Past exam of the physics B course of the University of Cambridge / 2022 / Paper 2 / Section A / A3

(a) Treat the lake as a heat bath at fixed temperature $T_0=288.15\mathrm{K}$ and the block's heat capacity as constant. Its initial temperature is $T_i=473.15\mathrm{K}$, and $C=mc=355\mathrm{J}{\mathrm{K}}^{-1}$. Although the cooling is irreversible, entropy is a state function, so evaluate the block's change along an imagined reversible thermodynamic process:The lake receives heat $Q=C(T_i-T_0)=65675\mathrm{J}$, and thereforeAdding the two contributions givesThe positive result is consistent with the Second law of thermodynamics for heat transfer across a finite temperature difference. The calculation uses $c=710\mathrm{J}\mathrm{k}{\mathrm{g}}^{-1}{\mathrm{K}}^{-1}$ exactly as printed in both the original PDF and the transcription; it does not replace the supplied value by a tabulated value for lead.

(b) The block starts and eventually finishes at the lake's temperature, so its net entropy change is approximately zero. Neglecting buoyancy, air resistance and the final immersion depth, the lost gravitational potential energy $mgh$ becomes internal energy in the lake after the motion and waves have dissipated. The lake remains at $T_0$, givingTemporary heating of the block or temporary storage in kinetic energy does not change this final energy and entropy balance once thermal equilibrium is restored.