Take independent steps, each with probability and with probability . Reverse a step sequence by reading it backward and changing each sign; use the same biased law for both experiments. With positive steps, the forward sequence weight is and its reversed weight is . Their logarithm ratio is
Here is dimensionless entropy production, not an entropy in joules per kelvin. A Markov chain on a three-state ring gives a state-space realization: start uniformly, take a clockwise step with probability and a counterclockwise step with probability . The uniform stationary distribution makes endpoint weights cancel. A physical interpretation as exchanged heat requires local detailed balance with bath entropy per directed step; the abstract model alone specifies path probabilities.
For an allowed value , the binomial distribution gives
This is an exact same-law finite fluctuation theorem, with no long-time approximation. For , and , and . The positive mean is , although the all-negative path has nonzero probability . Directly, .
Figure 1.
Exact biased-step model: discrete entropy-production probabilities and their log ratio at nine steps
. Details.
The left panel shows exact probability masses for , with negative values highlighted; the right panel tests the logarithm ratio against . These are model values, without experimental measurements or simulated measurement noise.
Consider a finite-duration Markov process with discrete, time-even states coupled to one thermal reservoir at positive temperature . Let include the initial probability of the sample trajectory . Define by reversing the control protocol and initializing it with the actual forward final probability distribution . Write for the same states visited in reverse time order. Require normalized path laws with matching probability support: a path has positive forward weight exactly when its reverse has positive reverse weight. This excludes irreversible forbidden transitions and missing initial states.
Under local detailed balance, with positive heat delivered to the thermal reservoir, the full path-weight logarithm is
The endpoint term is the change in stochastic system entropy; the conditional path ratio alone accounts for the thermal reservoir. Here is the Boltzmann constant. Both terms matter even for a short observation. [ref]
Define the conjugate reverse functional by , so . Summing the path identity over paths with a given value gives the exact finite fluctuation theorem
for nonzero denominator, using probability masses or corresponding probability density functions. This is defined by the paired laws: it need not be the total entropy production obtained by independently restarting the thermodynamic construction for the reverse experiment. A generic driven experiment therefore does not imply .
The first part of is the change of the quadratic energy associated with the active Ornstein–Uhlenbeck force. The second is minus the change in the particle's potential energy, measured in thermal-noise units. The time integral is the work done by active propulsion, again divided by its noise scale; the full log ratio is the trajectory's time-reversal asymmetry or entropy production.
In a stationary confining state the two endpoint terms remain as and have zero mean, while the mean active work and the mean log ratio grow proportionally to . Endpoint-term distributions approach time-independent distributions with positive and negative fluctuations. Under mixing assumptions, the time-integrated work has a large-deviation distribution: its central part becomes approximately Gaussian with mean and variance proportional to , while its far tails scale exponentially in . The log-ratio distribution obeys the corresponding fluctuation theorem symmetry.