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The energy eigenspace at $E$ is the vector subspacewhere $H$ is the Hamiltonian operator and $I$ is the identity operator. It is nonzero exactly when $E$ is an energy eigenvalue. Its dimension is the multiplicity of that energy eigenvalue; degenerate energy levels have multiplicity greater than one. The ground-state subspace is ${\mathcal{E}}_{E_0}$, and its dimension is the ground-state degeneracy. A vector in an energy eigenspace need not be one of a specially chosen orthonormal basis of energy eigenstates.

Linearity makes the useful point immediate: if $H{\varphi }_1=E{\varphi }_1$ and $H{\varphi }_2=E{\varphi }_2$, then $H(a{\varphi }_1+b{\varphi }_2)=E(a{\varphi }_1+b{\varphi }_2)$. Every normalized nonzero combination stays in the same energy eigenspace. For a time-independent Hamiltonian operator, its evolution is multiplication by the common global phase $e^{-iEt/\hslash }$, so it is a stationary state. A quantum superposition within a degenerate energy eigenspace can change spatial shape when its coefficients are chosen differently, but its density does not subsequently beat under this unchanged Hamiltonian operator.

Across distinct energy eigenspaces, relative quantum phases evolve. For orthonormal eigenfunctions ${\varphi }_1,{\varphi }_2$ of the Hamiltonian operator with energy eigenvalues $E_1\ne E_2$, an equal-weight quantum superposition hasand position probability densityThe interference term can change local probabilities even though the Born rule assigns the same time-independent probability $1/2$ to each energy measurement outcome. Orthogonality makes its integral zero, preserving wavefunction normalization. This pure state is not a stationary state; some particular measurement distributions may nevertheless remain constant. An incoherent mixed state with the same energy populations has no such interference term.

For the pictured infinite square well, $\theta =3E_{1}t/\hslash$ and the interference repeats after $T=2\pi \hslash /(3E_1)$. At $t=0$, direct integration gives $⟨x⟩=L/2-16L/(9{\pi }^2)$; halfway through the period it is $L/2+16L/(9{\pi }^2)$. This is a moving expectation value, rather than a trajectory of an individual particle. The distinction between an energy eigenspace and a combination of different energy eigenspaces is what makes the different behavior possible.

A ground state is a normalized energy eigenstate that attains the lowest possible energy of a quantum system. Precisely, let the Hamiltonian operator $H$ be a self-adjoint operator bounded below on a Hilbert space, and write $E_{\ast }=\inf \sigma (H)$ for the infimum of its spectrum. A ground state is a unit vector ${\psi }_0$ in the operator domain $D(H)$ satisfyingThus a ground state exists exactly when the spectral bottom $E_{\ast }$ is an energy eigenvalue. The lowest energy eigenvalue among some listed bound states is insufficient if other parts of the spectrum lie below it. The ground-state subspace collects all minimizing energy eigenstates; it can have ground-state degeneracy. The quantum variational principle characterizes $E_{\ast }$ as the infimum of normalized energy expectation values. ^[ref].

For the one-dimensional quantum harmonic oscillator, the ground state has energy $\hslash \omega /2$ above the minimum of the potential energy. This zero-point energy is compatible with being the lowest allowed energy: a localized wavefunction cannot simultaneously have zero kinetic energy. For a free particle on the whole line, the spectral bottom is zero but is unattained by any normalizable wavefunction; see ground-state energy. A lower bound therefore need not describe a physically preparable energy eigenstate.

The ground state supplies a reference for excitation costs and for the quantum variational principle. A ground state is also a stationary state under a time-independent Hamiltonian operator: its quantum phase changes, while its position probability density stays fixed. A nonzero ground-state energy does not imply motion along a classical trajectory, and ground-state degeneracy means there need not be a unique lowest quantum state.

When a ground state exists, its ground-state degeneracy is the dimension of the ground-state subspace:Here $I$ is the identity operator, and the kernel of a linear map is taken within the operator domain of the Hamiltonian operator $H$. The count concerns linearly independent energy eigenstates, rather than every normalized quantum superposition or every choice of global phase. Even a single energy eigenspace contains infinitely many representing vectors; its dimension measures independent freedom. Ground-state degeneracy is the lowest-energy instance of degenerate energy levels.

For an exact finite model with energy unit $\epsilon >0$, let the Hamiltonian operator be the diagonal matrixIts ground-state energy is zero and $g_0=2$: the first two coordinate unit vectors $e_1,e_2$ span the ground-state subspace. Every normalized $a{e}_1+b{e}_2$, with $|a{|}^2+|b{|}^2=1$, is a ground state, including $(e_1+e_2)/\sqrt{2}$. Its energy measurement is certain to return zero, even though a measurement distinguishing $e_1$ from $e_2$ need not have a definite outcome. Under the unchanged Hamiltonian operator, this quantum superposition is a stationary state because both components acquire the same global phase.

Ground-state degeneracy matters when an interaction selects or splits previously equal energy eigenvalues. In the finite model, adding $\epsilon \mathrm{diag}(\delta ,-\delta ,0,0)$ with $0<\delta <2$ gives the formerly lowest pair the distinct energies $\pm \epsilon \delta$, leaving a unique ground state. This direct calculation illustrates why degenerate perturbation theory first examines the perturbation inside the whole ground-state subspace.

A classical continuous-symmetry model can instead have a manifold of minimizing configurations, such as the sphere of orientations of a Néel state in an isotropic Heisenberg antiferromagnet. That geometric description does not by itself count the dimension of a finite quantum ground-state subspace.

The ground-state energy $E_0$ is the energy eigenvalue attained by a ground state. For a self-adjoint operator $H$ bounded below, distinguish this attained value from the always-defined spectral bottom $E_{\ast }=\inf \sigma (H)$. When a ground state exists, $E_0=E_{\ast }$. Some usage calls $E_{\ast }$ the ground-state energy even when it is unattained; here an unattained bottom is explicitly identified as an infimum. The quantum variational principle statesApproaching this infimum with trial wavefunctions does not ensure that a minimizing wavefunction exists. ^[ref].

For the whole-line free particle with mass $m>0$,Its spectrum is continuous and contains no energy eigenvalues represented by normalizable wavefunctions. The Fourier transform makes $H$ multiplication by ${\hslash }^2{k}^2/(2m)$; a fixed energy restricts $k$ to a set of zero length, on which a nonzero square-integrable function cannot be supported. ^[ref]. An explicit family of normalized Gaussian wave packets demonstrates how the bottom is approached:The formula follows from ${\psi }_s^{\prime }=-x{\psi }_s/(2s^2)$, integration by parts, and $⟨x^2{⟩}_s=s^2$. Every finite width gives positive kinetic energy. At zero energy, $H\psi =0$ would require an affine function on the whole line, which is never a nonzero normalizable wavefunction. Spreading a Gaussian wave packet indefinitely produces an unattained infimum, rather than a zero-energy ground state.

An additive choice of energy origin changes the numerical ground-state energy without changing the ground-state subspace. For $H^{\prime }=H+CI$, every energy eigenvalue becomes $E^{\prime }=E+C$, while all differences $E_j-E_i$ stay fixed. Time evolution gains only the global phase $e^{-iCt/\hslash }$. This makes excitation costs and spectroscopic differences more intrinsic than the isolated number $E_0$.

The ground-state subspace is the eigenspace of a Hamiltonian operator at its lowest eigenvalue $E_0$. A computational history state construction can have many valid quantum witnesses, hence a degenerate ground space. Perturbation bounds must optimize on this entire subspace, rather than on a chosen basis of ground states.

For a self-adjoint Hamiltonian operator bounded below with ground-state energy $E_0$, every admissible nonzero trial wavefunction has a Rayleigh quotient at least $E_0$. To see this explicitly in a complete orthonormal eigenbasis, write $|\psi ⟩={\sum }_n{c}_n|n⟩$ with $H|n⟩=E_n|n⟩$. ThensoFor continuous spectral components, the spectral theorem replaces the sum by an integral with the same nonnegative integrand. Equality requires the trial quantum state to lie entirely in the ground-state subspace. The variational method chooses a tractable family, evaluates the quotient and minimizes over its parameters. This gives an upper bound; enlarging the family can only improve that bound. The trial must belong to the operator domain for the operator expression above, or have finite energy in the corresponding quadratic-form version of the quantum variational principle.

For the oscillator, use the standard kinetic operator $T=-{\hslash }^2{d}^2/(2md{x}^2)$: the original PDF omits the superscript $2$ on the derivative in its numerator. Take $a>0$, and normalize the scaled exact ground state asThe factor $\sqrt{\lambda }$ is optional in a quotient but makes the calculation transparent. Changing variable to $u=\lambda x$ and differentiating the scaled wavefunction givesAt $\lambda =1$ this trial is the exact minimizing state, so its energy $\mathcal{E}(\lambda )={\lambda }^2{T}_0+{\lambda }^{-2}{V}_0$ has zero derivative there. Hence $2T_0-2V_0=0$. Since $E_0=T_0+V_0$,This is the quantum virial identity from scaling for a quadratic potential, and hence the oscillator form of the virial theorem.

For the inverse-power attraction, take $a>0$ and suppose, for contradiction, that an exact ground state exists with separately finite kinetic energy $T_0>0$ and potential mean $U_0<0$, admitting the same dilation variations. Homogeneity now givesStationarity at $\lambda =1$ would require $2T_0+p{U}_0=0$. Its second derivative would then beFor $p>2$ this is negative, contradicting a ground-state minimum. More strongly, one does not need a presumed exact state: choose any normalized smooth test function supported away from the singular origin. Its $T$ and $U$ are finite, and its scaled quotient satisfiesThe unregularized attraction therefore exhibits fall to the centre for a supercritical inverse-power potential and has no stable ground state.

There is a necessary qualification to the PDF's broader wording about “no bound state”. Under the usual finite-energy virial theorem assumptions, a putative negative-energy bound state would satisfywhich contradicts being below the continuum threshold at zero. Thus no negative-energy bound state satisfying those regularity assumptions is possible. But this singular differential expression needs a specified domain at $x=0$; separately divergent kinetic and potential means or boundary conditions not preserved by dilation invalidate that ordinary calculation. The domain assumptions in singular-potential virial arguments must therefore be stated: the scaling proof establishes absence of a semibounded ground-state problem, rather than a domain-independent theorem about every formal square-integrable solution. A short-distance regularization would be a different potential.

The quantum variational principle says that every admissible nonzero trial wavefunction obeyswhere $E_0$ is the ground-state energy. Thus the Rayleigh quotient is an upper bound. Equality holds when the trial lies entirely in the ground-state subspace.

Let $\{{\varphi }_j\}$ be a complete orthonormal eigenbasis of the Hamiltonian, with $H{\varphi }_j=E_j{\varphi }_j$ and $E_j\ge E_0$. Expand a nonzero admissible trial wavefunction as $\tilde{\Psi }={\sum }_j{c}_j{\varphi }_j$. ThenConsequentlyEvery numerator term is nonnegative and the denominator is positive. Equality requires the trial to lie wholly in the ground-state subspace; it need not be an individually chosen eigenvector when the ground energy is degenerate. This is the quantum variational principle, and wavefunction normalization before calculation is optional because the quotient removes the overall scale.

Use spin one-half states $|\uparrow ⟩,|\downarrow ⟩$ with $S^z=\pm 1/2$, so ${\sigma }^i=2S^i$ and $H=-J{\sum }_n({\sigma }_n^x{\sigma }_{n+1}^x+g{\sigma }_n^z)$. At $g=0$, every ferromagnetic bond has its lowest energy $-J$ when adjacent $x$ spins agree. On the connected periodic chain the normalized ground states arewhere $|\pm x⟩=(|\uparrow ⟩\pm |\downarrow ⟩)/\sqrt{2}$. Their span is the two-dimensional ground-state subspace; any normalized superposition is another ground state. They are exchanged by the global spin-flip discrete symmetry generated by ${\prod }_n{\sigma }_n^z$.

As $g\to +\infty$, the field dominates and selectsThe limiting polarized state is unique. At large finite $g$, exchange admixes virtual spin flips, so the product state is the limiting wavefunction rather than an exact finite-field eigenstate. The bulk expansion below gives $E_0/N=-J[g+1/(4g)+O(g^{-3})]$. The exact twofold degeneracy stated at $g=0$ should be distinguished from thermodynamic spontaneous symmetry breaking in the ordered phase: a finite chain at nonzero field can have a split pair of symmetry eigenstates.

Assume a complete orthonormal eigenbasis and a self-adjoint operator bounded below, with the trial state in its operator domain or associated energy-form domain. The expansion and orthogonality giveConsequentlyIt is a weighted average of eigenvalues, all at least $E_0$. This is the Rayleigh-Ritz variational principle; equality holds precisely when the trial state lies in the ground-state subspace. A continuous part of the spectrum would require the corresponding spectral integral in place of part of the sum.

The variational method estimates the lowest energy of a Quantum Hamiltonian by choosing a trial wavefunction, evaluating its energy, and optimizing the trial parameters. It uses the quantum variational principle, the Rayleigh-Ritz variational principle expressed for quantum states. Let $H$ be a self-adjoint operator bounded below, and define $E_0=\inf \sigma (H)$, the bottom of its spectrum. Every normalized admissible trial quantum state satisfiesWhen $E_0$ is an energy eigenvalue, it is the ground-state energy; equality holds precisely for a quantum state in the ground-state subspace. Otherwise the bottom of the spectrum need not be attained by any normalizable wavefunction.

Admissible means finite form energy. Choose a real $b\le E_0$ and use the shifted quadratic form of a positive quantum Hamiltonian:The form domain $Q(H)$ is independent of this choice of $b$ and can be larger than the operator domain $D(H)$. For $\psi \in D(H)$, $E_{\psi }=⟨\psi ,H\psi ⟩$ is the usual expectation value; for nonzero unnormalized trials, divide $q_H[\psi ]$ by $\Vert \psi {\Vert }^2$ to get the form version of the Rayleigh quotient. See the quantum variational principle for the general domain justification.

Thus each trial energy is an upper bound on $E_0$, and minimizing within a trial family improves that upper bound. It is not a lower bound on $E_0$. The Gaussian variational energy for the harmonic oscillator reaches $E_0=1/2$ because its family contains an exact ground state. The exact variational solution in a two-level system makes the equality condition visible as vanishing excited-state probability amplitude.

The method is useful when solving the Schrödinger equation exactly is difficult but integrals of a trial wavefunction are tractable. Enlarging a trial family cannot increase its optimal energy, although an optimum need not be attained. The beauty is that even an imperfect trial gives a rigorous bound, provided its form energy is computed exactly: numerical integration errors require separate control. The Gaussian variational estimate for a solvable sextic potential provides an existing example beyond a quantum harmonic oscillator.

A short proof explains the direction. With a complete orthonormal eigenbasis of energy eigenstates, write $\psi ={\sum }_n{c}_n{\varphi }_n$, where $H{\varphi }_n=E_n{\varphi }_n$ and ${\sum }_n|c_n{|}^2=1$. ThenThis is a weighted mean of nonnegative energy differences; equality requires every occupied energy eigenstate to have energy $E_0$. ^[ref]. For continuous spectrum, the spectral theorem replaces the sum by an integral against the scalar spectral measure of $\psi$, with the same nonnegative integrand. This proves the bound without assuming an orthonormal eigenbasis exists.

The historical setting predates quantum mechanics: Rayleigh's The Theory of Sound, volume I, appeared in 1877, and Ritz's paper on solving variational problems of mathematical physics appeared in volume 135 of Crelle's journal, catalogued by its publisher as 1909, pp. 1–61. These are original works associated with the Rayleigh-Ritz method; the dates here identify the publications rather than assert priority. ^[ref]; ^[ref].