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The ideal gas law is the equation of state relating the absolute pressure $P$, volume $V$, particle count $N$, and absolute thermodynamic temperature $T$ of a classical ideal gas:Here $k_B$ is the Boltzmann constant, $N_{\mathrm{A}}$ is the Avogadro constant, $R$ is the molar gas constant, and $n_{\mathrm{mol}}$ is the amount of substance in moles. The distinct symbol $n_{\mathrm{mol}}$ avoids confusing amount of substance with the number density $n=N/V$, measured in ${\mathrm{m}}^{-3}$: the same law can be written $P=n{k}_{B}T$. Use absolute pressure, relative to a vacuum, rather than an unconverted gauge pressure. ^[ref]

The exact SI definitions of the Avogadro constant and Boltzmann constant giveThis numerical value is exact; the applicability of the ideal gas model to a real gas is an approximation. ^{[ref] [ref]}

For $n_{\mathrm{mol}}=1\mathrm{mol}$, $T=300\mathrm{K}$, and $V=0.025{\mathrm{m}}^3$, direct substitution givesAt fixed temperature and particle count, doubling the volume to $0.050{\mathrm{m}}^3$ halves the pressure to approximately $49.887\mathrm{kPa}$: this is Boyle's law. At fixed volume and particle count, doubling the temperature from $300\mathrm{K}$ to $600\mathrm{K}$ doubles the pressure to approximately $199.547\mathrm{kPa}$. These ratios use kelvins, not readings in the degree Celsius scale: $300\mathrm{K}$ is $26.85{}^{\circ }\mathrm{C}$, and $600\mathrm{K}$ is $326.85{}^{\circ }\mathrm{C}$.

The curved slices show Boyle's law at three temperatures; the straight slice shows proportionality to absolute temperature at one fixed volume. They are relations among equilibrium states, rather than a prescribed process history. Compression could hold the temperature fixed through heat transfer, or raise it during adiabatic compression. To calculate a process's heat or work, supplement the ideal gas law with the process constraint, the first law of thermodynamics, and the relevant internal energy or heat capacity information. The graph's extrapolation toward $T=0$ is mathematical; it does not assert that a real gas remains classical or gaseous there.

For a stellar mixture with fixed mean molecular weight, the ideal gas law can be written $P=\mathcal{R}\rho T/\mu$, where $\rho$ is mass density and $\mathcal{R}$ is the stellar gas constant. It assumes negligible interaction corrections and a nondegenerate gas; excitation or ionization can change the particle count and thermodynamic response.

In his 1834 memoir on the motive power of heat, Émile Clapeyron combined gas laws into a relation between pressure, volume, and temperature while analysing heat engines (printed page 164). The equation above uses modern SI notation and absolute thermodynamic temperature; it is not a transcription of his historical temperature convention. ^[ref]

Use $\mathcal{R}$ for the stellar gas constant, reserving $R$ for the stellar radius. The specific internal energy of a monatomic gas obeying the ideal gas law is $e=P/[(\gamma -1)\rho ]=3P/(2\rho )$. At fixed enclosed mass, the first law of thermodynamics gives the heat available to the outgoing luminosity as $ϵ=-{\partial }_{t}e-P{\partial }_t(1/\rho )$ when there is no stellar nuclear fusion heating. ThereforeThe second coefficient includes both the mass density dependence of $e$ and pressure work. This is gravitational energy generation in a homologously contracting ideal-gas star.

Write the characteristic scales asThen $\rho ={\rho }_{0}b$, $P=P_{0}p$, $T=T_{0}p/b$, $m=Mq$ and $L_r=Ll$. Since $d/dr=R^{-1}d/dx$, direct substitution in the stellar hydrostatic equation and mass conservation givesFor radiative diffusion in a star, dividing the temperature equation by $T_0/R$ givesIn particular the fourth power here is of $\mathcal{R}$, not of the radius.

Because $q(x)$ is fixed and $M$ is constant, a fixed mass label has fixed $x$. Thus stellar homology gives ${\partial }_t\rho =-3\rho \dot{R}/R$ and ${\partial }_{t}P=-4P\dot{R}/R$. The heating rate reduces to $ϵ=-3P\dot{R}/(2\rho R)$, positive during Kelvin-Helmholtz contraction. Substitution in $d{L}_r/dr=4\pi r^2\rho ϵ$ now yieldsThe dimensionless profiles fix $D$ and $E$. In a common stellar homology family with fixed stellar composition and opacity normalization, the expression for $D$ impliesIt is independent of radius and constant in time for a particular fixed-mass star. The formula for $E$ gives $\dot{R}=-2EL{R}^2/(3G{M}^2)$, which integrates toWhen the initial-radius term is negligible,This is the Kelvin-Helmholtz contraction time law in the prescribed stellar homology model. Infinite initial radius is a limiting idealization; a finite initial radius retains the first term.

At main sequence arrival, CNO cycle heating with fixed stellar composition has luminosityThe integral is dimensionless and fixed within the stellar homology family. The constant-opacity radiative scaling still gives $L\propto M^3$. Equating the stellar nuclear fusion and transported luminosities givesFinally the Kelvin-Helmholtz contraction law evaluated at $R_{\mathrm{MS}}$ gives $t_{\mathrm{MS}}\propto M^2/(L{R}_{\mathrm{MS}})\propto M^{-34/19}$. In a coeval star cluster, the mass just arriving at the main sequence consequently satisfiesThese results comprise constant-opacity homologous contraction to CNO ignition; their mass exponents compare fixed-composition models with common dimensionless profiles.

Use radiative homology with proton-proton burning and inverse-fourth-power opacity, retaining the composition factors throughout. To distinguish the stellar radius from the stellar gas constant, write them as $R$ and $\mathcal{R}$. With gas pressure alone, introduce the scale factorsThe ideal gas equation gives $\rho ={\rho }_{\ast }b$, $P=P_{\ast }p$ and $T=T_{\ast }p/b$. Substitution into hydrostatic equilibrium and mass conservation givesso $p^{\prime }=-bq/x^2$ and $q^{\prime }=x^{2}b$.

Set $\zeta =Z(1+X)$. The radiative diffusion in a star equation, with the stipulated opacity, becomesHere ${\rho }^2{T}^{-7}={\rho }_{\ast }^2{T}_{\ast }^{-7}{b}^9{p}^{-7}$. ThusThe luminosity equation follows from the specific heating rate of the Proton–proton chain:ConsequentlyThese give all four dimensionless stellar structure equations with their numerical coefficients.

The stellar homology assumption means the dimensionless profiles are shared across the models, not merely that an individual model can be written in dimensionless coordinates. The displayed equations then require $D$ and $E$ to be fixed. Holding the universal constants and ${\kappa }_0,{ϵ}_0$ fixed givesEquating the two cancels $M^6$ and yields $R^6\propto X^2\zeta {\mu }^{-4}$. Therefore the radius and mass-luminosity relation areThe mass-independent radius is a consequence of the particular heating and opacity exponents in this model; it is not a general radius law for main-sequence stars.

Initially $X=X_0$ is the same for all stars. The adopted mean molecular weight $\mu =4/(5X+3)$ also has the same initial value, neglecting its small direct dependence on $Z$. Thus $R\propto Z^{1/6}$. At fixed luminosity, the Stefan–Boltzmann law $L=4\pi R^2\sigma T_e^4$ givesThe stars compared here can have different masses; the luminosity law adjusts the mass to keep $L$ fixed.

For the evolution, take the stellar mass as constant and maintain homogeneous composition. The available energy in the remaining hydrogen is $M{E}_{H}X$, so conservation of energy in the nuclear-powered model givesThis includes the entire mixed hydrogen reservoir, not just the mass in a central burning region.

To determine the turnoff mass of a homogeneously mixed proton-proton-burning population, write the luminosity law as $L=C{M}^6{Z}^{-7/6}H(X)$, whereSeparating variables, the time to evolve from $X_0$ to $f{X}_0$ isFor a common $X_0$ and $0\le f<1$, this integral is a positive finite constant independent of $M,Z,t$. It follows that the turning-off stars satisfyThe integration retains the evolving luminosity and mean molecular weight; replacing $L$ by its initial value is unnecessary.

In stellar ideal gas equations, the stellar gas constant $\mathcal{R}=k_B/m_u$ converts a dimensionless mean molecular weight $\mu$ into the specific thermal relation $P=\mathcal{R}\rho T/\mu$. Here $m_u$ is the reference atomic mass unit, commonly approximated by the proton mass in simplified hydrogen-helium models. It has units of energy per mass per temperature. It is the molar gas constant divided by the molar mass corresponding to $m_u$, rather than the molar gas constant used with a dimensional molar molecular weight.