The Mach number is , comparing the flow speed relative to a disturbance with the local sound speed. For a body moving supersonically, spherical acoustic disturbances emitted earlier have a tangent envelope with Mach cone half-angle . Signals cannot propagate arbitrarily far upstream. Compressive characteristics can converge and steepen into a shock wave, within which microscopic dissipation prevents a multivalued fluid state; supersonic motion alone does not require every flow to contain a shock.
Work in the shock frame with steady normal velocities . Integrating conservation of mass, normal momentum and total energy over a thin pillbox, neglecting gravity across the thin layer, gives the Rankine-Hugoniot conditions for a perfect gas:
The energy equation includes pressure work through specific enthalpy. The shock is adiabatic if negligible heat escapes the layer, but its irreversible dissipation means it is not isentropic.
Put and . Momentum conservation gives . Substitution in the energy equation produces the unshocked root and the compressive root
Since , the strong-shock limit has negligible upstream thermal pressure compared with ram pressure. The Strong-shock Rankine-Hugoniot conditions give
For unchanged composition, the ideal gas law implies , so
For , the compression tends to four and , where is mean particle mass.
With constant specific heat , entropy production in a perfect-gas shock is measured by the change in specific entropy
The strong-shock expression is therefore
The exact jump is positive for every compressive shock with , in accordance with the Second law of thermodynamics; the asymptotic expression is only for . There is a normalization issue in the printed description: this logarithmic formula with constant describes entropy per unit mass. The true entropy density is , so its difference is , rather than the same logarithmic jump with a constant heat capacity per unit volume. A material parcel's irreversible entropy increase should be assessed using .
Downstream gas is denser and hotter. For optically thin collisional emission the loss per unit volume is typically , whereas stored thermal energy scales approximately as . Compression can therefore reduce the radiative gas cooling time; excitation and ionization at the higher temperature can open additional cooling channels. The actual efficiency still depends on the astrophysical cooling function, composition and optical depth. In a radiative shock with separated scales, the temperature first rises across a narrow dissipative layer, then decreases through a much broader cooling region of characteristic length . Subsonic cooling usually brings further compression with approximately constant pressure. The immediate microscopic shock thickness and the macroscopic cooling length are distinct.
Let state be the fully cooled gas, with and the same composition. Set , the isothermal sound speed squared. Across the entire shock plus cooling layer, mass and momentum are still conserved, but gas energy alone is not. With ,
The nontrivial isothermal shock therefore has
If the upstream Mach number were defined with instead, this would be . Retaining the distinction avoids losing the factor .
The gas's specific entropy rises irreversibly at the hot shock and then decreases as escaping radiation removes heat. Since the final temperature equals the initial temperature,
This decrease for the gas is consistent with the Second law of thermodynamics: the emitted radiation and its eventual surroundings carry entropy away. It does not make the microscopic compressive shock reversible. The figure illustrates both the hot entropy jump and the subsequent cooling; its spatial cooling profile is schematic because no cooling law has been specified.
Figure 1.
Temperature and specific entropy across an adiabatic shock followed by radiative cooling
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