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Awarded to Owen Willans Richardson for thermionic emission and its emission law. He received the prize in 1929.^[ref]

Shot noise is fluctuation associated with discrete transfer events. For an electric current, individual charge carriers contribute finite amounts of electric charge, even when a meter displays a smooth mean. The simplest model is a stream of equal, independently arriving charges with constant rate: its Poisson process predicts both the mean electric current and the variance around it. Discreteness alone does not imply a Poisson distribution; the timing and correlations matter.

The useful surprise is that noise can reveal something a mean hides. Two devices can carry the same mean electric current yet have different fluctuations because one transfers charges independently and the other groups or regulates them. A calibrated shot noise photocurrent measurement can connect a macroscopic voltage variance to the elementary charge. Thermal electrical noise instead exists in an unbiased resistor at thermal equilibrium; a measured background can contain both mechanisms.

Walter Schottky's 1918 paper Über spontane Stromschwankungen in verschiedenen Elektrizitätsleitern treated amplifier sensitivity limits. Part II considered independent discrete transfers, including thermionic emission through a vacuum. On p. 563 he proposed amplifying fluctuations from a separate discharge tube to determine the elementary charge; those experiments were prospective, not reported results.^[ref]

An X-ray tube accelerates Electrons from a negative cathode to a positive target anode. A heated cathode supplies Electrons by thermionic emission; the evacuated envelope limits collisions before the target. This differs from the gas-discharge tube in the Röntgen X-ray discovery experiment.^[ref]

In bremsstrahlung, an Electron changes velocity in the target's electric fields, emitting a photon while losing kinetic energy. Different encounters allow a continuous range of transferred energies. This is distinct from the discrete electronic transitions producing Characteristic X-rays.

Changing the accelerating voltage changes the available kinetic energy per Electron and the X-ray tube cutoff. Changing the number of arriving Electrons changes the number of opportunities for photon emission. These are distinct controls: a larger electric current does not by itself give each Electron more energy. For an original idealized budget, $V=50\mathrm{kV}$ and tube electric current $i=0.20\mathrm{mA}$ give electrical power $Vi=10\mathrm{W}$ and arrival rate $i/e\simeq 1.25\times 10^{15}{\mathrm{s}}^{-1}$, where $e$ is the elementary charge. This is input power, not emitted X-ray power; obtaining the latter requires a conversion efficiency.