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The central system of protons and neutrons in an atom. Its mass number $A$ is its baryon number in ordinary nuclear states; $Z$ is the proton number and $N$ the neutron number.

The nucleus contains almost all of an atom's mass and carries positive electric charge $Ze$, where $e$ is the elementary charge. The atomic number $Z$ identifies the chemical element; changing $N$ at fixed $Z$ gives another isotope. The mass number $A=Z+N$ counts nucleons, rather than specifying the exact nuclear mass: nuclear binding energy lowers the mass of a bound system relative to its separated constituents. The simplest nucleus is a single proton; other atomic nuclei can contain many protons and neutrons bound by the nuclear force.

A nuclear quantum state has properties such as spin and a spatial nuclear charge distribution. These are different questions from merely counting nucleons. A small-angle elastic scattering measurement can reveal a nuclear charge radius, while a wider range of momentum transfer tests the distribution's shape. The Hofstadter nuclear electron scattering experiment made this connection between scattering patterns and nuclear structure experimentally concrete.

Isotope abundance, nuclear separation energies, spin and nuclear magnetic moments supply complementary tests: abundance concerns which atomic nuclei survive and accumulate, removal energy concerns binding, and magnetic properties test the angular momentum assignments. Agreement across these observables is more informative than fitting one list of numbers.

In her 1963 lecture, Maria Goeppert Mayer recalled excess abundances at $N=50$ and $82$. She contrasted the strong binding of the last neutron in oxygen isotope ${}^{16}\mathrm{O}$ with the weaker extra neutron in oxygen isotope ${}^{17}\mathrm{O}$, and displayed beta decay energies near $N=20$ and $50$. These are compiled empirical patterns, rather than readings from an apparatus she built.^[ref]

Her 1949 letter compared observed spins and nuclear magnetic moments with orbital assignments. For example, lead isotope ${}^{207}\mathrm{Pb}$ was assigned a $p_{1/2}$ neutron hole near $N=126$, whereas bismuth's odd proton began the next shell as $h_{9/2}$. The moments tested orbital character as well as spin.^[ref]

A useful comparison holds $Z$ fixed when comparing neighboring isotopes, and examines odd-even staggering separately from a shell discontinuity. Abundance additionally depends on production and decay history. Neither the abundance pattern nor a successful spin assignment directly images orbiting particles; neither fixes a unique nuclear mean field. The experimental techniques themselves include mass spectrometry and nuclear magnetic resonance, whose preparation and readout differ. The Hofstadter nuclear electron scattering experiment separately constrains nuclear size and nuclear charge distributions, rather than measuring these occupancies.

What is measured. A monoenergetic Electron beam is directed at a thin target. A movable magnetic spectrometer selects the scattering angle and outgoing momentum, separating elastic scattering from nuclear excitation and other backgrounds. Incident beam current and target thickness supply the normalization of the differential scattering cross-section. The Hofstadter nuclear electron scattering experiment is a classic implementation of this electromagnetic probe.

For a heavy, approximately spin-zero atomic nucleus, neglecting recoil and treating the electron in the Born approximation, the point-charge result is multiplied by the nuclear charge form factor:Here $q$ is the magnitude of the spatial momentum transfer in natural units. The cosine factor includes the Electron spin. Dividing the elastic data by the point-charge factor isolates $|F(q){|}^2$ within these approximations. Recoil, magnetic terms for targets with spin, radiative corrections and particularly Coulomb distortion in electron scattering must be included when significant.

From scattering to size and shape. For a spherical nuclear charge distribution,Thus the nuclear charge form factor is a normalized Fourier transform. Its low-$q$ expansion,measures the nuclear charge radius $r_{\mathrm{ch}}=\sqrt{⟨r^2{⟩}_{\mathrm{ch}}}$. Larger momentum transfers resolve the density profile through diffraction maxima and minima. For a uniform sphere of sharp radius $R$, the uniform-sphere nuclear charge form factor is $3[\sin (qR)-qR\cos (qR)]/(qR{)}^3$; its first zero is at $qR\simeq 4.493$, while $r_{\mathrm{ch}}=\sqrt{3/5}R$.

A practical extraction fits a family of densities to all measured cross sections, rather than treating a few measured values of $|F{|}^2$ as a complete density reconstruction. Finite angular coverage, resolution and the missing sign information make this an inverse problem.

Observed pattern. Apart from the lightest nuclei, the central density is approximately constant; the size grows approximately as $R\simeq 1.2A^{1/3}\mathrm{fm}$ and there is a diffuse surface. The coefficient describes an equivalent sharp nuclear radius, rather than the root-mean-square radius itself. Heavy nuclear charge distributions are often described by the two-parameter Fermi nuclear charge distribution, $\rho (r)={\rho }_0/[1+\exp ((r-c)/a)]$, with half-density radius $c$ scaling roughly as $A^{1/3}$ and diffuseness $a$ around $0.5\mathrm{fm}$. The surface thickness is then about $4a\ln 3\simeq 2.2\mathrm{fm}$. Shell effects, deformation and the lightest systems give departures from this smooth pattern. These qualitative features are established by the electron scattering density measurements.^[ref]

Complementary probes. Transition energies in a muonic atom are especially sensitive to nuclear size because the heavy negative muon orbits close to the charge. Electronic isotope shifts, after separating nuclear-mass and finite-size contributions, measure changes in $⟨r^2⟩$. Both require atomic-structure calculations. Electromagnetic excitation and transition strengths constrain deformation and charge multipoles. Hadronic scattering can also constrain nuclear dimensions, but carries uncertainties from the strong interaction and probes matter rather than purely electric charge.