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For refractive indices $n_{-}>n_{+}$, the critical angle for total internal reflection satisfies $\sin {\theta }_c=n_{+}/n_{-}$. Above it, the transmitted normal wavenumber is imaginary and the transmitted field is an evanescent wave.

The critical angle for total internal reflection is the boundary between outgoing refraction and an evanescent wave, rather than an angle at which the external electric field abruptly disappears. Write $n_1=n_{-}$ and $n_2=n_{+}$. At the threshold, Snell law for electromagnetic waves has ${\theta }_t=90^{\circ }$, henceHere inverse sine selects $0<{\theta }_c<90^{\circ }$. For $n_1=1.5$ and $n_2=1$, $\sin {\theta }_c=2/3$ and ${\theta }_c\approx 41.8103149^{\circ }$. The threshold is independent of polarization of an electromagnetic wave under the stated assumptions.

A short proof using phase matching at a planar wave interface reveals all three cases at once. Choose a Cartesian coordinate system with boundary $z=0$, incident medium $z<0$, and transmitted medium $z>0$. With vacuum wavenumber $k_0=2\pi /{\lambda }_0$, the shared tangential wavevector component is $q=n_1{k}_0\sin \theta$. The dispersion relation in medium two givesBelow ${\theta }_c$, choose the positive real square root for an outgoing plane electromagnetic wave. At ${\theta }_c$, $k_{2z}=0$: there is a grazing wave, with zero normal average power but no exponential confinement in $z$. Above ${\theta }_c$, choose $k_{2z}=i\kappa$ with $\kappa >0$, so the wave amplitude decays into the second half-space.

If $n_1\le n_2$, no nongrazing angle of incidence produces this threshold. As $n_2/n_1\to 1$ from below, ${\theta }_c\to 90^{\circ }$; as that ratio tends to zero, ${\theta }_c\to 0$. These limits explain why a larger refractive index contrast permits confinement over a wider range of internal angles.

The source-free Maxwell equations in a linear medium areHere the constitutive relations are $\mathbf{D}=\epsilon \mathbf{E}$ and $\mathbf{B}=\mu \mathbf{H}$.

Substitution of the sinusoidal plane waves into the two divergence equations gives the transversality of an electromagnetic plane wave,Faraday's law and the Ampère-Maxwell equation give, respectively,Taking $\mathbf{k}\times$ the first equation and using transversality yieldsThus a nonzero plane electromagnetic wave in a linear medium must satisfyIn particular, ${\mathbf{E}}_0$, ${\mathbf{B}}_0$, and $\mathbf{k}$ are mutually orthogonal, with $|{\mathbf{B}}_0|=\sqrt{\mu \epsilon }|{\mathbf{E}}_0|$.

Take the interface to be $x=0$ and the plane of incidence to be the $xy$-plane. The incident, reflected, and transmitted wavevectors may be writtenThe phase matching at a planar wave interface requires one common angular frequency and one common tangential wavevector:Since $k_{\pm }=\omega \sqrt{{\epsilon }_{\pm }\mu }=n_{\pm }\omega /c$, this gives the Snell law for electromagnetic waves,

For the final polarization, take the signed electric amplitudes along $\hat{\mathbf{z}}$. The dielectric-interface boundary conditions require continuity of tangential $\mathbf{E}$ and $\mathbf{H}$. Sincetheir $z$- and $y$-components giveandEliminating $E_I$ yieldsUsing ${\theta }_R={\theta }_I$ and Snell's law,Therefore the reflected-to-transmitted transverse-electric amplitude ratio iswith the polarization directions chosen so that the displayed signed factor is nonnegative; otherwise its absolute value gives the magnitude ratio.

The condition ${\mathbf{E}}_I\cdot \hat{\mathbf{x}}=0$, together with transversality ${\mathbf{k}}_I\cdot {\mathbf{E}}_I=0$, selects polarization along $\hat{\mathbf{y}}$ away from the normal-incidence degeneracy. Phase matching at a planar wave interface givesThe two dispersion relations give $|{\mathbf{k}}_T{|}^2=({\epsilon }_{+}/{\epsilon }_{-})k_I^2$. Choosing propagation into $x>0$ therefore yieldsEquivalently, this is Snell law for electromagnetic waves with refractive index proportional to $\sqrt{\epsilon }$ because the two media have equal magnetic permeability.

Choose the interface as $x=0$ and write the incident, reflected, and transmitted fields as plane waves with wavevectors $k_I,k_R,k_T$. The boundary conditions must hold for every tangential coordinate and every time. The phase matching at a planar wave interface therefore requiresand equality of tangential wavevectors:

The incident and reflected waves are in the same medium, so
$|k_I|=|k_R|$. Equality of their tangential components giveshence

At fixed frequency, $|k_{\pm }|=\omega /v_{\pm }$ is proportional to the refractive index $n_{\pm }$. Tangential phase matching between incident and transmitted waves gives the Snell law for electromagnetic waves:orHere $n_{\pm }=c/v_{\pm }=c\sqrt{{ϵ}_{\pm }\mu }$ if the vacuum speed $c$ is used to normalize the index.

For equal permeabilities on the two sides of an interface, tangential-field continuity and Snell law for electromagnetic waves givefor consistently signed electric amplitudes normal to the plane of incidence.

Total internal reflection occurs when a wave travels from higher to lower refractive index above the critical angle for total internal reflection, leaving no propagating transmitted plane electromagnetic wave normal to the interface.

At an infinite planar interface, total internal reflection returns all incident normal power in the reflected plane electromagnetic wave. Assume homogeneous dielectrics with isotropy, linearity, no dielectric loss, magnetic permeability ${\mu }_0$, and positive real refractive indices $n_1>n_2$. Above the critical angle for total internal reflection, both TE polarization and TM polarization have unit optical reflectance despite the external evanescent wave.^[ref]

This makes total internal reflection useful for guiding light in an optical fiber: suitable internal incidence angles keep energy inside successive boundaries. Its more surprising feature is that perfect optical reflectance coexists with an external electric field. The evanescent field in total internal reflection can interact with a nearby object, as the frustrated total internal reflection experiment demonstrates.

For an original idealized example, choose $n_1=1.5$, $n_2=1$ at vacuum wavelength ${\lambda }_0=633\mathrm{nm}$. At angle of incidence $40^{\circ }$, Snell law for electromagnetic waves gives an angle of refraction $\arcsin (1.5\sin 40^{\circ })\approx 74.6186^{\circ }$, so a transmitted light ray still emerges. At ${\theta }_c\approx 41.8103^{\circ }$, its direction becomes tangent to the boundary. At $50^{\circ }$, the proposed sine of a real angle of refraction would be $1.5\sin 50^{\circ }\approx 1.14907>1$: the transmitted wavevector must instead have an imaginary normal component. These are predictions for the stipulated media, not measured properties of a particular block.

A real semicircular-block experiment isolates this threshold. The University of Maryland laboratory instructions place a laser, motor-driven rotation stage and photodetector together; an aperture limits the detector voltage. The semicircular block is centered on the rotation axis, with the photodetector aligned along its flat face. The instructions identify a strong grazing-beam signal and a weaker signal just before the critical angle for total internal reflection. The readout is detector voltage versus stage angle. Retracing the incident laser beam identifies normal incidence for alignment.^[ref]

The semicircular shape supplies a geometric control: a light ray passing radially through the curved face enters at normal incidence, avoiding additional entrance refraction. The weaker signal near the flat face locates a limiting angle of refraction; a vanishing remote-detector signal alone would not establish that the external electric field vanishes. Beam width and alignment limit angular resolution; no measured threshold or decay depth is supplied.^[ref]