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During radiation domination, the weak conversion rate scales as $T^5$ whereas the Hubble parameter scales as $\sqrt{G{g}_{\ast }}{T}^2$. Their crossing fixes the cosmological weak freeze-out temperature. A faster expansion raises it, leaving a larger neutron-to-proton ratio, and shortens the interval for free-neutron decay after freeze-out. Both effects increase the helium-4 mass fraction if the extra component does not independently change reaction rates or inject decay products.

After cosmological weak freeze-out, the surviving neutron fraction is $x_n=r_f(1+r_f{)}^{-1}{e}^{-\Delta t/{\tau }_n}$, where $r_f$ is the initial neutron-to-proton ratio and ${\tau }_n=t_{1/2}/\ln 2$ is the mean lifetime. Baryon number is conserved because a decaying neutron becomes a proton. If almost all surviving neutrons enter helium-4, neutron-limited helium synthesis gives the displayed primordial helium mass fraction. Increasing the half-life increases survival. If the longer lifetime also represents uniformly weaker weak interactions, it raises the temperature of cosmological weak freeze-out and the initial neutron fraction, reinforcing the helium increase. That last conclusion requires specifying how the weak rates change, rather than treating lifetime alone as a complete microscopic model.

A moderately enhanced Hubble parameter raises the primordial helium mass fraction through earlier cosmological weak freeze-out and less free-neutron decay after freeze-out, provided nuclear burning still incorporates nearly all surviving neutrons into helium-4. This provision matters: if expansion carries the gas through the nuclear-burning temperature range faster than the reaction times, neutron-limited helium synthesis no longer applies. More neutrons surviving the bottleneck alone does not prove more final helium in that limit.

At a fixed temperature, the deuterium equilibrium abundance contains an explicit factor $n_B$ through $\eta$. Two nucleons have to encounter each other to make one bound nucleus. Their capture rate per volume is proportional to $n_n{n}_p$, whereas nuclear photodisintegration competes through the very numerous thermal photons. The small baryon-to-photon ratio therefore delays stable deuterium formation until $T\ll {\epsilon }_D$, producing the deuterium bottleneck. Changing the cosmological baryon density changes both its release time and the subsequent efficiency of nuclear burning. The residual primordial deuterium abundance is particularly sensitive to these rates: on the usual nucleosynthesis branch, increasing $n_B$ burns more deuterium into heavier nuclei and lowers the remaining D/H. The positive dependence of the instantaneous equilibrium expression and the negative dependence of the final relic D/H are different statements.

By contrast, once nuclear reactions are efficient, nearly every surviving neutron ends in helium-4. Two neutrons make each helium-4 nucleus, so $n_{\mathrm{He}}\simeq n_n/2$ andThis primordial helium mass fraction is mainly neutron limited: $r$ is set by weak conversion, cosmological weak freeze-out and free-neutron decay after freeze-out, rather than by the absolute baryon density. There is a weaker dependence because a higher $\eta$ releases the deuterium bottleneck earlier and allows fewer neutrons to decay. Thus $Y_P$ is comparatively insensitive, not exactly independent, of $n_B$. At such exceptionally small baryon densities that nuclei never form efficiently, the neutron-limited approximation would fail.

Use natural units with $c=\hslash =k_B=1$ and the unreduced Planck mass $M_{\mathrm{Pl}}=G^{-1/2}$. In a radiation-dominated universe, the effective number of relativistic energy degrees of freedom $g_{\ast }=\mathcal{N}$ givesThe ratio of weak conversion rate to expansion rate is proportional to $T^3$, so it decreases as the universe cools. Cosmological weak freeze-out occurs approximately at $\Gamma =H$, givingFor $g_{\ast }=10.75$, $G_F=10^{-5}{\mathrm{GeV}}^{-2}$ and $M_{\mathrm{Pl}}=1.22\times 10^{19}\mathrm{GeV}$ this estimate is $1.65\mathrm{MeV}$. Equivalently $g_{\ast }^{1/6}\simeq 1.5$ is only a mild multiplicative correction. The rate itself was given only to order of magnitude, so this is a decoupling scale, not a precise prediction for the weak freeze-out abundance.

Both neutrons and protons are nonrelativistic at this temperature. The nonrelativistic Maxwell--Boltzmann number density follows by the Gaussian momentum integral:Their equal spin degeneracies are $g_n=g_p=2$. Chemical equilibrium of the weak reaction gives ${\mu }_n+{\mu }_{{\nu }_e}={\mu }_p+{\mu }_e$; with negligible lepton asymmetry, ${\mu }_n\simeq {\mu }_p$. Taking the ratio and setting the nearly equal nucleon masses equal only in the prefactor gives the neutron-proton chemical equilibrium resultThe common baryon normalization cancels. Keeping the exact mass prefactor changes this by only order $Q/m_p$. Thus the printed simple exponential is the usual nonrelativistic equal-mass-prefactor approximation. Using $Q\simeq 1.29\mathrm{MeV}$ with the rough decoupling scale above gives a ratio of order one half; the rate's omitted numerical factors and gradual freeze-out must be included before using a more accurate neutron abundance.

At neutrino decoupling, the interaction rate is comparable with the Hubble parameter. Equating the supplied rates givesHere the Planck mass is the unreduced $m_P=G^{-1/2}\simeq 1.22\times 10^{19}\mathrm{GeV}$ in natural units, $G_F\simeq 10^{-5}{\mathrm{GeV}}^{-2}$, and the effective number of relativistic energy degrees of freedom is $g_{\ast }=10.75$. The supplied rate gives an order-of-magnitude neutrino decoupling estimate; a precise neutron-proton conversion temperature uses its own weak-rate coefficients.

The chemical equilibrium condition for $n+{\nu }_e\leftrightarrow p+e^{-}$ is ${\mu }_n+{\mu }_{{\nu }_e}={\mu }_p+{\mu }_e$. With negligible lepton chemical potentials, ${\mu }_n={\mu }_p$. The nonrelativistic Maxwell--Boltzmann number density therefore givesbecause $g_n=g_p=2$ and the small mass difference can be neglected in the prefactor. This is the neutron-proton chemical equilibrium relation.

For the deuterium equilibrium abundance, ${\mu }_D={\mu }_n+{\mu }_p$ because photons have zero chemical potential. The sign convention in the paper is important: $B=m_D-m_n-m_p<0$, while the positive nuclear binding energy is ${\Delta }_D=-B$. Using spin multiplicities $g_D=3$, $g_n=g_p=2$ givesWith $n_B=\eta n_{\gamma }$, $m_n\simeq m_p\simeq m_N$, $m_D\simeq 2m_N$ and photon number density $n_{\gamma }=2\zeta (3)T^3/{\pi }^2$, this becomesHere $X_D=n_D/n_B$ is a number fraction; the fraction of baryons bound in deuterium is $2X_D$. The formula estimates the onset of the deuterium bottleneck opening while depletion of free neutrons and protons remains small. Because $\eta \ll 1$, stable deuterium becomes abundant only far below the positive nuclear binding energy, not simply at $T={\Delta }_D$.

Let $T_f$ denote cosmological weak freeze-out of the neutron-to-proton ratio, $r_f=e^{-Q/T_f}$, and let $t_N$ mark efficient nuclear burning. Free-neutron decay after freeze-out givesAlmost every surviving neutron enters helium-4, whose atomic nucleus contains two neutrons and four baryons. Thus neutron-limited helium synthesis givesA longer neutron half-life leaves more neutrons available, increasing the primordial helium mass fraction. If the longer lifetime reflects weaker weak interactions, the accompanying earlier cosmological weak freeze-out can reinforce that effect.

During radiation domination, $H\propto \sqrt{G{g}_{\ast }}{T}^2$ whereas the weak conversion rate is proportional to $T^5$. Hence $T_f\propto (G{g}_{\ast }{)}^{1/6}$. Increasing the effective number of relativistic energy degrees of freedom raises $T_f$, increasing $r_f$, and shortens the interval for free-neutron decay after freeze-out. Both increase the primordial helium mass fraction while nuclear burning remains efficient. The same reasoning gives the primordial helium response to a varying gravitational constant: larger $G$ over this interval produces more helium, with fixed microscopic rates and the approximate Friedmann equation unchanged. Smaller $G$ has the opposite effect. A particular varying-$G$ model must specify its background expansion and time history; the simple trend must not be extrapolated to changes so large that nuclear burning itself fails.

Use natural units $\hslash =c=k_B=1$ and the unreduced Planck mass $M_P=G^{-1/2}$. Neutrino decoupling occurs when the weak interaction rate falls below the Hubble parameter. The weak-decoupling temperature estimate equates the given rate with the radiation-era expansion rate:Here $g_{\ast }$ counts the effective number of relativistic energy degrees of freedom, and the Fermi constant is $G_F\simeq 10^{-5}{\mathrm{GeV}}^{-2}$. The omitted reaction-rate coefficients make this an order-of-magnitude estimate: decoupling occurs at a temperature of order one MeV.

The charge-conserving channel is $n+{\nu }_e\leftrightarrow p+e^{-}$, together with $p+{\bar{\nu }}_e\leftrightarrow n+e^{+}$. The positron sign in the printed neutron-capture channel violates electric charge conservation. Chemical equilibrium requires ${\mu }_n+{\mu }_{{\nu }_e}={\mu }_p+{\mu }_e$. Negligible lepton chemical potentials therefore give ${\mu }_n\simeq {\mu }_p$. Since neutrons and protons are nonrelativistic particles, their Maxwell-Boltzmann distribution givesBoth nucleons have two spin states, and their masses agree closely in the prefactor. Thus neutron-proton chemical equilibrium impliesThe heavier neutron is suppressed by a Boltzmann factor.

For the deuterium equilibrium abundance, retain the paper's convention $B=m_D-m_n-m_p<0$; the positive nuclear binding energy is ${\epsilon }_D=-B\simeq 2.22\mathrm{MeV}$. Chemical equilibrium of $n+p\leftrightarrow D+\gamma$ gives ${\mu }_D={\mu }_n+{\mu }_p$ because the equilibrium photon chemical potential vanishes. Using the nonrelativistic Maxwell--Boltzmann number density for each species and dividing givesHere $g_D=3$ and $g_n=g_p=2$. With the baryon-to-photon ratio $\eta =n_B/n_{\gamma }$, the photon number density $n_{\gamma }=2\zeta (3)T^3/{\pi }^2$, and $m_D\simeq 2m_N$, $m_n\simeq m_p\simeq m_N$, this becomesIn this convention $X_D=n_D/n_B$ counts nuclei, so its contribution to the fraction of baryons in deuterium is $2X_D$.

The deuterium bottleneck explains why helium-4 formation waits until $T$ is far below ${\epsilon }_D$. At higher temperature, there are vastly more photons than baryons; even the dilute energetic tail can destroy newly formed deuterium. A crude estimate balances ${\eta }^{-1}{e}^{-{\epsilon }_D/T}$ against one, giving $T\sim {\epsilon }_D/\log ({\eta }^{-1})\sim 0.1\mathrm{MeV}$ for $\eta$ of order $10^{-9}$. The power-law factors in the deuterium equilibrium abundance and the nuclear reaction rates refine this estimate. Once stable deuterium accumulates, further reactions can efficiently place nearly all surviving neutrons into helium-4.

Write $r_N=n_n/n_p$ at the onset of nuclear burning. Each helium-4 nucleus requires two neutrons and contains four baryons. Neutron-limited helium synthesis therefore gives the primordial helium mass fractionFor a realistic rough cosmological weak freeze-out estimate, $r_f$ is about $1/6$ and free-neutron decay after freeze-out reduces it to about $1/7$, giving roughly one quarter of the baryonic mass in helium-4. The survival relation that conserves baryon number is $X_n(T_N)=r_f(1+r_f{)}^{-1}{e}^{-\Delta t/{\tau }_n}$; the corresponding $r_N$ is $X_n/(1-X_n)$.

The rough neutrino decoupling rate by itself does not determine that one-quarter value. Substituting $T_d=1.8\mathrm{MeV}$ literally into $e^{-Q/T_d}$ would give $r\simeq 0.49$ and $Y_4\simeq 0.65$ before neutron decay. Neutron-proton chemical equilibrium persists to a lower temperature, approximately $0.7$--$0.8\mathrm{MeV}$ once the actual conversion rates are included. The rate scaling fixes the MeV scale; accurate abundances need the conversion coefficients and the delay through the deuterium bottleneck. This sequence is described in David Tong's discussion of nucleosynthesis.

Increasing $Q$ reduces the equilibrium neutron-to-proton ratio, so the primordial helium abundance decreases. Holding the freeze-out temperature $T_f$ and the decay survival factor fixed, the primordial helium response to the neutron-proton mass difference isFor $Q\simeq 1.29\mathrm{MeV}$ and $T_f=0.7$--$0.8\mathrm{MeV}$ this is about $0.85$--$0.87$, a reduction of roughly fifteen percent. A larger $Q$ also changes neutron decay and detailed weak rates; their quantitative effects require more microscopic information. The sign from the Boltzmann factor is already clear.

For a moderately faster cosmic expansion that still permits efficient nuclear burning, the hydrogen mass fraction is smaller, since cooling from cosmological weak freeze-out to helium formation takes less time, fewer free neutrons decay into protons, and more surviving neutrons enter helium-4. If the change also affects cosmological weak freeze-out, its higher freeze-out temperature leaves a larger initial neutron-to-proton ratio and reinforces the helium increase. The conclusion assumes efficient neutron-limited helium synthesis: an unspecified arbitrarily rapid expansion could instead outrun the nuclear reactions, so the nuclear-burning qualification of the helium expansion-rate response prevents an unconditional assertion.

The weak-conversion rate per expansion time falls as $T^3$. Below the stated threshold it becomes less than one, so neutron-proton interconversion cannot track the rapidly changing equilibrium ratio: cosmological weak freeze-out occurs. Free neutrons subsequently decay, reducing their abundance until nuclei can survive photodissociation. Once the deuterium bottleneck is passed, nuclear reactions rapidly assemble neutrons into the strongly bound helium-4 nucleus. The short available time, low density and missing stable mass-five and mass-eight nuclei impede extensive production of heavier nuclei, leaving nearly all surviving neutrons in helium.

If $r=n_n/n_p$ just before helium formation, each helium nucleus uses two neutrons and two protons, so $n_{\mathrm{He}}=n_n/2$. Neglecting binding-energy corrections to nuclear masses,The remaining protons mainly become hydrogen. Counting all four helium nucleons, rather than only the captured neutrons, is essential to this mass fraction.

During radiation domination, the effective number of relativistic energy degrees of freedom, denoted $g_{\ast }$, gives the energy densityThe paper's ${\mathcal{N}}_{\mathrm{eff}}$ is this $g_{\ast }$; it is not the conventionally normalized effective number of neutrino species. With the specified reduced Planck mass, the Friedmann equation reads $H^2={\rho }_R/(3M_{\mathrm{Pl}}^2)$, whenceWrite the weak interaction conversion rate as $\Gamma =A{G}_F^2{T}^5$. The ratio $\Gamma /H$ scales as $T^3$, so it falls during cooling: conversion eventually becomes too slow to maintain neutron-proton chemical equilibrium. Equating the conversion and expansion rates givesOn suppressing the numerical coefficient, the cosmological weak freeze-out temperature is consequentlyThe one-sixth power reflects a balance between a conversion rate proportional to $T^5$ and a Hubble parameter proportional to $\sqrt{g_{\ast }}{T}^2$.

Work in natural units $\hslash =c=k_B=1$, at temperatures far below the $W$-boson mass but of order or above the electron mass. The Fermi interaction then supplies a local four-fermion amplitude. The Fermi constant has dimension energy${}^{-2}$. In scattering of a thermal lepton from a nonrelativistic nucleon, the nucleon current matrix element has size $m_N$, while the lepton current has size $T$. Thus $\mathcal{M}\sim G_F{m}_{N}T$. The two-body relativistic scattering cross-section contains the kinematic factor $s^{-1}\sim m_N^{-2}$; when the final and initial lepton energies are comparable, their momentum ratio is of order one. Consequently $\sigma \sim |\mathcal{M}{|}^2/m_N^2\sim G_F^2{T}^2$. This estimates temperatures above the electron mass and mass-splitting thresholds; those scales only affect the dimensionless rate function near freeze-out.

The light leptons in the thermal bath have number density $n\sim T^3$ and speed of order unity. Their conversion rate per nucleon is thereforeFor example, $n+{\nu }_e\leftrightarrow p+e^{-}$ and $n+e^{+}\leftrightarrow p+{\bar{\nu }}_e$ change the neutron-to-proton ratio. The bath density here is the lepton density, not the much smaller baryon density. Dimensionless weak couplings, phase-space integrals and the several reaction channels set a numerical coefficient. Electron masses and the neutron-proton splitting also become important for a precision rate near cosmological weak freeze-out.

Extra relativistic neutrino species increase the effective number of relativistic energy degrees of freedom. At fixed temperature the Hubble parameter rises as $g_{\ast }^{1/2}$, while the standard conversion rate is unchanged. Consequently cosmological weak freeze-out moves to higher temperature, $T_F\propto g_{\ast }^{1/6}$, and the neutron-to-proton ratio $r_F=e^{-Q/T_F}$ increases. The initial neutron fraction $r_F/(1+r_F)$ therefore increases as well.

The quicker expansion also reduces the cosmic time required to cool to the deuterium bottleneck temperature: during radiation domination, $t\propto g_{\ast }^{-1/2}{T}^{-2}$ while the thermal count is roughly constant. Fewer neutrons decay before burning. Both factors in the neutron budget increase, giving a larger final helium-4 mass fraction. This is the primordial helium response to extra relativistic species, under the assumption that the additional species contribute mainly to expansion rather than independently changing the conversion rates.

The small baryon-to-photon ratio suppresses nuclear equilibrium abundances through the factor ${\eta }^{A-1}$. Cooling eventually makes the binding-energy exponential favourable, but the deuterium bottleneck delays substantial nuclear burning until well after cosmological weak freeze-out. In ordinary Big Bang nucleosynthesis, nearly every neutron surviving that delay ends up in helium-4. This makes the final primordial helium mass fraction chiefly a neutron budget rather than an unrestricted equilibrium abundance.

Let $r_F$ be the neutron-to-proton ratio at freeze-out, let $\Delta t$ be the delay until effective nuclear burning, and let ${\tau }_n$ be the neutron mean lifetime. The initial fraction of baryons which are neutrons is $x_{n,F}=r_F/(1+r_F)$. Because neutron decay converts a neutron into a proton, total baryon number remains constant, while the neutron fraction becomes $x_{n,B}=x_{n,F}{e}^{-\Delta t/{\tau }_n}$. Each helium nucleus uses two neutrons and four baryons. Hence neutron-limited helium synthesis givesEquivalently, $Y_4=2r_B/(1+r_B)$ with $r_B=x_{n,B}/(1-x_{n,B})$. This accounts for the extra protons produced by neutron decay; multiplying $r_F$ alone by the survival factor would miss their contribution. The following responses refer to ordinary neutron-limited burning, without exotic particle injection or a change to the nuclear network.

Under the usual interpretation that the extra force simply slows otherwise adiabatic expansion, without changing reaction rates or injecting particles, the primordial hydrogen mass fraction would be larger. A smaller Hubble parameter makes cooling slower, delays the end of the deuterium bottleneck, and permits more free-neutron decay after freeze-out before nuclear assembly. If the reduced expansion also keeps weak conversions effective longer, the lower eventual cosmological weak freeze-out temperature further reduces the neutron-to-proton ratio. Both effects lower the primordial helium mass fraction and raise the remaining hydrogen mass fraction.

For fixed initial neutron fraction $x_{n,1}=n_n/(n_n+n_p)$, the post-freeze-out estimate is $x_n=x_{n,1}{e}^{-(t_N-t_1)/{\tau }_n}$, where $t_N$ is the onset of efficient nuclear assembly. Thus $Y_p\simeq 2x_n$ decreases when cooling delays $t_N$. The extra time is the time to reach the nuclear-assembly temperature, not an increase in the specified clock interval $300-1$ seconds. An unspecified force that also reheats the plasma, changes weak rates or causes recollapse would require additional information; the simple expansion-only interpretation is essential to this expectation.

At temperatures above a few MeV, weak interactions such as $n+{\nu }_e\leftrightarrow p+e^{-}$ and $n+e^{+}\leftrightarrow p+{\bar{\nu }}_e$ maintain neutron-proton chemical equilibrium. Negligible lepton chemical potentials give the neutron-to-proton ratio $r_{\mathrm{eq}}=n_n/n_p=\exp [-\Delta /(k_{B}T)]$, where $\Delta =(m_n-m_p)c^2\simeq 1.293\mathrm{MeV}$. At high temperature this ratio is nearly one.

During radiation domination, the interaction time grows as $T^{-5}$, faster than the expansion time $T^{-2}$. Their crossing therefore produces cosmological weak freeze-out. If $\Theta =T/(10^{10}\mathrm{K})$, equating the displayed order-of-magnitude times gives ${\Theta }_f^{-5}\sim g_{\ast }^{-1/2}{\Theta }_f^{-2}$, soUsing $H^{-1}=2t$ instead of $t$ changes only the order-one coefficient. Before electron-positron annihilation, the usual effective relativistic count is $g_{\ast }=2+(7/8)(4+6)=10.75$. The factor $7/8$ weights fermionic relative to bosonic energy density.

After freeze-out, free neutrons decay while protons increase correspondingly. Define the neutron baryon fraction $X_n=n_n/(n_n+n_p)$. In the instantaneous-freeze-out estimate,where ${\tau }_n=t_{1/2}/\ln 2$ is the neutron mean lifetime. Hence the ratio at the onset of nuclear synthesis isThis expression accounts for the protons produced by neutron decay.

Nuclear burning initially waits at the deuterium bottleneck: although deuterium is bound by about $2.2\mathrm{MeV}$, the many photons per baryon can still photodissociate it. Roughly, ${\eta }_b^{-1}{e}^{-B_D/(k_B{T}_N)}\sim 1$ sets the bottleneck temperature, with refinements from reaction rates and phase space. Around $k_B{T}_N\sim 0.1\mathrm{MeV}$, deuterium survives, reactions through deuterium, tritium and helium-3 rapidly build tightly bound helium-4, and nearly all surviving neutrons are captured.

Thus $n_{\mathrm{He}}\simeq n_n/2$ and the primordial helium mass fraction isFor the standard estimate $r_N\simeq 1/7$, neutron and proton constituent fractions are $1/8$ and $7/8$, respectively, and $Y_{\mathrm{He}}\simeq 1/4$. Free neutrons are negligible after capture. The remaining hydrogen mass fraction is about $3/4$, and the helium-to-hydrogen number ratio is about $1/12$.

The printed numerical time coefficients are schematic, not a precision prediction of this quarter fraction: their literal crossing with $g_{\ast }=10.75$ gives $k_B{T}_f\simeq 1.28\mathrm{MeV}$. Keeping physical weak-rate coefficients and the gradual freeze-out instead gives an effective freeze-out around $0.7$–$0.8\mathrm{MeV}$, followed by decay over a few minutes. The abundance formulas above explain the standard quarter fraction and its parameter dependence without treating the rounded time formulas as exact nuclear-rate data.

For a nonrelativistic particle, $E(p)=m{c}^2+p^2/(2m)$. The Gaussian integral yieldsIndeed ${\int }_0^{\infty }{p}^2{e}^{-p^2/(2m{k}_{B}T)}dp=\sqrt{\pi }(2m{k}_{B}T{)}^{3/2}/4$, which combines with $4\pi /h^3$ to give the prefactor. For the two species this givesChemical equilibrium imposes ${\mu }_a+{\mu }_{\alpha }={\mu }_b+{\mu }_{\beta }$. If the two massless bath species have zero chemical potentials, then ${\mu }_a={\mu }_b$; their masses alone do not imply this chemical-potential condition.

Weak reactions such as $n+{\nu }_e\leftrightarrow p+e^{-}$, with leptons treated as relativistic, interconvert neutrons and protons. Negligible lepton chemical potentials give approximately $n_n/n_p=\exp [-(m_n-m_p)c^2/(k_{B}T)]$, since their degeneracies and masses are nearly equal. Equilibrium favors protons increasingly as temperature falls. But the weak reaction rate decreases faster than the expansion rate and eventually falls below it: cosmological weak freeze-out prevents the ratio from following its equilibrium exponential to zero. Free neutrons subsequently decay, reducing the frozen ratio further.

In Big Bang nucleosynthesis, cooling eventually makes deuterium survive photodissociation. Nuclear reactions then build helium through deuterium and the light intermediate nuclei, locking almost all surviving neutrons into stable helium-four. Neglecting binding-energy corrections and taking $r=n_n/n_p\le 1$, each helium nucleus uses two neutrons and two protons, so $n_{\mathrm{He}}=n_n/2$ andFor example $r=1/7$ gives a helium mass fraction $1/4$, with the remaining baryons predominantly hydrogen.

At weak freeze-out, photons, electrons, positrons and all four neutrino flavors are relativistic and approximately at the same temperature. The effective number of relativistic energy degrees of freedom changes fromThe expansion rate at fixed temperature is larger by $\sqrt{50/43}\simeq 1.078$. Equating the supplied weak interaction time with the supplied age gives $T_f^3=\sqrt{g_{\ast }}$ when $T_f$ is measured in MeV. ThereforeEarlier cosmological weak freeze-out at a higher temperature leaves more neutrons. With negligible chemical potentials, the neutron-to-proton ratio in equilibrium is $r_f=\exp (-Q/T_f)$, where $Q=m_n-m_p\simeq 1.293\mathrm{MeV}$. If almost all surviving neutrons enter helium-4, the primordial helium mass fraction before neutron decay is $Y_f=2r_f/(1+r_f)$. Literal use of the given rate normalizations yieldsEquivalently, the leading response is $\delta Y_f/Y_f=[Q/(T_f(1+r_f))]\delta T_f/T_f$. This is a roughly one-percentage-point absolute increase in the helium fraction, rather than a one-percent relative increase.

The deuterium bottleneck delays nuclear burning, allowing free-neutron decay after freeze-out. If its end temperature is $T_N$, and ${\tau }_n$ is the neutron mean life, a sharper instantaneous-freeze-out estimate conserves total baryon number and givesThis formula evolves the neutron fraction, not just the neutron-to-proton ratio, because each neutron decay also creates a proton. After electron annihilation, let $r_T=(4/11{)}^{1/3}$. The radiation counts relevant to the age at fixed $T_N$ areConsequently $t_N^{(4)}/t_N^{(3)}\simeq \sqrt{3.36/3.82}\simeq 0.939$. Less time is available for neutron decay, adding to the helium increase. As an explicit illustrative completion, $T_N=0.07\mathrm{MeV}$ and ${\tau }_n\simeq 880\mathrm{s}$ give an increase of approximately $0.012$ in this toy model. The precise helium fraction requires the nuclear-burning temperature, baryon abundance and properly normalized weak rates; the question supplies only approximate time laws. In particular, the large no-decay fractions in the table must not be interpreted as precise predictions for the observed primordial abundance. The robust effect is extra relativistic energy raises the primordial helium fraction, with an absolute change of order $10^{-2}$ for one thermally populated flavor.

Two effects must be distinguished in Big Bang nucleosynthesis. The positive extra neutrino energy density increases the Hubble parameter through the Friedmann equation. Holding weak rates fixed, faster expansion causes earlier neutron-proton cosmological weak freeze-out, leaving more neutrons, and leaves less time for neutron decay before nuclear reactions begin. Both tendencies increase the primordial helium mass fraction.

Electron-flavor degeneracy also changes the charged-current balance directly. Chemical equilibrium for $n+{\nu }_e\leftrightarrow p+e^{-}$ gives, with negligible electron chemical potential,This is the primordial helium response to electron-neutrino degeneracy. Positive ${\xi }_{{\nu }_e}$ favors conversion of neutrons to protons and reduces the neutron abundance; negative ${\xi }_{{\nu }_e}$ favors the opposite balance. When neutrons are the limiting ingredient and nearly all surviving neutrons enter helium-4, the neutron-limited helium synthesis estimate isIn this usual proton-rich regime, the direct electron-neutrino effect lowers $Y_p$ for positive degeneracy and raises it for negative degeneracy, other conditions held fixed. At sufficiently large negative degeneracy the equilibrium ratio can instead exceed one; protons then become limiting. The corresponding ideal complete-capture estimate is $Y_p\simeq 2\min (r,1)/(1+r)$, so the neutron-limited trend is not a universal monotonic law at arbitrary negative chemical potential. Degeneracy in the other flavors primarily affects helium through the expansion rate in this simplified discussion.

For very large degeneracy the weak reaction rates themselves also change, so a quantitative freeze-out calculation must include both the altered distributions and the altered expansion rate. The two effects can compete for a positive electron-neutrino asymmetry. The primordial helium mass fraction change is not determined by $|{\mu }_{\nu }|$ alone: its flavor and sign matter as well as its energy density.

The effective number of relativistic energy degrees of freedom count two photon polarizations, four electron/positron spin states, and six neutrino/antineutrino states, with the Fermi-Dirac distribution factor $7/8$ for fermions. Treating these species as relativistic and at a common temperature gives $\boxed{g_{\ast }=2+(7/8)(4+6)=10.75}$.

The mass-equivalent radiation mass density is $\rho =({\pi }^2/30)g_{\ast }(k_{B}T{)}^4/({\hslash }^3{c}^5)$. Therefore the Friedmann equation givesAt $T_0=10^{10}\mathrm{K}$, $H_0\simeq 0.503{\mathrm{s}}^{-1}$. Equating the specified weak interaction rate to $H_0(T/T_0{)}^2$ gives $(T_{\ast }/T_0{)}^3=H_0/(1{\mathrm{s}}^{-1})$ and henceThe approximate equilibrium neutron-to-proton ratio, neglecting chemical potentials, is $r_{\ast }\simeq \exp [-(m_n-m_p)c^2/(k_B{T}_{\ast })]$, about $0.152$ using the mass difference $1.293\mathrm{MeV}$. This is a freeze-out estimate rather than a detailed reaction-network computation.

After weak cosmological weak freeze-out, free neutrons undergo beta-minus decay; neutrinos decouple, and electron-positron annihilation heats the photons relative to the neutrinos. Initially the abundant energetic photons destroy deuterium almost as soon as it forms. Once the deuterium bottleneck ends, nuclear reactions rapidly pass through deuterium, tritium and helium-three to helium-4. Reactions eventually become too slow compared with cosmic expansion; nearly all surviving neutrons are bound in helium-four. Its mass fraction is approximately $Y_4=2r/(1+r)$, where $r$ is evaluated when nuclear assembly begins.

Increasing $g_{\ast }$ increases the Hubble parameter, raises $T_{\ast }$, increases the freeze-out neutron-to-proton ratio, and leaves less time for free-neutron decay after freeze-out. Both effects increase $Y_4$; decreasing $g_{\ast }$ reverses them. Most deuterium is only an intermediate product and is burned into helium, so its residual abundance and its absolute change are tiny compared with the helium mass fraction. This does not imply a negligible fractional change in residual deuterium. Faster expansion also shortens the time available to burn it, and its relative abundance can be appreciably sensitive to extra radiation. The distinction matters when interpreting the final wording of the question; joint deuterium and helium abundances constrain extra relativistic species, as discussed in the Particle Data Group nucleosynthesis review.

If the Friedmann equation remains approximately $H^2=8\pi G\rho /3$, radiation domination and fixed weak microphysics give $H\propto \sqrt{G}{T}^2$ and a neutron-proton conversion rate proportional to $T^5$. Cosmological weak freeze-out then occurs at $T_f\propto G^{1/6}$. Increasing $G$ during this era raises the neutron-to-proton ratio at freeze-out and shortens the time for free-neutron decay after freeze-out. Both increase the primordial helium mass fraction when neutron-limited helium synthesis remains efficient. Arbitrary variation of $G$ over time requires its history and the full gravitational field equations; this scaling is a controlled background approximation, rather than a complete model of gravity with arbitrary time dependence.