-})-\mu {\varphi }_{-}$. These equate the chemical potentials and pressures, respectively.

Equivalently, their bulk chemical potentials are both zero and their pressures are equal:These are precisely the conditions of the common-tangent construction for phase coexistence: the horizontal supporting tangent touches both minima. Equal chemical potentials prevent net composition exchange, and equal pressure gives mechanical equilibrium at a flat interface.

In the high-tension, narrow-gap regime, the almost spherical membrane has area $4\pi (R+\delta {)}^2$. Its spherical bending energy $8\pi k_c$ is independent of radius, while Helfrich repulsion over area $4\pi R^2$ costsUp to terms independent of $\delta$, a suitable free energy is consequentlyIts stationary point satisfiesUsing $\delta /R\ll 1$ gives the fluctuation-supported membrane--particle gapThe inverse-square entropic repulsion prevents contact, while membrane tension limits the area gained by opening the gap.

The phase stiffness is the coefficient of $\frac{1}{2}\int d^{d}x(\nabla \theta {)}^2$ in the long-distance free energy. Its renormalized value determines the thermal phase fluctuations and algebraic correlation function of a two-dimensional O(N) model with $N=2$.

The polar molecular field is the functional derivative of the free energy with respect to the polar order parameter. In the positive-derivative convention, dissipative dynamics is $D_t\mathbf{p}=-\Gamma \mathbf{h}$ with positive kinetic coefficient. For a quartic local term and an isotropic gradient penalty,Some authors instead define the molecular field with a minus sign, which changes the associated stress and evolution conventions.

For a real statistical source convention $Z[h]=\int \mathcal{D}\varphi e^{-H_0[\varphi ]+\int h\varphi }$, define $F=-\log Z$ and the displayed Legendre transform. On a differentiable stable branch, $\delta \Gamma /\delta m=h$. In the Landau approximation, the branch expression is ${\Gamma }_{\mathrm{L}}[m]=H_0[m]$. The exact Legendre effective free energy is convex; a bare nonconvex Landau free energy is a local approximation and requires branch or coexistence interpretation.

For the Landau free energy $G(\varphi )={\varphi }^6/6+g{\varphi }^4/4+\epsilon {\varphi }^2/2$, positive $g$ gives a continuous phase transition at $\epsilon =0$. For negative $g$, phase coexistence between the disordered global minimum $\varphi =0$ and the ordered global minima occurs on $\epsilon =3g^2/16$, with ${\varphi }^2=-3g/4$. Indeed, on that locus the polynomial is $G(\varphi )={\varphi }^2({\varphi }^2+3g/4{)}^2/6\ge 0$, so these three zeros are global minima. For $g<0$, the disordered and ordered spinodal points are respectively $\epsilon =0$ and $\epsilon =g^2/4$; equality of stationary free energies determines phase coexistence, while loss of a local minimum determines a spinodal point.

For the spin inversion symmetry parameterization $W=c\left(\begin{array}{ccc}1& x& y\\ x& z& x\\ y& x& 1\end{array}\right)$ with positive entries, spin decimation gives the same form with $x^{\prime }=x(1+y+z)/(1+x^2+y^2)$, $y^{\prime }=(x^2+2y)/(1+x^2+y^2)$ and $z^{\prime }=(z^2+2x^2)/(1+x^2+y^2)$. Multiply $W$ by itself and divide by its $(+,+)$ entry to prove these ratios. The leftover scalar is an additive free-energy coupling; dropping it leaves normalized expectations unchanged but loses the full free energy.

For additive Gaussian white noise and a time-even order parameter, a midpoint discretization of the Onsager–Machlup functional evaluates drift derivatives at the midpoint configurations. Reversing a trajectory visits the same midpoints in reverse order, so the noise-to-path Jacobian determinant is invariant under reversal. It may depend on the trajectory, and must be distinguished from the constant normalization of the noise measure.

For nonconserved order-parameter dynamics with $\dot{p}=-\Gamma \mu [p]+f$, the factor at one time step, apart from a path-independent power of the step size, isHere the fields have first been restricted to a finite spatial grid, and ${\mathcal{H}}_n$ is the Hessian matrix of the free energy.

For mixed conserved and nonconserved order-parameter dynamics, the required noises for a joint configuration and flux trajectory arewhere $\mathsf{D},\mathsf{G}$ represent the divergence and gradient, and $\Delta =\mathsf{DG}$ represents the Laplacian. The Jacobian matrix isTaking its Schur complement gives the joint factorFor periodic boundary conditions, discretizing the two spatial operators compatibly gives $\mathsf{D}=-{\mathsf{G}}^{\mathsf{T}}$, so $\Gamma I-M\Delta$ is the positive relaxation operator when $\Gamma ,M>0$. Reversal leaves ${\mathcal{H}}_n$ unchanged and reverses the sign of the flux. The product of the joint factors is consequently the same for both histories, justifying its cancellation from the joint path probability of an order parameter and its flux. The functional chain rule used in the action ratio holds in the continuum limit of this midpoint convention.