The statistical Hamiltonian in this question is already in thermal units, as indicated by without an additional . Define and . The mean field and its linear response are
These are functional derivatives of the connected generating functional; the subtraction defines the connected correlation function. In the Landau approximation, neglect loop corrections and evaluate the field integral at a stable saddle . It satisfies the Euler-Lagrange equation
This follows by varying the gradient term and integrating by parts, with periodic, decaying, or otherwise appropriate boundary conditions.
The two requested free energy functionals, following the source and Legendre conventions of the question, are
In the scalar-field source Legendre transform on the chosen stable branch, is chosen to produce , and . Thus the imposed-source Helmholtz free energy and the fixed-order-parameter Gibbs free energy have the appropriate opposite source derivatives. These names are used in the question's magnetic-ensemble convention; the defining sign relation is what fixes the calculation. At leading Landau approximation there is no fluctuation-determinant term in .
Differentiate the saddle equation with respect to . The response obeys
Therefore
Equivalently, the inverse Hessian relation for a connected two-point function states that is the inverse kernel of . The factor follows from twice differentiating the quartic term ; it is not . This tree-level connected response is obtained by varying the saddle. It does not require replacing the exact connected correlator by a product of the saddle values, which would incorrectly give zero.
For the requested single-momentum formula, assume a homogeneous source and a translationally invariant equilibrium phase, so and . Set
The Fourier transform with the printed positive sign sends to , while the Dirac delta function transforms to one. Hence the Ornstein--Zernike correlation function has
The inverse convention is . For general inhomogeneous , has nonconstant coefficients and depends separately on its two positions; the displayed momentum-diagonal formula then does not follow. The preceding differential equation still holds in that case.
At zero source and for , the homogeneous saddle is for , and on either selected stable ordered branch for . Thus the Landau scalar correlation length is
In the ordered phase the negative bare quadratic coefficient is compensated by the positive curvature at the nonzero saddle. Retaining below the transition would instead give an unstable kernel and is not a physical correlation length. With the usual analytic thermal tuning , , both branches diverge as , so the correlation-length critical exponent is
The high-temperature amplitude is times the low-temperature amplitude for the same . This statement is within Landau theory; fluctuations can change critical behavior outside the mean-field regime.
When , the field theory is a Gaussian field theory, so integrating out short-wavelength modes can be done exactly rather than merely at a saddle. Introduce an ultraviolet momentum cutoff and a scale factor , then split into and . Orthogonality of Fourier modes eliminates cross terms in the quadratic Hamiltonian. A constant source couples only to the zero-momentum mode and therefore does not couple to .
Before rescaling, the Gaussian functional integral factorizes:
where has the original and , restricted to low momenta. Up to a field-independent normalization, the eliminated modes contribute
The determinant affects the additive free energy, but generates neither a mass correction nor a source correction, since no interaction mixes low and high modes. This remains true beyond the Landau approximation: it is an exact integration of a Gaussian field theory, not neglect of the high-mode fluctuations.
To restore the original cutoff, use , , and choose the field rescaling
Substitution into the low-mode Hamiltonian gives the Gaussian momentum-shell scaling
The gradient coefficient is unchanged: the volume factor is , the two derivatives contribute , and the two fields contribute . The mass term gains , while the source term gains . Thus
For a nonconstant source the corresponding formula is , after restricting its coupling to retained modes. The constant-source case avoids that extra source filtering.
Writing , the exact Gaussian renormalization-group flow has
Both perturbations are relevant at the massless zero-source Gaussian fixed point, with and . There is no anomalous field rescaling here, so and the correlation-length critical exponent is again . The coefficient changes arise from rescaling, not from an interaction-induced shift in during shell integration.
A stable real Gaussian functional integral requires , or an infrared prescription that treats the zero mode at the massless point. With and , the field energy is unbounded below; the Gaussian field theory alone cannot describe a stable ordered phase. The scaling laws are therefore interpreted about the Gaussian fixed point from the stable side, with finite-volume zero-mode regularization when needed.
Discuss the zero-field phase boundaries, taking and writing , , . This qualification matters because a conjugate field generally rounds the zero-field continuous transition. Nonzero stationary points satisfy .
For , the continuous phase transition occurs at
On the side the only stable phase is ; on the side the equilibrium global minima are with . The magnetization therefore grows continuously from zero as changes sign.
For , the first-order phase transition instead occurs while is positive. At phase coexistence, and are equally deep global minimum points. With , stationarity and equality of free energies give
Eliminating gives , hence
At this coexistence value, the sextic even Landau potential factors as . This verifies that the three equal stationary values are global minima. Above this coexistence value of the disordered phase wins; below it the ordered phase wins, with a finite jump in the phase-selected magnetization. The values and are the disordered and ordered spinodal points, respectively, not the coexistence boundary: the latter follows from the repeated root of .
The two transition loci meet at the tricritical point,
Two independent control parameters such as and can tune these two conditions. In a generic local phase diagram their coefficient map has a Jacobian matrix of rank two at the intersection; unspecified functions and do not by themselves determine the geometric orientation of the boundaries. The sextic term stabilizes this intersection and the negative-quartic first-order side.
These are mean-field critical exponents at a tricritical point. Hold the other control at its tricritical value and take the coefficients to be real analytic functions of temperature along a thermal approach with , , , and or . At fixed tricritical , a generic real analytic temperature path with nonzero thermal slope has and meets the last condition. Paths tangent to a scaling direction can have different apparent temperature powers.
At zero field on the ordered side with , stationarity gives ; under the more general approach , this relation holds to leading order. Thus the order-parameter critical exponent is
For the zero-quartic representative, putting this minimum into the Landau free energy gives the singular order-parameter contribution (and the leading asymptotic contribution under the stated negligible-quartic approach)
Using at fixed other control yields , specifically to leading order. Hence
This heat-capacity critical exponent refers to the nonzero ordered-side singular amplitude; in this mean-field approximation to Landau theory, the disordered global minimum contributes zero singular free energy, while any regular background remains. Fluctuation corrections lie outside the present approximation.
In the disordered phase, differentiating the equation of state at gives the magnetic susceptibility . On the ordered branch its curvature is , so . Both give the magnetic-susceptibility critical exponent
At the tricritical temperature with both lower coefficients zero, , so and the critical-isotherm exponent is
The Widom scaling relation and Rushbrooke scaling relation both check these powers. Their validity here is a mean-field conclusion, not a claim that fluctuations in every spatial dimension preserve them.
Take the couplings in the Hamiltonian to include inverse temperature, so the Boltzmann factor is . If physical energies are used instead, first replace by their products with . Split the on-site term equally between its two bonds. For spin states the spin-chain transfer matrix has entries
Using the specified coupling coordinates, in the order this is
For example, and . This is the nearest-neighbour Blume–Emery–Griffiths model with an additive constant and the paper's sign convention for .
Summing the periodic spin chain gives the partition function . For finite real couplings all entries of are strictly positive; the Perron–Frobenius theorem gives a unique positive dominant eigenvalue with for . Since is a symmetric matrix, all its eigenvalues are real. Thus in the thermodynamic limit,
The positivity condition is stronger and more useful than mere ordering by signed value: subdominant eigenvalues can be negative. Also, the printed strict ordering between the other two is not guaranteed for all couplings. For instance, makes the positive constant matrix with two equal zero eigenvalues. Degeneracy there does not affect the largest-eigenvalue limit; no explicit generic eigenvalues are needed.
For spin magnetization, introduce a dimensionless field through , or insert into the trace. Then
where is a normalized eigenvector of the largest eigenvalue and . Spin inversion symmetry gives , since the positive eigenvector of the largest eigenvalue is unique. Therefore
at zero field, both at finite and in the finite-coupling thermodynamic limit. The finite- result follows directly by pairing each configuration with its spin-reversed partner. Eigenvalues at a single fixed field do not determine a general observable: a field derivative of the largest eigenvalue, or its eigenvector, is required. Positivity and the real analytic dependence on the couplings exclude a finite-temperature spontaneous symmetry breaking transition in this one-dimensional finite-range chain; singular zero-temperature coupling limits require separate treatment.
For even , spin decimation on alternate sites sums the middle spin of each two-bond segment, hence the coarse spin-chain transfer matrix is . Define
Direct multiplication gives . Matching its entry ratios to the original parameterization yields the spin-1 chain decimation recursion
The remaining overall positive factor is absorbed into . Keeping that factor preserves the free energy as well as normalized spin probabilities. Indeed , exactly; on an odd ring an unmatched boundary segment needs separate handling rather than assuming a uniform two-site block decomposition.
Use a dimensionless Hamiltonian in the functional weight , assume , and let . Reality means . At zero field, the quadratic form is
In the momentum-shell renormalization group, split into below and above . Disjoint Fourier supports make the quadratic form split into . Integration over the shell gives a source-independent Gaussian functional integral multiplying the partition function, or an additive constant in the effective free energy; it leaves the slow-mode quadratic coefficients unchanged before rescaling. A uniform field has support only at zero momentum, so it does not change this shell integration.
Restore the ultraviolet cutoff by , , and choose
The measure, two gradients and two fields have scale factors , and , whose product is one. The mass term has factor , while the uniform source term has factor . Hence the Gaussian momentum-shell scaling is
For a slowly varying nonuniform source the corresponding formula is . Here the nonuniform source on the right is its projection onto the retained Fourier modes; an eliminated source component contributes only to the field-independent Gaussian normalization. The field engineering dimension is and its Gaussian anomalous dimension is zero. The mass and uniform source are relevant perturbations of the Gaussian fixed point. Positivity of is necessary for a stable kinetic term near this point. One can use a finite volume and positive mass as infrared regulators and then take the critical limit; at exactly zero mass the integral over the zero Fourier mode alone is not a normalized finite-volume Gaussian measure.
Let be a coarse-grained configuration, with restricted partition function and free energy . Its Boltzmann distribution is . Microscopic reversibility pairs every equilibrium microscopic history with a history read backwards, including reversal of all time-odd variables. Summing this identity over the microscopic histories representing a given coarse-grained path preserves it; a Markov assumption is not needed for this argument.
Write for the probability density of a specified history conditional on its starting configuration , and for its physically reversed history conditional on starting at , where reverses time-odd variables. Equilibrium time-reversal symmetry gives
Since , the desired conditional path relation is
For a reversible Markov chain, this also follows by multiplying detailed balance ratios along the history: the intermediate equilibrium weights telescope.
The conditioning is essential. If the starting equilibrium weights are included in the path probabilities, the forward and reversed probabilities are equal, rather than differing by the displayed exponential. For example, a two-state continuous-time Markov chain with , , rates and has equal equilibrium-weighted probabilities for the two reversed single-jump histories. Their conditional rate ratio is instead . Normalized bridges conditioned on both endpoints also have a different normalization from the path weights used above. The PDF prints in the denominator while its explanatory text defines ; the latter is the intended notation. For the scalar order parameter used subsequently, .
With periodic or sufficiently decaying boundary conditions, integration by parts gives
Assume for a stable quadratic free energy; the diffusive smoothing discussed below requires . In a periodic box of volume , use the unitary convention . A real field has . Since the Fourier transform of a derivative converts to , each Fourier mode obeys
It is an Ornstein-Uhlenbeck process. Multiplication by the integrating factor gives
The noise integral is understood as an Itô integral with a deterministic kernel; writing is shorthand for the corresponding Wiener increment. Direct differentiation in the mild stochastic sense checks both the equation and the initial value. The stated Kronecker-delta noise covariance corresponds to this finite-volume normalization. Unlike a conserved order parameter, the zero wavenumber mode decays at the nonzero rate .
The total charge of the widely separated pair is zero, so a uniform planar nematic director is compatible with the far boundary if it imposes no additional winding. Each integer defect is susceptible to energetic fission of an integer nematic disclination: the positive defect can split into two defects and the negative defect into two defects. Like-sign elementary defects repel, whereas opposite signs attract through their elastic distortion. This commonly produces subsequent encounters and annihilations of opposite half-integer defects.
The attraction can also be seen before fission. In the fixed-amplitude outer theory, a neutral pair of charges separated by has
Its energy therefore falls as the separation decreases. In nematic defect-antidefect annihilation, opposite defects meet, the amplitude can vanish in their merging cores, and the local winding disappears; the remaining smooth director distortion relaxes towards the uniform energy minimum.
Expected route: integer-defect fission and attraction of opposite elementary defects, followed by annihilation and relaxation of the remaining texture.
Direct approach and annihilation of the unsplit integer pair is also topologically allowed. Whether fission happens first, the paths of the four elementary defects, and the annihilation time require a specified dynamical law and core mobilities; the free energy alone does not fix them. Pinning, imposed boundary textures, or sustained thermal production of defect pairs can prevent a strictly defect-free final state. The stated final state presumes dissipative relaxation with no such obstruction.
Use the usual homogeneous, local, analytic Landau-Ginzburg theory; rotational symmetry and Z2 symmetry alone do not specify locality, analyticity, or the signs of the coefficients. The local derivative expansion contains every rotational scalar with an even total number of fields:
The omitted terms include all allowed higher field powers and contracted spatial derivatives. Terms differing by a total derivative are equivalent for bulk behavior with suitable boundary conditions. The displayed gradient energy assumes spatial homogeneity. If only rotations about an origin are imposed, rotationally invariant position-dependent coefficients are also possible.
In the mean-field approximation, take a spatially uniform order parameter and minimize its Landau free energy. For , and with , keeping the quadratic and quartic terms gives
The single minimum splits into two minima as the temperature passes below the critical temperature. Choosing one minimum gives spontaneous symmetry breaking of the Z2 symmetry and a continuous phase transition. The order parameter is the expectation in a selected ordered state; averaging equally over both states gives zero. A Z2 symmetry does not guarantee a continuous phase transition: a negative quartic coefficient stabilized by a positive sextic coefficient can instead give a first-order phase transition.
Relaxing the Z2 symmetry permits odd terms. A nonzero linear source generally rounds this ordinary continuous phase transition. A cubic term can instead give a first-order phase transition: for , and , equal minima occur at
The order parameter jumps from zero to . A continuous phase transition without an exact Z2 symmetry is still possible with additional tuning; odd terms do not logically exclude it.
For the multicritical even Landau potential, set and assume an integer , and . For , all lower even interactions must be absent or tuned to zero to obtain these mean-field critical exponents. The stationary equation is
Its nonzero solutions are minima because . Thus the order-parameter critical exponent is
Substituting into the minimum free energy density gives
The singular heat capacity per unit volume is . Smooth variation of the other coefficients does not change the leading power. Consequently
For , this means a finite heat capacity jump, with ; for , the tricritical point has and . The case would contain only a quadratic potential and would not stabilize an ordered phase.
The Gaussian fluctuation correction near a critical point is more singular than the mean-field approximation contribution when
This is the upper critical dimension of an even scalar interaction. Equivalently, its coupling has engineering dimension , positive below . Dominant fluctuations signal breakdown of the mean-field approximation; the Gaussian expression is not then a calculation of the exact interacting heat-capacity critical exponent. At , equality of the powers allows logarithmic corrections.
Absorb into the free energy, so the statistical weight is . Under the Gaussian fixed point rescaling, invariance of the gradient energy gives the engineering dimension
The engineering dimensions of are respectively . Their coupling eigenvalues are , hence . The quadratic and quartic interactions are relevant operators; the sextic interaction is a marginal operator at this order.
The three steps of the momentum-shell renormalization group are:
  • Split into slow modes and fast modes , and integrate over .
  • Rescale to restore the ultraviolet cutoff to .
  • Rescale the field as to normalize the gradient energy.
Here , so increasing means flowing toward longer distances. At leading order, the fast field has a Gaussian distribution with covariance
This perturbative integration requires on the shell. By the Wick theorem, odd fast-field moments vanish and , . Therefore the first term of the cumulant expansion of a coarse-grained free energy is
This is the quartic interaction generated by a sextic interaction. Including the rescaling, the requested flow is
In spherical coordinates, . In particular, for ,
The same integration shifts the quadratic coefficient by before rescaling and adds an irrelevant constant to the free energy. Thus setting the bare quartic coupling to zero does not place the theory on the tricritical critical surface.
To calculate the sextic renormalization-group beta function to second order, let . The required cumulant expansion is
The subtraction removes disconnected contributions. The term at each vertex supplies the primitive sextic correction. The Wick contractions give
The first term contains three propagators connecting the two vertices; its factor is the number of bijections between the three fields at each vertex. The second contains a local tadpole diagram at each vertex and one connecting propagator. The primitive contribution to the free energy is therefore
Expanding the slow fields about a common point gives a negative local sextic correction proportional to
where restricts a momentum to the shell. This connected Feynman diagram has two independent loop momenta. Other Wick contractions also generate lower interactions and tadpole diagrams; they must be included or subtracted consistently when fixing the tricritical critical surface.
To extract the logarithmic tricritical sextic beta function, use normal ordering to remove local tadpoles and tune the quadratic and quartic relevant operators. The massless three-dimensional propagator is . The same three-line contraction over short separations gives
Its positive coefficient and the negative sign of the second cumulant expansion term establish the sign of the flow. Matching this logarithm to a renormalized coupling, or performing consistent iterated shell integration, gives
The precise normalization of is not needed. In a sharp momentum cutoff scheme, simply forcing all three internal momenta into one infinitesimal shell does not extract this two-loop logarithm: the shell restrictions remove its linear-in- phase space. The finite-shell cumulant and the logarithmic renormalized calculation above are distinct stages of the computation. Field normalization corrections at order enter this renormalization-group beta function only at order .
A positive, stabilizing sextic coupling is marginally irrelevant in three dimensions on the tricritical critical surface. Reversing the convention for reverses the sign of the renormalization-group beta function. A negative sextic coupling without higher stabilizing powers makes the potential unbounded; moreover, the untuned bare choice generally flows away through its generated relevant operator.
Let be the polar molecular field, with the positive functional derivative convention used in the paper. During a pure advective displacement , the polar order parameter changes by
The free energy change is . Assume periodic boundaries, or boundary conditions that eliminate the surface work, and incompressibility . Integration by parts in the advective term gives
Relabelling the dummy indices in the rotational and flow alignment of a polar order parameter terms gives
Therefore , with the reversible stress of a polar liquid crystal
For a local free-energy density , an explicit choice is
Its divergence is exactly , by the Euler-Lagrange equation for . A pressure term can be reassigned in an incompressible flow; the chosen representative realizes the printed divergence without that ambiguity. The force density has mechanical power , the negative of the advective free energy rate, which checks the stress sign.
For the stated uniaxial nematic order normalization, the nematic director is an eigenvector of with eigenvalue , and the two perpendicular eigenvalues are . Therefore
Using precisely the Landau-de Gennes free energy convention in the preceding solution gives
If the quartic invariant were instead normalized as , its coefficient would be ; the physical predictions are unchanged after redefining .
For a nonzero global minimizer of the free energy, compare opposite values of the scalar nematic order parameter:
The lower one has , so
The claim concerns the stable ordered phase, not every metastable stationary point. For the two signs are degenerate. For , equality of the ordered and isotropic free energies, together with stationarity, gives and . The finite jump exhibits the first-order phase transition driven by the cubic invariant.
A scalar coupling linear in the nematic order parameter requires a second-rank anisotropy. A single electric field supplies no such tensor, while does. Its isotropic part gives . Hence the lowest joint order in and of the electric-field coupling to nematic order is
Terms depending only on do not affect minimization over . With the angle between the nematic director and the electric field,
For , the lowest free energy occurs at , so the nematic director aligns along either or . Then , giving
Unlike the linear composition term in a conserved binary fluid mixture, this term changes the equilibrium nematic order parameter: its spatial integral is not fixed.
Within this analytic quartic Landau theory, equilibrium of a nonconserved scalar order parameter requires . At a continuous phase transition, its restoring curvature vanishes, so . A nonzero would leave a cubic leading term in the Taylor expansion about that state and prevent it from being a local minimum. Thus a stable critical endpoint of a quartic Landau free energy requires all three derivatives to vanish, with . The condition alone can instead identify a spinodal point.
For , , the successive equations are
They give
At these values, the free energy is exactly , proving stability. With no electric field, , so necessarily , followed by .
For and , the electric-field coupling to nematic order supplies the required negative at
Tuning the quadratic coefficient to simultaneously reaches the field-induced critical endpoint of the isotropic-nematic transition. The PDF's in the last clause is undefined; it is interpreted here as the previously defined . The endpoint is a prediction of the stable quartic, small-field mean-field approximation; higher-order terms or a field beyond the expansion's validity can shift it.
A momentum-shell renormalization group step has three parts. First split the field into slow and fast Fourier modes, , and integrate over the shell . Second rescale , or equivalently , to restore the ultraviolet cutoff to . Third rescale the field so that the coefficient of returns to its chosen normalization. The resulting free energy has the same operator expansion but new couplings; iteration traces a renormalization-group flow in coupling space.
For the first step only, write and average over the fast modes of the Gaussian field theory. The cumulant expansion gives
Here
At order , the connected contraction of two vertices gives the low-momentum two-point term. Since ,
Expanding at small external momentum and matching yields
The first cumulant also produces a term linear in ; it is removed by fixing the one-point function, or equivalently by a field redefinition, and does not change the displayed one-particle-irreducible correlation function correction to the mass.
The leading vertex correction is order . Taking from each of three vertices, the connected Wick contractions form a triangle. There are eight contractions, so the third cumulant contributes times the triangle integral. At zero external momentum,
For nonzero external momenta the three propagators carry the corresponding shifted loop momenta, with every internal line restricted to the fast shell.