An order parameter distinguishes thermodynamic phases and transforms under the symmetry that may be broken. For a scalar ferromagnet it is the magnetization per site; a disordered zero-field phase has , while ordered pure thermodynamic phases have . In a fluid one can instead use the density measured relative to its critical value; the field conjugate to it is then related to the chemical potential rather than literally a magnetic field. A nonzero value in the presence of an explicit conjugate field is not by itself evidence of a spontaneous transition.
The LG theory describes a slowly varying local order parameter by a symmetry-constrained free-energy functional, for exampleAt , a symmetry excludes odd powers. The coefficients are assumed analytic functions of the controls near the transition, and the expansion is stabilized by a positive highest retained even coefficient. The Landau approximation obtains equilibrium by minimizing this functional, neglecting long-wavelength fluctuation corrections. Its nonconvex local potential describes distinct candidate phases and mean-field metastability; the exact thermodynamic potential is convexified when macroscopic mixtures are admitted.
In a finite symmetric system, the zero-field expectation of can vanish even below the transition because both ordered orientations are sampled. Spontaneous order is defined by taking the thermodynamic limit before removing a selecting field, for example . This distinction also matters for the connected correlations used below.
A first-order phase transition has a discontinuity in a first derivative of the equilibrium free energy, such as the entropy or order parameter. It can have latent heat when the entropy jumps. A continuous phase transition has a continuously vanishing order parameter and no latent heat, with singular higher derivatives and a diverging correlation length. The LG theory compares global minima, not merely the points where a local minimum loses stability.
For the uniform quartic Landau free energythe equation of state is . At zero field the stable minimum is for , and for . Thus tuning through zero gives a continuous transition. For a fixed , varying through zero instead switches between the two ordered minima and makes jump, giving a first-order phase transition in the conjugate field.
A temperature-like first-order transition can occur at zero field when and a positive sextic term stabilizes the potential. Write . Stationarity of a nonzero phase gives , while equality with gives . Solving these two conditions yieldsThe order parameter jumps from zero to . At this pointso the competing stationary points are genuinely global minima. This phase coexistence condition differs from the spinodal points and , which mark loss or creation of local stability, not equilibrium coexistence.
If the symmetry permits a cubic term , a positive quartic coefficient does not preclude a first-order transition. For with , stationarity and coexistence give and . This is the first-order transition in a cubic-quartic Landau potential; the symmetry restriction on the expansion is therefore part of the prediction.
Along an isolated two-phase coexistence line, two distinct stable minima have equal free energy. If this line ends at an ordinary interior endpoint without encountering another phase, the distinction between the two phases must disappear: their minima and the intervening barrier merge. For separated nondegenerate minima, their stationary values are smooth functions of the controls. The difference has . The implicit function theorem therefore continues the equation as a local coexistence curve. It cannot end while those distinct stable minima persist.
At the merger the potential satisfiesThe third-derivative condition is essential: a stationary zero-curvature point with nonzero third derivative is an inflection, not a stable equilibrium. Shifting to gives an ordinary quartic Landau free energy with two independent control directions, temperature-like and field-like. The curvature and the order-parameter discontinuity vanish, the magnetic susceptibility diverges, and the correlation length diverges. The endpoint is therefore associated with a continuous transition. This is the critical endpoint of a quartic Landau free energy mechanism.
In the symmetric quartic example, the coexistence line is . Its jump vanishes at , where . This supplies a concrete realization. The word “must” requires the stated ordinary-endpoint assumptions: a first-order line can instead meet a third phase, a multicritical point, a boundary of parameter space, or continue without a finite endpoint. A spinodal point alone is not an equilibrium critical endpoint.
Critical exponents describe leading power-law singularities as the reduced temperature and the conjugate field tend to zero. Their amplitudes depend on microscopic details, while the exponents are characteristic of a universality class. Define on a selected ordered branch, at zero field, for the singular heat capacity, and . Also define and . In these statements is the order-parameter critical exponent, not inverse temperature.
Assume with and a nonzero positive quartic coefficient . Minimizing the quartic potential gives , hence . Differentiating its equation of state givesso with different amplitudes. At , , giving . The minimized potential is zero above the transition and below, so its second temperature derivative has a finite jump: .
The quadratic fluctuation kernel around the stable uniform minimum is , so . Since is above and below, . Its critical momentum dependence is , giving . Thus the ordinary mean-field critical exponents areThese are predictions of the Landau approximation, whose validity is constrained by the Ginzburg criterion; they need not be the exponents of the fluctuating theory below its upper critical dimension.
A tricritical point joins continuous and first-order transition loci and requires tuning an additional temperature-independent control. In the scalar sextic potentialit occurs at : both the quadratic and quartic terms vanish. At , the transition is continuous at ; at , it is first-order at . The jump tends to zero as , so these loci meet at the tricritical point.
For the three-control phase diagram with coordinates , the sheet below these transition loci has coexistence of the two ordered phases. For its boundary is the ordinary continuous critical line . For the boundary is a tricritical three-phase line, where and all coexist. Two symmetry-related tricritical wings extend from that line into and , describing first-order coexistence between small- and large-magnitude phases of the same sign. Each wing ends along an ordinary wing critical edge.
The critical-edge conditions giveHere , so these are ordinary quartic endpoints. The two wing critical edges and the zero-field ordinary critical line are three continuous critical lines meeting at the tricritical point; the three-phase first-order line also ends there. The “3D” phase diagram refers to three independent controls; it is distinct from the spatial dimension of the field theory.
The figure uses actual sextic-potential coexistence surfaces rather than drawing arbitrary wings. For two coexisting nonnegative minima , put . The tricritical wing coexistence factorizationholds when , and . It proves that both minima are globally stable. The limits and produce the three-phase line and critical edge, respectively; reflection gives the other wing.
At , on the ordered side and . At the critical isotherm . Thus the tricritical mean-field critical exponents areThe source's extra control is required to tune to zero; simply changing temperature in a generic quartic system does not produce tricriticality. The tricritical upper critical dimension is three, as established in Question 3.
The scaling hypothesis for critical phenomena says that the singular part of the equilibrium free energy is a generalized homogeneous function of its thermal and field-like controls. Smooth backgrounds must first be removed; the hypothesis does not claim that the entire free energy, including arbitrary regular terms, has a pure scaling form.
For the ordinary scalar quartic LG theory, set with and , and rescale the uniform order parameter asThe order-parameter-dependent free-energy density becomesDefine as the minimum of the braces, with the sign of the quadratic term respectively positive or negative. ConsequentlyFor an extensive , additionally contains the system volume. The printed double-inequality subscript labels the two temperature branches: the upper-temperature function is and the lower-temperature function is . It does not classify positive and negative magnetic fields. In particular and ; below the transition the field dependence has a cusp at zero, so derivatives are taken on a selected branch.
For the following derivatives, take to be a density, so is the magnetization density; for total free energy the derivative gives total magnetization instead. Differentiate this mean-field scalar free-energy scaling form. The magnetization is , giving and . The magnetic susceptibility is , giving . At zero field the nonzero curvature amplitudes are and .
To allow nonclassical critical exponents, replace the fixed powers byThe heat-capacity critical exponent is defined by ; temperature differentiation gives the thermal exponent in . The order-parameter critical exponent has , and the magnetic-susceptibility critical exponent has . Differentiating the scaling form givesEliminating proves the Rushbrooke scaling relationThe critical-isotherm exponent is defined by . At fixed small , the limit requires , so that the temperature factors cancel. Therefore , yielding . But the two differentiated identities also give , and hence the Widom scaling relationThese are relations among the leading power indices. At marginal dimensions, multiplicative logarithms can accompany them, and an additive analytic background must not be mistaken for the singular scaling contribution.
Work in a translation-invariant pure thermodynamic phase, and write to distinguish inverse temperature from the order-parameter exponent. The connected correlation function isAway from criticality in the massive scalar order channel, it decays exponentially, possibly multiplied by an algebraic factor. An exponential correlation length is defined by when that limit exists. At a continuous transition diverges and the critical decay is algebraic. In an ordered symmetric mixture, a nondecaying contribution can remain; selecting a pure branch prevents confusing it with connected critical fluctuations.
Let and . Differentiating the partition function with the energy term gives the correlation-function susceptibility sum ruleIf the source is instead the dimensionless , the explicit inverse-temperature factor is absent. In continuum physical coordinates the lattice sum is approximately .
Choose a normalized blocking kernel such that , replacing the sum by an integral for continuous variables. A deterministic example is a product of delta functions imposing that each coarse variable equals the average of spins in a block of sites, with its field normalization included consistently. Define the effective Boltzmann weight byKernel normalization makes the blocked partition function exactly equal to the original. Its coarse-grained variables retain the long-distance observables through their defining relation to the original fields. An exact RG step generally generates all symmetry-allowed operators; keeping only a small coupling set is an approximation, not an exact closure assumption. The geometrical coarse lattice hasso its physical volume is unchanged. A subsequent coordinate rescaling may restore the numerical lattice spacing to its initial value, which is the equivalent rescaled-coordinate convention.
Here define as free energy per lattice site, . Exact partition-function invariance givesBecause multiplies the identity operator, a blocking step has , where is the generated constant per blocked site. With this impliesThe identity-operator contribution to renormalization-group free energy includes the eliminated modes' entropy, connected vacuum terms and field-measure normalization. It cannot be discarded when calculating an absolute free energy, even though it cancels out of normalized correlation functions.
There is a useful convention behind the word “singular” in this inhomogeneous equation. After removing , still contains a regular coupling-dependent background. If and , then the genuinely nonanalytic part obeys . Thus the printed inhomogeneous representative and homogeneous singular scaling below are consistent after background subtraction. At resonances or marginal points this subtraction may leave additive or multiplicative logarithms; a strictly homogeneous pure-power form is then qualified accordingly.
A renormalization-group fixed point satisfies . Diagonalizing the linearized map gives scaling coordinates . For increasing coarse-graining length, defines a relevant operator, an irrelevant operator, and a marginal operator, whose fate needs nonlinear analysis. Here the are logarithmic scaling exponents: the eigenvalues of the discrete Jacobian matrix are , not the numbers themselves. The critical surface is the stable manifold flowing into the critical fixed point after every relevant scaling field is tuned to zero. A repulsive renormalization-group trajectory leaves the fixed point along relevant directions and flows toward a different long-distance phase.
For the requested two relevant fields, take and , with . Ignoring nonsingular irrelevant corrections and choosing a total blocking scale , the homogeneous singular free-energy density obeysChoose so the renormalized thermal field is . This provesMetric factors and regular analytic redefinitions of the scaling fields only change amplitudes. Likewise , so at the correlation-length critical exponent is . Two thermal derivatives of give the heat-capacity critical exponent , proving the hyperscaling relationTwo field derivatives also give ; one field derivative gives , and using to set the blocking scale on the critical isotherm gives . These statements assume that no dangerously irrelevant coupling makes the scaling function singular as it is removed. In particular the naive hyperscaling form need not describe the quartic ordered phase above four dimensions, where its stabilizing quartic coupling is dangerously irrelevant. That restriction reconciles this derivation with the mean-field exponents and Question 3.
The scaling form of the connected correlation function is in the continuum long-distance regime. For , tends to a finite nonzero constant. For , it decays exponentially with a possible algebraic prefactor; an isolated massive pole gives the familiar Ornstein--Zernike correlation function tail with a temperature-dependent amplitude. Exponential decay is the essential feature; the same critical algebraic power need not remain the exact large-distance prefactor.
Using the susceptibility sum rule and spherical integration givesFor and an ordinary exponentially decaying scaling function the integral tends to a finite constant: it converges at zero because is finite, and at infinity because of the exponential decay. Microscopic distances add a regular background. Thus , establishing the Fisher scaling relation
For a continuous field, field scaling and anomalous dimension giveThis field renormalization is additional to the canonical engineering factor . It makes . Invariance of the uniform source coupling then gives , agreeing with the susceptibility exponent above. With a convention , the fixed-point choice is ; the sign of the logarithmic derivative depends on this stated convention.
The parameters of a cutoff statistical field theory describe only the retained modes. Changing the ultraviolet cutoff changes which fluctuations have already been integrated out, so its effective mass, interaction coefficients and gradient normalization must change to preserve the same long-distance physics. They are not separately cutoff-independent observables. Because the source's weight is , its statistical Hamiltonian is dimensionless, with the physical inverse-temperature factor already absorbed.
For example split the scalar field into slow modes with and shell modes with . Define the momentum-shell renormalization group step byThis integrates out short-wavelength fluctuations exactly if all generated terms are retained. The new Hamiltonian can be expanded in local symmetry-allowed operators when the retained external momenta are well below the shell scale. A cumulant expansion of a coarse-grained free energy gives perturbative coefficients. Restoring the cutoff with and, for a canonical gradient term, , gives and . Interaction corrections also change the field normalization. Repeating the step produces the effective theory at successively longer distances.
To obtain the LG theory, assume a short-range scalar theory, slowly varying retained fields, analytic local couplings, positive gradient stiffness and stability, and a regime in which fluctuation corrections at the remaining scales are small. Keeping the leading gradient, quadratic and quartic operators gives a local Landau-Ginzburg theory functional. Its equilibrium in the Landau approximation is a uniform minimum, with a quadratic coefficient proportional to after the critical mass has been tuned. The RG explains why this is asymptotically consistent for the ordinary transition above four dimensions: the quartic interaction is irrelevant near the Gaussian fixed point, while it must still be retained to stabilize the ordered phase. Below four dimensions it cannot be dropped in the asymptotic critical region; an interacting Wilson-Fisher fixed point rather than the elementary saddle generally controls the transition. At four dimensions the interaction is marginal and produces logarithmic corrections. Tuning a quartic coefficient through zero requires a sextic stabilizing term and leads to tricriticality.
More concretely, in the Gaussian scaling regime let so the local quartic term is . At a total blocking scale , the leading couplings are , , . Apply the saddle approximation to the blocked potential and multiply its minimum by to convert back to original volume units. Rescaling the saddle field by givesAll blocking-scale factors cancel. This explicitly recovers mean-field scalar free-energy scaling with . Although above four dimensions, the saddle free energy is proportional to ; setting it to zero before minimization would remove the ordered phase. This is the dangerously irrelevant coupling mechanism rather than homogeneous two-variable hyperscaling.
For the perturbative calculation make the source's kinetic convention explicit. Write . The canonical normalization of a scalar gradient term uses , so the canonical quadratic and quartic coefficients are and . In what follows denote those canonical coefficients; then the reference propagator has denominator . Without this normalization the propagator denominator is , and the unmodified printed integral would not apply. At one loop the quartic tadpole is momentum independent, so it produces no gradient renormalization at this order.
In the convention fixed by the displayed equation, the truncated two-point function is the one-particle-irreducible two-point vertex, not the connected two-point cumulant itself. If and is the Legendre transform, then its second derivative is the inverse of . For a translation-invariant background,Decompose the canonically normalized statistical Hamiltonian into a Gaussian part of mass , a mass counterterm , and the quartic interaction . With the Euclidean sign convention in which a positive mass correction increases the inverse propagator, the self-energy expansion isHere contains loop corrections from proper two-point diagrams, excluding the separately displayed mass counterterm. The corresponding connected propagator begins . This fixes the sign, which would be reversed if “self-energy” instead denoted the insertion added with a plus sign inside a Dyson series.
The one-loop proper diagram is the tadpole diagram. Attaching two external fields to the quartic vertex gives contractions, divided by , so its symmetry factor is . With the loop momentum restricted by the cutoff,It is independent of external momentum. Impose the zero-momentum mass condition . This gives , henceThis is the one-loop relation using a renormalized mass in the reference propagator, or the corresponding self-consistent tadpole approximation if solved without expanding in . It is not an exact all-orders gap equation. Away from the critical infrared problem, replacing the loop mass by the bare one changes a strict perturbative result only at higher order.
Take smooth and nonzero for an ordinary stable quartic transition. To test the assumed linear thermal mass, work from the disordered side and put . For , is infrared finite. The critical bare mass is shifted, not generically zero: . Absorb the smooth temperature dependence of couplings into an analytic thermal tuning , with . Critical subtraction gives the one-loop critical-mass subtractionwhereThe infrared asymptotics of the critical-mass subtraction now distinguish the dimensions. For , is finite, soFor , diverges logarithmically. For , substitution givesso the correction to scales as and dominates the analytic linear term. Pure mean-field linear mass scaling is therefore consistent only aboveAt the boundary dimension logarithms modify the simple power law. Below it this calculation diagnoses the failure of the Gaussian expansion; the exponent obtained by treating the self-consistent one-loop equation as exact is not automatically the exponent of the interacting scalar theory. For , the massless subtraction itself has an infrared divergence, so this perturbative argument cannot establish absence of a transition. In particular it does not rule out the two-dimensional Ising critical point.
The same upper dimension follows by engineering dimension counting: a canonical scalar field has dimension , so . For a tricritical point tune the renormalized quadratic and quartic terms to zero and retain a positive sextic interaction . Its engineering dimension isIt is marginal at , irrelevant above three, and relevant below three. More generally the upper critical dimension of an even scalar interaction is .
A Ginzburg criterion check gives the same result: at tricritical mean-field scaling and , whereas fluctuations in a correlation volume scale as . Their ratio to is , which tends to zero only for . ThusThe tricritical tuning concerns renormalized couplings: shell contractions of a sextic term can regenerate quadratic and quartic terms even when their bare coefficients vanish. At three dimensions the marginal sextic coupling produces logarithmic corrections rather than a strictly fluctuation-free mean-field limit.
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