Critical exponents describe leading singular powers as the reduced temperature or conjugate field approaches zero. With used for the order-parameter critical exponent to avoid confusion with inverse temperature, the definitions include
At criticality the connected correlation function behaves as . These definitions refer to the singular part and allow additional logarithms at marginal dimensions.
For an ordinary scalar Landau free energy, the equation of state is . Below the transition , giving . Differentiating the equation of state gives : it equals above and below the transition, so . The quadratic fluctuation kernel is in the symmetric phase, giving correlation length and . At zero mass the momentum-space correlation function is proportional to , so . The minimized free energy and critical equation of state give and , as calculated in the root solution.
At the tricritical point, and . Then , and is above and below the transition. The gradient kernel still gives and . Therefore
These are mean-field critical exponents. A systematic derivation incorporating fluctuations uses the renormalization group, extracts the relevant scaling eigenvalues, and differentiates the singular free-energy density, as in Question 3.
After separating an additive identity term and using dimensionless couplings, let be one blocking-and-rescaling step. A renormalization-group fixed point satisfies . Near it, linearization gives scaling coordinates with
At a critical renormalization-group fixed point, no finite characteristic length survives. Since the correlation length measured in lattice units transforms as , a nonzero scale-invariant critical length must be infinite. A sequence of systems approaching the same fixed point therefore has common long-distance behavior.
The scaling hypothesis for critical phenomena asserts that the singular free-energy density transforms homogeneously under these scaling coordinates. It follows from repeated blocking near the fixed point, once analytic backgrounds are removed and no dangerously irrelevant coupling supplies an additional singular dependence. The temperature and magnetic-field scaling directions set the principal departures from criticality; irrelevant directions label microscopic differences that disappear at long distances.
Use the connected correlation function
Away from criticality its large-distance decay is exponential, with a model-dependent algebraic prefactor; the exponential rate defines the correlation length . At criticality diverges and the decay becomes a power law. Subtracting the disconnected product is essential in the ordered phase: the unconnected correlation function tends to the square of the spontaneous magnetization rather than to zero.
For total free energy , at fixed temperature and a field-independent additive constant,
Writing , differentiation of the Boltzmann weight gives . Consequently
For a translation-invariant state, each separation occurs times, so . Without translation invariance, the double-sum formula remains the correct relation.
Gaussian calculation and thinning. Interpret the displayed local expression as a Hamiltonian density, to be integrated over space. For and , completing the square in Fourier modes gives the connected correlation function
The uniform field changes the mean to because of the source's convention, but does not change this covariance. The nearest pole has inverse length , equivalently the Green function solves . Thus
Here is the positive mass coefficient; if denotes its positive square root, .
For a Gaussian thinning transformation, split modes into and . The modes are independent, so integrating out the shell produces only an additive free-energy density and leaves the low-mode quadratic action unchanged. Restore the cutoff by and . Substituting into the kinetic, mass and source terms gives
Hence the thermal and field scaling eigenvalues are and . Applying the exponent relations derived in part (f) gives the requested formal Gaussian critical exponents
The heat-capacity result can also be checked directly: the quadratic determinant contributes , after removing analytic ultraviolet terms, and two derivatives with respect to give . At , the free-energy power is accompanied by a logarithm, , whose second derivative still has index . At this becomes a logarithmic heat capacity singularity, with index , rather than a strictly constant singular term.
There is an important ordered-phase obstruction in a Gaussian scalar model. A purely quadratic potential is unbounded below for , so the Hamiltonian as printed has no stable ordered phase and no literal spontaneous-magnetization exponent. The displayed is its Gaussian scaling index, obtained by assigning the field its Gaussian scaling dimension; it is not a construction of a stable ordered equilibrium. For , a stabilizing quartic interaction is relevant and generally changes the actual critical fixed point. For , massless Gaussian infrared fluctuations also obstruct interpreting the formal zero or negative index as an ordinary bounded-spin ordering law. These qualifications do not alter the requested thinning calculation, but are necessary for its physical interpretation.
Use the connected correlation function , so that the constant ordered contribution is removed. Away from a thermodynamic critical point its long-distance decay defines the correlation length: when this limit exists. In a massive rotation-invariant phase the exponential decay is typically multiplied by an algebraic factor.
Expand the Landau-Ginzburg theory free energy about a stable uniform minimum , writing . To quadratic order,
integration of the Gaussian field theory gives the Fourier-space connected correlation function . Thus the Ornstein--Zernike correlation function has
For an ordinary quartic transition, above the transition and below, so and , respectively. The correlation length diverges as on both sides, with different amplitudes. At criticality the mass vanishes and the Gaussian correlation function is proportional to for . Interactions can change this power to .
At a continuous phase transition the equilibrium order parameter tends continuously to its critical value, there is no latent heat, and the correlation length diverges. For at zero field, minimizing gives when and when . These minima join continuously at . The minimized singular free-energy density is zero above and below, so its first thermal derivative is continuous, while its second derivative has a finite jump in mean-field approximation.
A first-order phase transition instead has competing minima whose free energies cross while their order parameters remain distinct. The first derivatives of the equilibrium free energy generally jump; along a temperature-driven crossing this gives latent heat. For the symmetric sextic potential with , let . At phase coexistence, the stationary points and equality of the two free energies require
Eliminating gives , hence
At coexistence , proving that all three degenerate minima are global. The equilibrium order parameter jumps from zero to one of the two nonzero values even though . The disordered minimum loses local stability at , and the nonzero stationary points first appear at . These spinodal points delimit metastability and are not the equilibrium transition line. Cubic terms, when symmetry permits them, provide another common route to a first-order transition.
Figure 1.
Quartic Landau minima through a continuous transition and three degenerate sextic minima at first-order coexistence
. Details.
Use for inverse temperature, to distinguish it from the order-parameter critical exponent . In a translation-invariant pure thermodynamic phase, the connected two-point correlation function is
For finite correlation length, at it decays exponentially, possibly with an algebraic prefactor; is the asymptotic exponential decay rate. Below an ordered transition the pure phase is selected by taking the thermodynamic limit before or . A zero-field symmetric mixture of the two ordered phases has a nondecaying connected term and does not describe the usual pure-phase magnetic susceptibility.
Let denote extensive physical free energy and . Since the field contributes to the statistical Hamiltonian, differentiation gives
Expanding the variance and using translation invariance proves the correlation-function susceptibility sum rule:
The sum includes . If the source is instead defined as the dimensionless quantity , the corresponding derivative omits the displayed inverse-temperature factor.
A real-space renormalization group step of length factor uses a local blocking kernel satisfying . For example, a deterministic majority-spin rule assigns one coarse Ising spin to each block; tied blocks can be resolved with equal probabilities. Define the blocked statistical Hamiltonian by
The spacing becomes . All generated interactions, including multispin terms and the field-independent constant, must be retained for an exact transformation. Summing over uses normalization to prove . Iteration gives and .
The coarse probability law is the exact marginal law of these block variables. Indeed, for any coarse observable , its expected value is the microscopic expected value of . A blocking rule that retains the long-wavelength order-parameter mode, with source and observable transformations tracked, therefore retains long-distance response and correlation functions. Their field normalization may change, while their physical length scales and critical singularities do not. Partition-function equality alone would not justify this assertion for an arbitrary kernel that discards all slow variables. Truncating the generated operator family is likewise an approximation.
For the free-energy recursion use dimensionless free energy per site,
in the thermodynamic limit. Exact partition-function invariance gives . If one step sends to , the coefficient records the identity-operator contribution from eliminated fluctuations and normalization. Consequently
Repeated substitution derives the additive free-energy recursion under blocking:
In physical energy units, divide this convention by . The additive term is essential for absolute free energies even when it does not affect the leading critical powers.
A renormalization-group fixed point satisfies . Linearize in scaling coordinates so that . A relevant operator has , an irrelevant operator has , and a marginal operator has with behaviour decided by nonlinear terms. Thus the eigenvalues of the discrete linear map are ; the sign criterion applies to the generator exponents , not to the discrete multipliers. The critical surface is the stable manifold on which every relevant scaling field has been tuned away. Irrelevant coordinates flow to the renormalization-group fixed point along it. A repulsive renormalization-group trajectory leaves the renormalization-group fixed point along an unstable relevant direction, ultimately entering a noncritical phase or another scaling regime.
Figure 1.
Local renormalization-group flow in the zero-field slice: attraction along the critical surface and repulsion in the thermal direction
. Details.
To separate the singular free-energy density from its regular background, suppose the eliminated-mode contribution is analytic near the renormalization-group fixed point. Look for an analytic background satisfying . Then satisfies . In linear thermal and field coordinates, an analytic monomial has background coefficient
provided the denominator is nonzero. This explicitly explains when analytic subtraction of an inhomogeneous renormalization recursion works. The printed inhomogeneous equation may describe the free-energy function before this subtraction, or a singular part defined only up to analytic terms. The inhomogeneous sum need not be small compared with the full free energy: an analytic constant can dominate a vanishing singular contribution. It can be omitted in deriving leading singular powers after regular subtraction, provided no renormalization-group free-energy resonance, marginal logarithm or dangerously irrelevant coupling obstructs the homogeneous critical asymptotics. At a renormalization-group free-energy resonance , additive logarithms can remain, so simply dropping the term would miss them.
Suppose there are exactly two relevant scaling fields, thermal and magnetic , with positive exponents , and the remaining fields approach a regular limit. Physical reduced temperature and magnetic field agree with these coordinates to leading order, up to nonuniversal metric factors. The homogeneous scaling hypothesis for critical phenomena is
as an asymptotic scaling equation. Choose to make the thermal argument or . Defining gives
The two functions describe respectively and : approaching the transition from disordered and ordered sides need not give the same function. In particular the ordered zero-field function has one-sided derivatives associated with spontaneous magnetization. Metric factors multiply this formula in different microscopic normalizations.
The correlation length in Bravais lattice units obeys . At , the same choice of gives . Two thermal derivatives of give . One and two field derivatives give, respectively, and , assuming the relevant branch amplitudes are nonzero. At , choose ; then , so . Hence
Simple algebra now gives the Rushbrooke scaling relation and the hyperscaling relation . Also , giving the Widom scaling relation. These statements refer to leading singular contributions with the homogeneous two-field scaling assumptions. Above the upper critical dimension, the quartic coupling is dangerously irrelevant because it is still needed to stabilize the ordered phase; ordinary mean-field critical exponents then satisfy Rushbrooke and Widom but generally not hyperscaling. Marginal logarithms also require qualifications at the upper critical dimension.
For the connected-correlation scaling form , the function tends to a finite nonzero value as and decays exponentially at large , up to powers of , in a massive short-range phase. The scaling ansatz alone does not fix that prefactor. If the usual massive Gaussian field correlation tail applies, matching the powers gives , with a correlation-length-dependent amplitude in fixed by matching the critical scaling form.
In physical coordinates the lattice sum has site-density factor . Its long-distance singular part therefore gives
where is the area of the unit sphere in dimensions. For , finite , an integrable exponential tail and a nonzero integral, the last factor tends to a finite nonzero constant as . Microscopic distances contribute a regular background. Thus , proving the Fisher scaling relation
Equivalently the field has scaling dimension , so its conjugate field has , which gives the same identity from the exponent formulas above.
Write the transverse displacement as and take the common line-of-sight interval to be . The rotation measure is a line integral of the magnetic field, so its correlation is
Substitute the Fourier inversion of the solenoidal isotropic spectral tensor. Keeping the finite observation length gives the exact windowed expression
The allowed extension of the longitudinal displacement integral to the whole real line is the long-path projection of a magnetic correlation. It applies when is much larger than the correlation length: equivalently, the squared window becomes inside the integral. The Dirac delta function sets , leaving
Statistical isotropy makes this a function of . The displayed two-dimensional relation is the intended long-path approximation; the preceding windowed formula accounts for finite-length edge effects.
Use the connected correlation function in a selected pure thermodynamic phase. The exponential correlation length is defined by , when this limit exists in the chosen direction. Linearizing the Landau-Ginzburg theory around a stable uniform minimum gives
Hence the Landau scalar correlation length is . Away from criticality the massive Gaussian field correlation tail behaves as , up to its amplitude. At a continuous transition tends to zero, so diverges and fields vary on scales much longer than the lattice spacing. This motivates a gradient expansion, but the simultaneous growth of correlated fluctuations is precisely why the Ginzburg criterion must be checked.
A first-order phase transition exchanges distinct global minima of the Landau free energy; the order parameter jumps and a thermal crossing generically has latent heat. A continuous phase transition has minima merging continuously and a diverging correlation length. A local loss of stability at a spinodal point is not the equilibrium coexistence condition.
For the sextic even Landau potential, write . At a nonzero zero-field stationary point, . To coexist with , also require . Eliminate to obtain and , which requires . On this locus
proving that all three equal minima are globally stable. Their curvatures are at zero and at the nonzero minima, so the correlation length is finite when is fixed. For , by contrast, the nonzero minimum approaches zero as , giving the ordinary continuous transition. At fixed and , crossing exchanges the two ordered minima discontinuously even though the zero-field thermal transition at is continuous.
Use for inverse temperature, to distinguish it from the order-parameter exponent. In a translation-invariant pure thermodynamic phase, the connected correlation function is
The subtraction is essential below the transition. Its exponential correlation length is defined by , with direction specified if the lattice is anisotropic. Away from criticality, has a tail proportional to times an algebraic prefactor. In the massive continuum scalar approximation that prefactor is ; at criticality the exponential cutoff disappears and instead. The large-distance limit here is , as the PDF shows.
Let . With the energy convention , the magnetization per site and magnetic susceptibility are
Writing , direct differentiation of the partition function gives . Thus the correlation-function susceptibility sum rule is
In physical continuum coordinates the lattice sum becomes , so omitting the site-density factor would change the normalization. A derivative with respect to the dimensionless source instead absorbs the explicit inverse-temperature factor.
An exact renormalization-group transformation with length factor can be defined by a nonnegative normalized blocking kernel satisfying . A deterministic majority rule is one example; randomized tie-breaking preserves its normalization. Define the blocked energy, including its constant, by
Summing over proves . All generated operators must be retained for this identity to remain exact; a finite-coupling truncation is an approximation. After iterations, and the spacing is . Long-distance physics is preserved because this is a marginalization of microscopic probabilities, with observables and sources transformed along with the energy. It integrates short-distance variables rather than changing their effects on retained observables. Physical lengths remain fixed even though the correlation length in units of the new spacing is reduced by .
For clarity, now use dimensionless free energy per site . Exact equality of the partition functions gives
A constant microscopic energy shifts every blocked weight by the same factor, so . Substitution at one step yields the additive free-energy recursion under blocking
Induction now gives the requested relation
The function is the identity-operator contribution to renormalization-group free energy: it records eliminated-mode entropy, integration constants and normalization factors. A free-energy function satisfying this inhomogeneous equation need not be purely singular until its analytic background has been subtracted.
At a renormalization-group fixed point, . Linearize in scaling coordinates so . Here is a scaling exponent, not the discrete multiplier itself. A positive gives a relevant operator, a negative one an irrelevant operator, and zero a marginal operator. The critical surface is the stable manifold: tune every relevant scaling field to zero and the irrelevant coordinates flow toward . A repulsive renormalization-group trajectory leaves along a relevant direction; it can still have irrelevant coordinates contracting toward that manifold. The plot shows the section when temperature and field are relevant: is the critical line in this section, while an independent nonzero field is another direction away from criticality.
Figure 1.
Renormalization-group trajectories near a critical fixed point, showing thermal repulsion and irrelevant contraction in the zero-field section
. Details.
The inhomogeneous term cannot simply be discarded from the full free energy. If an analytic background solves , its subtraction leaves obeying homogeneous scaling. For example, in linear thermal and field coordinates, a source monomial is removed by
When the denominator vanishes, the source is resonant and can instead produce a logarithm. Thus the homogeneous singular equation is justified after analytic subtraction when there is no relevant resonance affecting the leading singularity, no marginal logarithm that has been omitted, and no singular dependence on a dangerously irrelevant coupling. Merely saying that is regular is insufficient to discard the whole weighted sum without this analysis.
Under these assumptions, with two relevant scaling fields , choose so that is of order one. The scaling hypothesis for critical phenomena then gives
Writing recovers the PDF's notation:
The sign labels the two matching branches and , which enter different phases when the flow leaves the critical neighborhood. The constants retain a branch-dependent identity contribution or a chosen split of the scaling function. They are determined by the same matching problem, not independently adjustable nonuniversal free-energy offsets. An arbitrary analytic offset from belongs to the subtracted background. The formula describes the singular part; adding that background recovers the full physical free energy.
At , restore the common metric factors as . Their ratio at equal is , proving the expected universal singular free-energy amplitude ratio because and cancel. The ratio of full free energies including an arbitrary regular is not universal; zero amplitudes and logarithmic resonances also require separate treatment.
The critical exponents are obtained by rescaling and differentiating, not by identifying them with the discrete multipliers. The correlation length obeys , hence . Two temperature derivatives of give , while one and two field derivatives give the ordered magnetization and susceptibility powers. Thus
For , instead set and choose the blocking scale by , obtaining and then differentiate. A nonzero spontaneous ordered-branch derivative is assumed in the formula for . In particular the hyperscaling relation is . Its physical assumption is an order-one singular free energy per correlation volume, with a single diverging length and no dangerous variable changing its volume scaling. Above the upper critical dimension, a stabilizing quartic coupling can invalidate that assumption even though the correlation length still scales.
For the last model, take the quadratic Hamiltonian exactly as visually printed: its source term is , outside the half multiplying the gradient and mass terms. With and , its connected quadratic covariance is proportional to
The pole scale, or the massive Gaussian field correlation tail obtained by its Fourier transform, gives
The uniform source shifts the mean to and does not change the connected covariance. Replacing by matches the earlier magnetic source convention without changing any scaling index.
Define a Gaussian thinning transformation by retaining momenta , integrating the Gaussian shell, and rescaling
The gradient coefficient is unchanged. Counting volume and field powers in the remaining action gives
Shell integration contributes only the additive determinant term. Thus when the thermal variable is proportional to , and . Inserting these into the homogeneous index formulas gives the requested Gaussian critical exponents
The specific-heat power can also be verified without hyperscaling: two mass-squared derivatives of produce an integral proportional to . For , rescaling gives ; at the divergence is logarithmic, with power index zero. At the determinant itself has an additive resonance, although its heat-capacity power remains one.
There is a genuine limitation to the last printed request. The Gaussian order-parameter scaling index is formal: a pure quadratic theory has at , and at the uniform energy is unbounded below, so its partition function diverges. It therefore has no stable ordered branch from which a spontaneous-magnetization exponent can be measured. The thinning derivation establishes the index requested by the PDF, but not a nonexistent ordered phase. A stabilizing quartic interaction is relevant for and generally changes these Gaussian indices to the interacting critical ones.
Use the arc length and the unit tangent of an inextensible filament. In the high-force state choose its positive longitudinal branch. The constraint gives
The extension is . The curvature of a space curve obeys . Since is second order in small fluctuations, its squared contribution is fourth order. Thus the worm-like chain energy through quadratic order is
Positive force suppresses transverse orientation fluctuations, while the filament bending modulus penalizes their spatial variation.
To apply the equipartition theorem without missing either component or a mode-counting factor, expand each component in a real orthonormal basis of eigenfunctions of , , with and . The quadratic energy is . Each real quadratic degree of freedom contributes , so
For a chain long compared with the force-dependent correlation length, the interior is translation invariant and the mode sum per length becomes . Equivalently, for the Fourier transform ,
The negative and positive wavenumbers here represent the real-field mode count consistently, rather than two independent complex modes. Summing both transverse components gives the high-force worm-like chain elasticity
where the integral follows by setting and using . Therefore
Here is the three-dimensional zero-force persistence length. The result requires , negligible backbone stretching, and a long-chain bulk approximation. It does not describe the eventual bond-stretching regime. For a continuum polymer description, the force-dependent length should also exceed the microscopic cutoff.
For comparison, a three-dimensional freely jointed chain has contour length and independent link orientations. At force , a link of polar angle has Boltzmann factor with . Its angular canonical partition function is
The total canonical partition function is . Differentiating with respect to force gives the force-extension of a three-dimensional freely jointed chain:
Consequently
The extension deficits scale as and respectively. Inverting them gives force divergences proportional to the first and second inverse powers of the deficit. Freely jointed link rotations cost no bending energy; the worm-like chain instead has a continuum of coupled bending modes whose contributing wavelengths change with force. Setting a long-wavelength coarse-grained link length can match weak-force statistics, but does not make these high-force laws identical.
For the transverse tangent correlation of a stretched worm-like chain, use a separation consistently: the source writes but integrates a separation denoted . In the translation-invariant bulk the spatial average is redundant and
To evaluate the integral without an assumed decay law, let be the inverse Fourier transform of . Then . Away from zero, decay at both infinities requires with . Integrating across zero yields , so . Thus
At this agrees with the two-component equipartition theorem calculation. The correlation length decreases with force and is distinct from the zero-force persistence length. The full tangent correlation has a nonzero aligned background; the exponentially decaying quantity here is specifically the transverse correlation.
For a finite open chain, the source's integral samples beyond and supplies no endpoint tangent conditions. An exact finite-length correlation is therefore not uniquely specified. The result above is the intended bulk form when . As one explicit finite convention, periodically extending the tangent fluctuations gives the periodic finite-length tangent correlation of a stretched worm-like chain
where is the distance from zero around the periodic interval. Then , and the extension formula acquires this same finite-length factor. The bulk law is recovered as . This makes the endpoint assumption explicit rather than claiming an unspecified finite-chain correlation is exactly translationally invariant.
Use the connected correlation function , since the disconnected constant in an ordered phase does not measure fluctuation decay. Away from criticality its large-distance exponential defines the correlation length:
when that limit exists. Algebraic prefactors do not affect this definition.
Expand the Landau-Ginzburg theory about a stable homogeneous minimum . With , the quadratic fluctuation energy is . The Gaussian functional integral gives
This Ornstein--Zernike correlation function shows why the curvature of the free-energy minimum controls correlations. At a continuous phase transition that curvature vanishes, allowing long-range fluctuations. In the ordinary quartic theory with , above the transition and on either ordered branch below, so on both sides. At an equilibrium first-order transition the competing minima generally retain nonzero curvature, and the correlation length remains finite. The limit of local stability at a spinodal point is a distinct mean-field phenomenon.