Past exam of the mathematics course of the University of Cambridge 2006 iii Paper 51 1 b Solution Created 2026-10-03 Updated 2026-10-14
Use the connected correlation function , so that the constant ordered contribution is removed. Away from a thermodynamic critical point its long-distance decay defines the correlation length: when this limit exists. In a massive rotation-invariant phase the exponential decay is typically multiplied by an algebraic factor.
Expand the Landau-Ginzburg theory free energy about a stable uniform minimum , writing . To quadratic order,integration of the Gaussian field theory gives the Fourier-space connected correlation function . Thus the Ornstein--Zernike correlation function hasFor an ordinary quartic transition, above the transition and below, so and , respectively. The correlation length diverges as on both sides, with different amplitudes. At criticality the mass vanishes and the Gaussian correlation function is proportional to for . Interactions can change this power to .
Past exam of the mathematics course of the University of Cambridge 2008 iii Paper 50 1 b Solution Created 2026-10-03 Updated 2026-10-14
Use the connected correlation function in a selected pure thermodynamic phase. The exponential correlation length is defined by , when this limit exists in the chosen direction. Linearizing the Landau-Ginzburg theory around a stable uniform minimum givesHence the Landau scalar correlation length is . Away from criticality the massive Gaussian field correlation tail behaves as , up to its amplitude. At a continuous transition tends to zero, so diverges and fields vary on scales much longer than the lattice spacing. This motivates a gradient expansion, but the simultaneous growth of correlated fluctuations is precisely why the Ginzburg criterion must be checked.
Past exam of the mathematics course of the University of Cambridge 2008 iii Paper 50 1 Solution 2026-10-14
A phase diagram locates stable pure thermodynamic phases and their phase coexistence boundaries in a space of control parameters. For a concrete three-dimensional example, take the temperature, crystal-field parameter, and magnetic field of the Blume–Capel model. Its spins take values ; changing the cost of the zero-spin state can turn a continuous ordering transition into a discontinuous one. A local scalar description near the resulting tricritical point is the Landau-Ginzburg theoryThe three local control coordinates are , with varying linearly with the thermal scaling field. For , , the transition at is continuous. For , zero-field coexistence is at , and the magnetization jumps between zero and . The two loci meet at , the tricritical point.
The full three-dimensional phase diagram has an ordered coexistence sheet at , where the two opposite magnetizations exchange stability when changes sign. On its three-phase line it meets two nonzero-field tricritical wings. These wings are first-order phase transition surfaces between minima of the same sign but different magnitude, terminating at ordinary thermodynamic critical points. Their tricritical wing critical edges are found by :Indeed fixes , and substituting into and gives ; ensures a stable critical quartic minimum. The two signs give the two wings. All transition surfaces and critical edges end together at the tricritical point. The following plot uses ; its wing surfaces come from the exact tricritical wing coexistence factorization, rather than schematic unconstrained surfaces.
Tricritical coexistence surfaces, the zero-field phase diagram, and ordinary, first-order and tricritical Landau potentials
. Details. The unheaded requests for critical exponents follow from the uniform equation of stateFor an ordinary thermodynamic critical point, is fixed and , . At , , the small ordered minimum obeys , so the order-parameter critical exponent is . Above the transition , giving the magnetic-susceptibility critical exponent . At , , so the critical-isotherm exponent is . At the tuned tricritical point, , instead below the transition and on its critical isotherm, while the disordered susceptibility remains . ThereforeBelow the transition the inverse susceptibility is , giving in the ordinary limit and in the tricritical limit. Thus both sides give the same susceptibility power, with different amplitudes.
To derive the general Ginzburg criterion, tune away all lower even nonlinearities and let the leading stabilizer be , . The equation of state gives , and its curvature at the ordered saddle is , so . The fluctuations of the order parameter averaged over a correlation volume are estimated by its long-wavelength quadratic covariance:The integral has a fixed dimensionless upper limit after ; this is a coarse-volume fluctuation estimate, not the ultraviolet-dominated point variance. Consequently the multicritical Ginzburg ratio isThe Landau approximation is asymptotically controlled by this test only when the ratio tends to zero. This gives the upper critical dimensionThe same threshold follows by giving its Gaussian engineering dimension : the coupling to has scaling exponent , which becomes relevant below .
For , the fluctuation ratio diverges and the saddle calculation cannot predict the generic interacting critical exponents. At the test is marginal, not a proof of changed power exponents: the ratio has zero thermal power and marginal interactions can produce logarithmic corrections. Thus the PDF's inclusion of equality in a blanket claim about wrong power exponents needs this qualification. The Landau-Ginzburg theory as a fluctuating field theory remains useful; what loses validity is its fluctuation-free Landau approximation.
Past exam of the mathematics course of the University of Cambridge 2008 iii Paper 50 4 c Solution Created 2026-10-03 Updated 2026-10-14
For , the quartic interaction has a nonzero limiting value instead of disappearing under coarse-graining. Long-wavelength thermal fluctuations are therefore interacting, so the fluctuation-free Landau approximation cannot give the generic critical powers. For example, its ordinary correlation-length critical exponent is , whereas the relevant thermal eigenvalue just derived givesThe tadpole is momentum independent, so the anomalous dimension begins at . Combining this with the scaling relations yields , , and , exhibiting the deviation from ordinary mean-field indices. These are controlled statements for small positive , not exact numerical exponents at arbitrary dimension. The Landau-Ginzburg theory itself is not invalid: integrating its fluctuations is precisely how the Wilson-Fisher fixed point was obtained. The invalid step is replacing that interacting long-distance theory by a uniform saddle and ignoring its fluctuation corrections.
Past exam of the mathematics course of the University of Cambridge 2009 iii Paper 43 1 a Solution Created 2026-10-03 Updated 2026-10-14
For a ferromagnet the scalar order parameter is the spontaneous spin magnetization. It distinguishes a symmetry-invariant phase with zero mean from one of two phases with a nonzero mean of opposite signs. At zero field, a finite system with spin inversion symmetry has exactly zero mean. The spontaneous value is defined by taking the thermodynamic limit first and then sending the symmetry-breaking conjugate field to zero from one side.
A Landau-Ginzburg theory promotes the coarse magnetization to a scalar field and usesAt , spin inversion symmetry permits only even local powers. The gradient term penalizes spatial variations. The equilibrium statistical weight is ; the Landau approximation chooses a stable minimum of , whereas the full functional integral retains fluctuations around it. In a homogeneous phase this gives the equation of state . The field is conjugate to the order parameter, with .
Past exam of the mathematics course of the University of Cambridge 2009 iii Paper 43 1 b Solution Created 2026-10-03 Updated 2026-10-14
Use the connected correlation function , since the disconnected constant in an ordered phase does not measure fluctuation decay. Away from criticality its large-distance exponential defines the correlation length:when that limit exists. Algebraic prefactors do not affect this definition.
Expand the Landau-Ginzburg theory about a stable homogeneous minimum . With , the quadratic fluctuation energy is . The Gaussian functional integral givesThis Ornstein--Zernike correlation function shows why the curvature of the free-energy minimum controls correlations. At a continuous phase transition that curvature vanishes, allowing long-range fluctuations. In the ordinary quartic theory with , above the transition and on either ordered branch below, so on both sides. At an equilibrium first-order transition the competing minima generally retain nonzero curvature, and the correlation length remains finite. The limit of local stability at a spinodal point is a distinct mean-field phenomenon.
Past exam of the mathematics course of the University of Cambridge 2009 iii Paper 43 1 c Solution Created 2026-10-03 Updated 2026-10-14
Microscopically different systems can have the same critical exponents and appropriately normalized scaling functions. This universality means that they belong to one universality class when coarse-graining brings them to the same renormalization-group fixed point. Spatial dimension, order parameter symmetry and the range of the interactions affect that classification; changing a lattice spacing or a microscopic coupling generally changes nonuniversal amplitudes and the critical temperature instead.
In the scalar short-range Landau-Ginzburg theory, a positive quartic term and one thermal tuning produce ordinary Ising-type criticality. A generic sextic term does not change that fixed point, but tuning the quartic coefficient to zero exposes a different tricritical point with different exponents. The mean-field approximation itself neglects fluctuations. Its numerical exponents are reliable only when the Ginzburg criterion makes those fluctuations subleading; the ordinary scalar upper critical dimension is four, while the tricritical one is three. At an upper critical dimension logarithmic corrections can remain.
Past exam of the mathematics course of the University of Cambridge 2010 iii Paper 41 1 iii Solution Created 2026-10-03 Updated 2026-10-14
At fixed average order parameter, a nonconvex local potential need not describe the equilibrium free energy. A mixture of two phases can lower it to the common-tangent convex envelope. If their magnetizations are , the coexistence field satisfiesEquivalently, , the equal-area Maxwell construction. An average between and is obtained by choosing their volume fractions according to the lever rule. The gradient term in Landau-Ginzburg theory gives a finite interfacial energy and smooth domain walls; in the thermodynamic limit the bulk gain dominates the interface cost. Domains are therefore especially natural under a constrained mean magnetization or suitable boundary conditions. Without such a constraint, one pure phase is also an equilibrium state at coexistence.
Past exam of the mathematics course of the University of Cambridge 2010 iii Paper 41 1 i Solution Created 2026-10-03 Updated 2026-10-14
An order parameter distinguishes phases through a macroscopic observable, such as the mean spin of a ferromagnet. Its vanishing can reflect an unbroken symmetry, while choosing one of several nonzero equilibrium values gives spontaneous symmetry breaking. Landau-Ginzburg theory treats it as a slowly varying field and expands the free energy in terms allowed by symmetry:Here penalizes spatial variation, is the conjugate field, and the highest retained even coefficient must stabilize large . For a spin-flip-symmetric system, odd powers are forbidden at . Equilibrium in the Landau approximation minimizes this functional; near an ordinary continuous transition with and .
Past exam of the mathematics course of the University of Cambridge 2010 iii Paper 41 3 Solution Created 2026-10-03 Updated 2026-10-14
The ultraviolet cutoff specifies which fluctuations remain explicit. Changing it integrates out some modes; to preserve long-distance predictions, their effect must be absorbed into the mass, interactions, and other couplings. Thus bare coefficients depend on . The long-distance inverse connected correlation function has the form . After fixing the gradient normalization, the infrared mass is an inverse correlation length. With the question's unrescaled gradient coefficient, at Gaussian level, so proportionality rather than literal equality is appropriate until that normalization is chosen.
As a concrete momentum-shell renormalization group step, split into modes below and in the shell , and defineThen rescale coordinates and the field to restore the cutoff and gradient coefficient. A local derivative expansion of gives new quadratic, quartic, and higher even couplings. If the system has short-range interactions, the field varies slowly, the effective potential is analytic, and remaining fluctuations are small, retaining the leading gradient and lowest stabilizing powers and minimizing the resulting functional gives Landau-Ginzburg theory. Suppressing the omitted fluctuations is the substantive Landau approximation; it is justified sufficiently far from the narrow fluctuation region or above the appropriate upper critical dimension.
The truncated two-point function in this question is the one-particle-irreducible two-point vertex, . It is the Hessian of the Legendre effective action, not merely the connected two-point function. In perturbation theory,Here is the Gaussian propagator about the chosen reference mass, is the mass counterterm or bare-to-reference mass shift, and is the interaction self-energy, computed from proper diagrams. Fix the gradient normalization so , and choose the infrared reference mass . Then at this order. The mass renormalization condition is .
At one loop the only two-point diagram is the quartic tadpole diagram. There are choices for attaching its two external lines, leaving the other pair contracted; dividing by gives its factor . It is independent of external momentum, soThe renormalization condition therefore gives the self-consistent one-loop equationUsing inside the loop is a self-consistent resummation; replacing it by the bare mass gives the same formal first-order expansion away from infrared problems.
Subtract the equation at , where , and absorb regular temperature dependence of into the thermal coefficient. Let and . ThenFor , the integral divided by tends to a finite cutoff-dependent constant, since its small-momentum radial integrand is . Thus is proportional to , consistent with the Landau prediction. For , set : the correction instead scales as and dominates . At it is proportional to . Hence a pure linear Landau mass law without logarithmic modification is consistent only aboveFor , the massless integral itself is infrared divergent, so the subtraction already needs additional care. The sub-four-dimensional self-consistent approximation locates the breakdown of mean-field behavior; it is not an exact calculation of interacting critical exponents.
At a tricritical point the quartic coupling is tuned away and the leading stabilizing interaction is . At the Gaussian fixed point, the field has engineering dimension , so the sextic coefficient rescales as . It changes from irrelevant to relevant atThis is the sextic case of the upper critical dimension of an even scalar interaction; marginality at three dimensions allows logarithmic corrections.
Past exam of the mathematics course of the University of Cambridge 2011 ii Paper 1 36C Solution Created 2026-09-24 Updated 2026-10-14
In the Landau-Ginzburg theory functional, is the magnetic field energy density; the covariant-gradient term is the carrier kinetic energy including phase gradients and electromagnetic coupling. The terms give the local condensation energy. With the normalization in the question, is the carrier density.
For a uniform field-free equilibrium, minimize over . Stability for large requires , and a nonzero minimum requires . ThereforeThe factor two follows from the question's quartic coefficient , rather than a convention using .
Let . Under the gauge transformation,Its squared magnitude is unchanged, is unchanged, and is unchanged. Thus the full energy has gauge invariance.
For uniform , write . The kinetic density is . Varying with compactly supported variations and integrating the magnetic term by parts givesAt a minimum its coefficient vanishes, giving the London equationTaking another curl, using and a smooth phase so , yieldsFor a planar surface this has the decaying solution inside the material; the growing solution is excluded by boundedness in the bulk. Hence magnetic fields penetrate only a surface layer of thickness and vanish deep in the macroscopic bulk, the Meissner effect. This conclusion uses the uniform-density, smooth-phase setting; a vortex has a singular phase and a nonuniform core and is outside those assumptions.
Past exam of the mathematics course of the University of Cambridge 2012 iii Paper 49 1 i Solution Created 2026-10-03 Updated 2026-10-07
In Landau-Ginzburg theory, a scalar order parameter distinguishes macroscopic phases: for an Ising model it is the magnetization per site, while near a liquid–gas endpoint it can be a shifted density. An ordered pure thermodynamic phase has a nonzero value even when the conjugate field is removed. For a symmetry-related pair, take the thermodynamic limit before ; a finite-volume symmetric ensemble instead has zero average.
Coarse-grain to a slowly varying real field and use a local, symmetry-constrained free-energy density. A useful convention isFor spin inversion symmetry, odd powers other than the externally imposed source are absent. Take when the quartic coefficient can be negative; for an ordinary transition already stabilizes the quartic truncation. The gradient energy penalizes spatial variations. In the Landau approximation, minimize this functional, usually first over constant fields. The corresponding statistical field theory also integrates fluctuations with weight . The order parameter identifies the phase; its spatial field describes both equilibrium order and its fluctuations.
Past exam of the mathematics course of the University of Cambridge 2012 iii Paper 49 3 Solution Created 2026-10-03 Updated 2026-10-07
Take a positive gradient coefficient , a positive squared mass, a finite-volume regulator and an ultraviolet cutoff. Use the dimensionless statistical action convention : inverse temperature is absorbed into the coefficients. If denotes dimensional energy instead, the exponent below gains a factor and the covariance gains . These conventions cannot be mixed.
Choose the Fourier transform conventionIntegration of the quadratic gradient and source terms givesComplete the square with . Translation of the regulated real Gaussian variables leaves their measure unchanged, so the Gaussian integral givesHere is the source-free Gaussian partition function. For independent regulated real coordinates and a positive quadratic matrix , it is under Lebesgue normalization. The continuum determinant needs the stated regulator and a measure convention. Reality pairs the nonzero Fourier modes, so they must not be counted as two independent real fields.
A connected correlation function subtracts the product of the means. The logarithm generates its cumulants: differentiating twice with respect to the source, using the measure in the functional derivative convention, yieldsThe source changes the mean but not the covariance; the stated zero-source limit therefore follows immediately. Momentum conservation uses , appropriate for a real field without complex conjugation on either displayed factor.
For the continuum massive Gaussian field correlation tail, set and . Fourier inversion givesThe large-argument Modified Bessel function of the second kind has . Hence is proportional to at large distance andAt zero mass the exponential length diverges. For the critical continuum tail is algebraic, ; in lower dimensions infrared regulation needs additional care.
For a uniform source , perform a momentum-shell renormalization group step: separate slow modes and fast modes . In a Gaussian field theory they decouple; the uniform source couples only to the retained zero mode. Integrating fast modes contributes only a field-independent determinant to the free energy. Restore the cutoff by , andThe factors from the measure, gradient and two fields cancel in the gradient term. The mass term gains , and the linear source gains . ThereforeHere is the positive mass; for signed thermal coordinates it is the squared-mass relation that applies. The Gaussian fixed point has thermal scaling eigenvalue , source eigenvalue and zero anomalous dimension.
Under the formal homogeneous Gaussian scaling hypothesis, substitution of those eigenvalues givesThe last two values are independently visible in and , agreeing with Landau-Ginzburg theory. The specific-heat power follows directly from the determinant: after two thermal derivatives its singular contribution is proportional toThe change of variables proves this power because the rescaled integral converges at large exactly when . The two-dimensional free energy itself has a resonance, while its second derivative still has the indicated power.
The printed magnetization exponent is a formal Gaussian scaling index, not a proved ordered-phase law of the purely quadratic model. The ordered-phase obstruction in a Gaussian scalar model is explicit: the uniform field has energy density . At it tends to as , and the partition function diverges. For , the mean is and tends to zero as , so there is no spontaneously ordered branch. Thus no literal for can be established from this Statistical Hamiltonian alone. The value follows from the scaling dimension of the field if one assumes such a branch; for its nonpositive value further warns against that interpretation. Adding a stabilizing quartic interaction defines an ordered phase, but below four dimensions that interaction is relevant and generally leads to the Wilson-Fisher fixed point, not these Gaussian thermodynamic powers.
For the Gaussian specific-heat infrared threshold, at the same determinant integral grows like , so as a power exponent, with a logarithmic divergence. For , it has a finite cutoff-dependent limit; the leading heat capacity is a regular constant and has no divergent power, again described by in the requested convention. After subtraction of this background the Gaussian singular term can still have the negative power index ; it is not correct to erase that distinction. In a stable quartic Landau-Ginzburg theory above four dimensions, the quartic coefficient is a dangerously irrelevant coupling: it is needed for the ordered phase and contributes , giving the mean-field specific-heat jump and while invalidating naive hyperscaling relation. At four dimensions, marginal interactions can add further logarithmic corrections. The agreement with Landau theory is in the leading heat-capacity power; it does not assert the absence of logarithms or supply a missing stable Gaussian ordered phase.
Past exam of the mathematics course of the University of Cambridge 2014 iii Paper 42 3 Solution Created 2026-10-03 Updated 2026-10-06
The parameters of a cutoff statistical field theory describe only the retained modes. Changing the ultraviolet cutoff changes which fluctuations have already been integrated out, so its effective mass, interaction coefficients and gradient normalization must change to preserve the same long-distance physics. They are not separately cutoff-independent observables. Because the source's weight is , its statistical Hamiltonian is dimensionless, with the physical inverse-temperature factor already absorbed.
For example split the scalar field into slow modes with and shell modes with . Define the momentum-shell renormalization group step byThis integrates out short-wavelength fluctuations exactly if all generated terms are retained. The new Hamiltonian can be expanded in local symmetry-allowed operators when the retained external momenta are well below the shell scale. A cumulant expansion of a coarse-grained free energy gives perturbative coefficients. Restoring the cutoff with and, for a canonical gradient term, , gives and . Interaction corrections also change the field normalization. Repeating the step produces the effective theory at successively longer distances.
To obtain the LG theory, assume a short-range scalar theory, slowly varying retained fields, analytic local couplings, positive gradient stiffness and stability, and a regime in which fluctuation corrections at the remaining scales are small. Keeping the leading gradient, quadratic and quartic operators gives a local Landau-Ginzburg theory functional. Its equilibrium in the Landau approximation is a uniform minimum, with a quadratic coefficient proportional to after the critical mass has been tuned. The RG explains why this is asymptotically consistent for the ordinary transition above four dimensions: the quartic interaction is irrelevant near the Gaussian fixed point, while it must still be retained to stabilize the ordered phase. Below four dimensions it cannot be dropped in the asymptotic critical region; an interacting Wilson-Fisher fixed point rather than the elementary saddle generally controls the transition. At four dimensions the interaction is marginal and produces logarithmic corrections. Tuning a quartic coefficient through zero requires a sextic stabilizing term and leads to tricriticality.
More concretely, in the Gaussian scaling regime let so the local quartic term is . At a total blocking scale , the leading couplings are , , . Apply the saddle approximation to the blocked potential and multiply its minimum by to convert back to original volume units. Rescaling the saddle field by givesAll blocking-scale factors cancel. This explicitly recovers mean-field scalar free-energy scaling with . Although above four dimensions, the saddle free energy is proportional to ; setting it to zero before minimization would remove the ordered phase. This is the dangerously irrelevant coupling mechanism rather than homogeneous two-variable hyperscaling.
For the perturbative calculation make the source's kinetic convention explicit. Write . The canonical normalization of a scalar gradient term uses , so the canonical quadratic and quartic coefficients are and . In what follows denote those canonical coefficients; then the reference propagator has denominator . Without this normalization the propagator denominator is , and the unmodified printed integral would not apply. At one loop the quartic tadpole is momentum independent, so it produces no gradient renormalization at this order.
In the convention fixed by the displayed equation, the truncated two-point function is the one-particle-irreducible two-point vertex, not the connected two-point cumulant itself. If and is the Legendre transform, then its second derivative is the inverse of . For a translation-invariant background,Decompose the canonically normalized statistical Hamiltonian into a Gaussian part of mass , a mass counterterm , and the quartic interaction . With the Euclidean sign convention in which a positive mass correction increases the inverse propagator, the self-energy expansion isHere contains loop corrections from proper two-point diagrams, excluding the separately displayed mass counterterm. The corresponding connected propagator begins . This fixes the sign, which would be reversed if “self-energy” instead denoted the insertion added with a plus sign inside a Dyson series.
The one-loop proper diagram is the tadpole diagram. Attaching two external fields to the quartic vertex gives contractions, divided by , so its symmetry factor is . With the loop momentum restricted by the cutoff,It is independent of external momentum. Impose the zero-momentum mass condition . This gives , henceThis is the one-loop relation using a renormalized mass in the reference propagator, or the corresponding self-consistent tadpole approximation if solved without expanding in . It is not an exact all-orders gap equation. Away from the critical infrared problem, replacing the loop mass by the bare one changes a strict perturbative result only at higher order.
Take smooth and nonzero for an ordinary stable quartic transition. To test the assumed linear thermal mass, work from the disordered side and put . For , is infrared finite. The critical bare mass is shifted, not generically zero: . Absorb the smooth temperature dependence of couplings into an analytic thermal tuning , with . Critical subtraction gives the one-loop critical-mass subtractionwhereThe infrared asymptotics of the critical-mass subtraction now distinguish the dimensions. For , is finite, soFor , diverges logarithmically. For , substitution givesso the correction to scales as and dominates the analytic linear term. Pure mean-field linear mass scaling is therefore consistent only aboveAt the boundary dimension logarithms modify the simple power law. Below it this calculation diagnoses the failure of the Gaussian expansion; the exponent obtained by treating the self-consistent one-loop equation as exact is not automatically the exponent of the interacting scalar theory. For , the massless subtraction itself has an infrared divergence, so this perturbative argument cannot establish absence of a transition. In particular it does not rule out the two-dimensional Ising critical point.
The same upper dimension follows by engineering dimension counting: a canonical scalar field has dimension , so . For a tricritical point tune the renormalized quadratic and quartic terms to zero and retain a positive sextic interaction . Its engineering dimension isIt is marginal at , irrelevant above three, and relevant below three. More generally the upper critical dimension of an even scalar interaction is .
A Ginzburg criterion check gives the same result: at tricritical mean-field scaling and , whereas fluctuations in a correlation volume scale as . Their ratio to is , which tends to zero only for . ThusThe tricritical tuning concerns renormalized couplings: shell contractions of a sextic term can regenerate quadratic and quartic terms even when their bare coefficients vanish. At three dimensions the marginal sextic coupling produces logarithmic corrections rather than a strictly fluctuation-free mean-field limit.
Past exam of the mathematics course of the University of Cambridge 2015 iii Paper 45 1 Solution Created 2026-10-03 Updated 2026-10-14
In Landau-Ginzburg theory, use the sextic even Landau potential with a fixed positive stabilising coefficient :Here is the scalar order parameter, its conjugate magnetic field, and an independent symmetry-preserving control, such as the single-ion coupling in the Blume–Capel model. Thus need not break , whereas does. The Blume–Capel mean-field tricritical parameters are one realization; generally, a tricritical point occurs whenTwo controls tune away the quadratic and quartic terms. For , crossing at gives a continuous phase transition; for , the quartic term instead favours a finite- minimum before the origin loses local stability. The sextic term bounds the free energy below. The tricritical point joins the continuous and discontinuous transition loci.
For the symmetric phase diagram, write . A nonzero stationary point obeys . Its free-energy density relative to the origin is . Equality of the two minimum values, together with stationarity, givesAt this phase coexistence point,so are genuinely degenerate global minima, not just stationary solutions. The spinodal points are for the disordered local minimum and for the appearance of the ordered minima. They are limits of metastability, distinct from the equilibrium first-order phase transition at .
Accordingly, the coefficient equations determining the physical temperature curves areThe simultaneous zeros of and determine and . For the alternative normalization , the same first-order condition is , with . These equations determine the curves implicitly; their slopes in actual coordinates depend on the material-specific coefficient functions.
In three controls , or locally equivalent coordinates, there are tricritical first-order wings. The plane contains a coexistence sheet of the two symmetry-related ordered phases. For it ends on the ordinary critical line ; for it reaches the three-phase line . Two further first-order surfaces extend from that line into and . Across a wing, two minima of the same sign but different magnitudes exchange global stability; the field favours that sign. Each wing ends on an ordinary critical edge where those minima and their intervening maximum merge. The three surfaces and their critical boundaries meet at the tricritical point.
The tricritical wing critical edges follow by imposing at :Here , confirming an ordinary quartic critical minimum locally. The field scale and the temperature-like displacement both vanish at the tricritical point. If are independent smooth local coordinates in , the following diagram has the same local topology as the physical three-dimensional phase diagram. Its surfaces use exact equal-minimum conditions, as described by tricritical wing coexistence factorization.
For the order-parameter critical exponent and critical-isotherm exponent at the tricritical point, set to leading order and take . For , the ordered saddle has , while at the equation of state is . Hence the tricritical mean-field critical exponents areThese are mean-field critical exponents. Below the tricritical upper critical dimension they need not be the interacting exponents, and at that dimension logarithmic corrections can accompany the powers. Along a generic path with the quartic term is subleading in the tricritical balance; a path keeping fixed instead approaches ordinary critical behaviour.
For the Blume–Capel model, take ferromagnetic , count each nearest-neighbour bond once and use hypercubic coordination . The nearest-neighbour direction sum in the printed Hamiltonian is understood implicitly. In a ferromagnetic mean-field approximation, write and replace the interaction by its self-consistent single-site field . The single-site partition function and variational free-energy density areThe first term prevents double counting the interaction energy. Differentiation gives the mean-field self-consistency equationSet and , the occupied-spin probability at . Expanding the single-site logarithm yieldsThe nontrivial simultaneous quadratic and quartic zeros require and , hence . At those values the sixth-order coefficient is , so the degeneracy is a stable tricritical point. The mean-field tricritical parameters areThis is a mean-field result, not a dimension-independent exact lattice transition temperature. The Boltzmann constant is kept explicit in this lattice calculation.
Past exam of the mathematics course of the University of Cambridge 2018 iii Paper 303 1 Solution Created 2026-10-03 Updated 2026-10-05
Use the usual homogeneous, local, analytic Landau-Ginzburg theory; rotational symmetry and Z2 symmetry alone do not specify locality, analyticity, or the signs of the coefficients. The local derivative expansion contains every rotational scalar with an even total number of fields:The omitted terms include all allowed higher field powers and contracted spatial derivatives. Terms differing by a total derivative are equivalent for bulk behavior with suitable boundary conditions. The displayed gradient energy assumes spatial homogeneity. If only rotations about an origin are imposed, rotationally invariant position-dependent coefficients are also possible.
In the mean-field approximation, take a spatially uniform order parameter and minimize its Landau free energy. For , and with , keeping the quadratic and quartic terms givesThe single minimum splits into two minima as the temperature passes below the critical temperature. Choosing one minimum gives spontaneous symmetry breaking of the Z2 symmetry and a continuous phase transition. The order parameter is the expectation in a selected ordered state; averaging equally over both states gives zero. A Z2 symmetry does not guarantee a continuous phase transition: a negative quartic coefficient stabilized by a positive sextic coefficient can instead give a first-order phase transition.
Relaxing the Z2 symmetry permits odd terms. A nonzero linear source generally rounds this ordinary continuous phase transition. A cubic term can instead give a first-order phase transition: for , and , equal minima occur atThe order parameter jumps from zero to . A continuous phase transition without an exact Z2 symmetry is still possible with additional tuning; odd terms do not logically exclude it.
For the multicritical even Landau potential, set and assume an integer , and . For , all lower even interactions must be absent or tuned to zero to obtain these mean-field critical exponents. The stationary equation isIts nonzero solutions are minima because . Thus the order-parameter critical exponent isSubstituting into the minimum free energy density givesThe singular heat capacity per unit volume is . Smooth variation of the other coefficients does not change the leading power. ConsequentlyFor , this means a finite heat capacity jump, with ; for , the tricritical point has and . The case would contain only a quadratic potential and would not stabilize an ordered phase.
The Gaussian fluctuation correction near a critical point is more singular than the mean-field approximation contribution whenThis is the upper critical dimension of an even scalar interaction. Equivalently, its coupling has engineering dimension , positive below . Dominant fluctuations signal breakdown of the mean-field approximation; the Gaussian expression is not then a calculation of the exact interacting heat-capacity critical exponent. At , equality of the powers allows logarithmic corrections.
The Landau-Ginzburg theory promotes the order parameter to a field and penalizes spatial gradients:with stiffness . Further even powers and higher-derivative terms may be included when required by accuracy.
Past exam of the mathematics course of the University of Cambridge 2023 iii Paper 303 1 a Solution 2026-09-28
Landau theory treats the order parameter as spatially uniform and expands the free-energy density in powers allowed by its symmetries. The Landau-Ginzburg theory promotes it to a field and adds gradient terms such as . It therefore describes spatial fluctuations, interfaces, defects, and correlation lengths, while reducing to Landau theory for uniform fields.

