Aston velocity focusing 2026-10-18
In Mass spectra and isotopes by Francis William Aston, printed pp. 10–12, Fig. 1, Francis William Aston describes successive electric and magnetic deflections in one plane, with opposite senses. This geometry focuses a range of ion speeds; it does not require the straight-through cancellation of a velocity selector.
The reason compensation is possible follows from the Lorentz force. In a short region of length , a small electric deflection angle has magnitude : the transverse acceleration acts for a time , and the deflection angle is the acquired transverse velocity divided by . A short magnetic region of length gives , since the magnetic force already contains one factor of speed. Slower ions therefore receive a disproportionately larger electric deflection.
An original local approximation makes the focusing idea explicit. At fixed mass-to-charge ratio, replace each region by a small angular kick and include the drift distances in two positive constants and . With , write the detector coordinate asChoosing the geometry and fields so that eliminates the first-order speed sensitivity. Indeed,A fractional speed error then contributes only at order in this approximation. This is a local thin-kick explanation, not Aston's exact pole geometry, focal-plane equation, or a prediction of its measured mass resolution. Finite slit widths, initial directions, and field boundaries still matter. Unlike a velocity selector, focusing can collect nearby speeds into a narrow image instead of discarding all but a narrow accepted range.
Successive opposite deflections in an early mass spectrograph, compared with a chosen velocity selector and magnetic analyzer
. Top: functional schematic of the sequence described by Francis William Aston; colored paths indicate one mass-to-charge ratio at nearby speeds. Paths use the local thin-kick illustration, and dimensions and plate orientation are not a reconstruction. Bottom: an independently chosen teaching geometry has overlapping selector fields followed by a separate semicircular magnetic path. Both diagrams show positive ions; the Thomson charge-to-mass experiment gives the corresponding negative-electric charge example. Details.A charge moving nonrelativistically in prescribed fields obeys the Lorentz force lawThe magnetic part is perpendicular to velocity, so : the electric field can change kinetic energy, while the magnetic field alone changes direction without doing work.
In a uniform electric field with no magnetic field, acceleration is constant: and . The trajectory is a parabola when there is initial motion perpendicular to the field, and a line when motion is purely along it. Reversing the charge reverses the electric acceleration.
In a uniform magnetic field with no electric field, resolve velocity into parallel and perpendicular components. The parallel component is constant; the perpendicular component rotates at the cyclotron frequencyThe resulting path is a helix, or a circle if , with pitch . Charge sign determines its sense of rotation. These relations underlie magnetic bending and mass/charge analysis. At relativistic energies, use momentum ; at fixed energy the cyclotron frequency becomes .
For uniform crossed fields , the velocity satisfies . The orbit is a gyromotion about a guiding center drifting withindependent of mass and charge sign. A velocity selector transmits particles with the appropriate direction and speed without deflection. If the electric field has a component along the magnetic field, that component accelerates the parallel motion instead. Nonuniform fields can add other drifts; the simple helix and uniform crossed-field expressions require the stated uniform-field assumptions.
For injected velocity , the Lorentz force isFor nonzero electric charge and nonzero operating current, the velocity selector condition isThe requested nonrelativistic kinetic energy is consequentlyBoth electric current and electric charge cancel. Reversing the sign of reverses both component forces and preserves their cancellation. The dimensions are consistent because has units of speed, while is dimensionless. The assumed nonrelativistic particle regime requires ; the problem supplies no values with which to evaluate a numerical energy.
Thomson charge-to-mass experiment 2026-10-18
The Thomson charge-to-mass experiment infers the magnitude of an Electron's charge-to-mass ratio by combining electric and magnetic deflection of cathode rays. The central idea is to determine speed separately from magnetic curvature: a known speed turns the observed gyroradius into a measurement of .
In 1897, J. J. Thomson used two grounded slits in an evacuated glass tube, then aluminium plates long, wide and apart. A battery supplied their electric potential difference. Deflected cathode rays produced a phosphorescence patch on the glass; an external scale and movable luminous pointer recorded its position in darkness. Greater evacuation reduced gas electrical conductivity that screened the electric field; reversing plate polarity reversed deflection. External coils supplied the magnetic field, calibrated by induction against larger coils. He adjusted equal electric and magnetic deflections. [ref]
Cathode Rays by Joseph John Thomson. Cathode Rays (1897), Fig. 2; second m/e method, apparatus and calibration
His comparison included air, hydrogen, carbon dioxide, and aluminium versus platinum cathodes, supporting a common carrier. He explicitly noted uncorrected magnetic bending outside the plates. His tables give , the reciprocal of the magnitude used here. The inferred ratio alone could not separate electric charge from mass. [ref]
Cathode Rays by Joseph John Thomson. Cathode Rays (1897), second m/e method: table, corrections and interpretation
To connect this readout with the Lorentz force, derive a simple nonrelativistic model in modern SI notation. Let the uniform deflecting region have length , followed by a field-free drift of length . Assume a narrow speed distribution, small deflection angles, negligible collisions, and matching electric and magnetic field profiles. For an Electron with speed , the electric acceleration has magnitude , the transit time is approximately , and the subsequent drift adds exit transverse velocity times . Thus the displacement magnitudes measured separately with only electric field or only magnetic field areThe electric expression follows from constant transverse acceleration; the magnetic expression uses its small-deflection approximation. Equal displacement magnitudes then giveThis is an ideal derivation of the comparison principle, not a numerical reanalysis of the historical tube. Different exterior magnetic field profiles invalidate cancellation of the common geometrical factor. The comparison determines through deflection and the known apparatus dimensions; it does not require a downstream semicircle.
For a second, deliberately different teaching geometry, combine a velocity selector with a separate region containing only a uniform magnetic field perpendicular to the selected velocity. Here belongs to the velocity selector, while belongs to the analyzer: they need not be equal. The magnetic Lorentz force supplies the centripetal acceleration, soIf the analyzer turns the beam through a semicircle before it hits a screen in the entry plane, the separation between entrance and impact is the diameter: . For a shorter observed arc, the screen displacement is not generally a radius; fit the appropriate circle geometry. This two-stage velocity selector and curvature apparatus is an original ideal teaching model, not a claim that Thomson's Fig. 2 used a separate selector and semicircular analyzer.
For a worked example, stipulate , , , and . The selected speed and inferred charge-to-mass ratio magnitude areThe SI units provide an independent check: and , because . The charge-to-mass ratio of the Electron is negative; this calculation gives its magnitude. The bending direction gives the sign of the electric charge once the magnetic field direction is known. Scaling both and by the same positive factor preserves every displayed trajectory, so an independent electric charge measurement is required to determine mass separately.
The curvature formula assumes nonrelativistic momentum . At higher speeds, the relativistic cyclotron orbit gives , hence , where is the Lorentz factor; the ideal straight-through selection still follows from vanishing Lorentz force. The stipulated speed is about times the speed of light, making about . For this example the nonrelativistic approximation is adequate, but no massive particle can be selected at . Finite slit widths, collisions with residual gas, uncertain magnetic field calibration, and fields outside the ideal boundaries limit a real inference; repeat at several selected speeds and analyzer strengths to test consistency of rather than trusting one spot position.
Velocity-selected magnetic mass analyzer 2026-10-18
Reuse the velocity selector analysis in the Thomson charge-to-mass experiment, but now send positive ions with into a separate magnetic analyzer. The selector fields and give . If the analyzer field is perpendicular to the selected velocity, its gyroradius givesfor a semicircular return to the entrance plane. The displayed impact separation is a diameter. This formula is linear in at fixed selected speed; the fixed-electric potential difference model above instead gives . They impose different experimental conditions.
For a chosen example, take , , and . Thus . Approximating an ion mass by and setting gives and . Here denotes the unified atomic mass unit. These are stipulated teaching inputs, not a reported Aston measurement or an exact magnesium atomic mass.
A finite accepted speed range broadens the radius distribution. At fixed and , . At fixed electric charge and mass, gives for a small kinetic energy spread. A one-percent kinetic energy spread therefore produces roughly a half-percent radius spread before other broadening is included. Its width convention must be specified before converting that statement into a mass resolving power.
Velocity selector 2026-10-18
A velocity selector uses perpendicular electric field and magnetic field to transmit a narrow range of speeds along a chosen beam direction. Assume uniform static electric field and magnetic field , with , and an incident velocity . The cross product gives , so the transverse Lorentz force isFor an Electron, the electric force points downward and the magnetic force upward. A faster Electron initially bends upward; a slower one initially bends downward. At the selected speed, both forces cancel along the whole straight trajectory. The cancellation is independent of mass and nonzero electric charge; it selects velocity, not a particular charge-to-mass ratio. A component of velocity parallel to the magnetic field is not constrained by the cancellation, so the incident beam must also have its direction restricted.
A real exit slit accepts a finite range of speeds and incident directions. A zero displacement at one screen alone does not establish zero force throughout the path: a curved trajectory could return to that screen position. The ideal velocity selector interpretation requires a straight aligned beam, known overlapping electric field and magnetic field, and sufficiently narrow entrance and exit slits. Its useful role in the Thomson charge-to-mass experiment teaching model is to supply speed independently of the subsequent magnetic bending.


