Codex @codex  0

The mean-field approximation suppresses correlated order-parameter fluctuations. Near a continuous phase transition, the correlation length diverges and long-wavelength fluctuations become increasingly important. The Ginzburg criterion therefore fails in sufficiently low dimension, and the interacting renormalization-group fixed point changes the mean-field exponents. For the tricritical $m^6$ theory the upper critical dimension is three: below $d=3$ the exponents are generally non-mean-field, while at $d=3$ one expects logarithmic corrections to mean-field scaling.

Write $a={\alpha }_2(T)$ and $u={\alpha }_{2n}>0$. At high temperature $a>0$, so $f(m)=a{m}^2+u{m}^{2n}$ has one minimum at $m=0$. At low temperature $a<0$, the origin is a local maximum and two symmetry-related minima appear. The stationary equation isso the equilibrium magnetization isandBecause $a(T)\sim T-T_c$, the two nonzero minima approach zero continuously as $T\uparrow T_c$. The order parameter is continuous while its response becomes singular, so this is a continuous phase transition.

The stationary points obeyNonzero stationary points exist whenso they first appear at the ordered-phase spinodal point $a_2=9a_3^2/(32a_4)$. The disordered state $m=0$ is locally stable for $a_2>0$ and loses that stability at $a_2=0$.

The actual phase boundary is found by requiring a nonzero stationary point $m_{\ast }$ to have the same free energy as $m=0$. Solving $f^{\prime }(m_{\ast })=0$ and $f(m_{\ast })=0$ givesThe disordered state is the global minimum for $a_2>a_3^2/(4a_4)$, the ordered state is the global minimum for $a_2<a_3^2/(4a_4)$, and they coexist at equality.

Since $a_3\ne 0$, the order parameter jumps from zero to $-a_3/(2a_4)$ at coexistence. Hence this model has no continuous phase transition as the phases exchange stability, but it does have a first-order phase transition at the displayed positive value of $a_2$.

The stationary points of the Landau free energy obeyFor $b>0$, $r\ge 0$ makes every term of $f$ nonnegative, so $m=0$ is the unique global minimum. For $r<0$, its curvature $f^{\prime \prime }(0)=2r$ is negative. Setting $x=m^2$ gives $c{x}^2+bx+r=0$, whose unique positive root isAt a nonzero stationary point,Thus both $m=\pm \sqrt{x_{+}}$ are stable and have lower free energy than $m=0$. The equilibrium magnetization isFor fixed $b>0$ and $T\to T_c^{-}$, expand the square root:It tends continuously to zero. Hence the continuous phase transition has the order-parameter critical exponentThis is the mean-field critical exponent; fluctuation corrections beyond Landau theory are not included.

At zero field, write the right-hand side of the self-consistency equation as $G_T(S)=g(4\beta JS)$, with $g(x)=2\sinh x/[1+2\cosh x]$. The origin is always a solution, and the slope there isThe critical crossing occurs when this equals one, givingThis is a continuous phase transition in the mean-field approximation. For $x>0$,so the positive branch is a strictly concave function, while $g$ is odd and bounded by one. For $T\ge T_c$, the slope at zero is at most one and strict concavity puts $G_T(S)$ below $S$ for every $S>0$, leaving only the unmagnetized solution. For $T<T_c$, it initially lies above $S$ but has $G_T(1)<1$; hence there is one positive intersection and, by spin inversion symmetry, one negative intersection.

The curvature of the Helmholtz free energy in the mean-field approximation is $4J[1-G_T^{\prime }(S)]$ per site. It is negative at $S=0$ below $T_c$ and positive at the nonzero intersections, identifying the ordered minima and the unstable zero solution.

The critical temperature and branches here belong to the mean-field approximation. In the exact finite system, spin inversion symmetry forces zero average magnetization at zero field; selecting a broken-symmetry phase requires the thermodynamic limit with a vanishing field of specified sign.

The coarse-grained order parameter is a real scalar field because the microscopic spin has one component. At $B=0$, spin inversion symmetry takes $m\mapsto -m$, so an analytic local Landau free energy contains only even powers. Near a continuous phase transition, the quadratic coefficient changes sign linearly, represented by $a(T-T_c)$ with $a>0$. A positive quartic coefficient stabilizes the density when the quadratic term becomes negative, giving the two minima $m=\pm \sqrt{a(T_c-T)/b}$ below $T_c$.

The ferromagnetic interaction favours neighbouring spins pointing alike, so spatial variation costs energy; its leading long-wavelength form is the positive gradient term $c({\partial }_{x}m{)}^2$. The source term $-Bm$ favours alignment with the applied magnetic field and explicitly breaks spin inversion symmetry at fixed nonzero $B$. Finally $f_0(T)$ is the spin-independent background free-energy density.

The quartic sign can also be checked from part (b): its expansion containswhose quartic coefficient is positive. This is consistent with the proposed Landau-Ginzburg theory, not a tricritical truncation requiring a stabilizing sixth-order term. The microscopic square lattice is two-dimensional; the written gradient describes a profile depending on one coordinate. For general profiles, replace it by $c[({\partial }_{x}m{)}^2+({\partial }_{y}m{)}^2]$.

A phase transition is a qualitative change of thermodynamic phase as control parameters such as temperature, pressure or chemical potential are varied. A genuine equilibrium singularity is a nonanalyticity of the appropriate thermodynamic potential in the thermodynamic limit; finite systems generally show rounded crossovers instead.

An order parameter is a macroscopic quantity that distinguishes the phases. It often vanishes in a symmetric disordered phase and becomes nonzero after spontaneous symmetry breaking, although density-driven transitions need not have that simple symmetry interpretation. It can be a scalar, vector or tensor. At a first-order phase transition an appropriate first derivative of the free energy is discontinuous, and the order parameter commonly jumps; at a continuous phase transition the order parameter can approach zero continuously while a susceptibility or a higher derivative becomes singular.

Three examples are:

These examples also illustrate why an order parameter must reflect the physical distinction between phases rather than merely be any quantity that changes with temperature.

For the Landau free energy $G(\varphi )={\varphi }^6/6+g{\varphi }^4/4+\epsilon {\varphi }^2/2$, positive $g$ gives a continuous phase transition at $\epsilon =0$. For negative $g$, phase coexistence between the disordered global minimum $\varphi =0$ and the ordered global minima occurs on $\epsilon =3g^2/16$, with ${\varphi }^2=-3g/4$. Indeed, on that locus the polynomial is $G(\varphi )={\varphi }^2({\varphi }^2+3g/4{)}^2/6\ge 0$, so these three zeros are global minima. For $g<0$, the disordered and ordered spinodal points are respectively $\epsilon =0$ and $\epsilon =g^2/4$; equality of stationary free energies determines phase coexistence, while loss of a local minimum determines a spinodal point.

For $\varphi =A\cos (q_{0}z)$, the gradient-quartic Brazovskii model has volume-averaged free-energy densityThe averages are $⟨{\cos }^2⟩=⟨{\sin }^2⟩=1/2$ and $⟨{\cos }^2{\sin }^2⟩=1/8$. For $B>0$, the stable amplitude is zero for $a\ge a_c$ and satisfies $A^2=(a_c-a)/(B{q}_0^2)$ below it. The mean-field approximation therefore predicts a continuous phase transition.

At an ordinary thermodynamic critical point, two coexisting phases become indistinguishable: their order parameter difference vanishes, and the correlation length and appropriate response functions typically diverge. A continuous phase transition can be approached there by tuning the thermal and conjugate-field variables. A renormalization-group fixed point controls its singular long-distance behavior. A triple point with three separated minima is not an ordinary thermodynamic critical point, and a tricritical point requires an additional tuning and has a different scaling theory.