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The emission coefficient $j_{\nu }$ measures emitted energy per unit volume, time, solid angle and frequency. Its SI units are $\mathrm{W}{\mathrm{m}}^{-3}\mathrm{s}{\mathrm{r}}^{-1}\mathrm{H}{\mathrm{z}}^{-1}$. Along a ray it contributes $j_{\nu }ds$ to specific intensity. For an isotropic spontaneous emission transition with a normalized spectral line profile, $j_{\nu }=h{\nu }_{21}{n}_2{A}_{21}\phi (\nu )/(4\pi )$; integration over solid angle removes the $4\pi$ denominator.

An absorption equivalent width is $W_{\lambda }=\int [1-I_{\lambda }/I_{\lambda }^0]d\lambda$, the wavelength width of a completely black interval that removes the same continuum-normalized area. For a narrow spectral line profile, small optical depth and negligible stimulated emission, the energy-density convention for Einstein coefficients gives $W_{\lambda }=h{B}_{12}{N}_1/{\nu }_{12}$. This follows by replacing $1-e^{-{\tau }_{\nu }}$ by ${\tau }_{\nu }$ and using $|d\lambda /d\nu |=c/{\nu }^2$. At redshift $z$, the observed and rest-frame values satisfy $W_{\mathrm{obs}}=(1+z)W_{\mathrm{rest}}$.

Use the Einstein coefficients convention in which $B_{ij}$ multiplies spectral radiation energy density $u_{\nu }$, with $u_{\nu }=c^{-1}\int I_{\nu }d\Omega$. A normalized spectral line profile obeys $\int \phi (\nu )d\nu =1$. The spontaneous emission probability per upper-state atom per unit time is $A_{21}$; the stimulated emission and upward absorption rates per atom are respectively $B_{21}\int u_{\nu }\phi (\nu )d\nu$ and $B_{12}\int u_{\nu }\phi (\nu )d\nu$.

For isotropic spontaneous emission, $n_2{A}_{21}$ transitions occur per unit volume and time, each supplying photon energy $h{\nu }_{12}$. Dividing among $4\pi$ steradians givesFor a small incident beam, its contribution to $u_{\nu }$ is $I_{\nu }d\Omega /c$. Absorption removes and stimulated emission adds photons in the incident direction. Matching the net loss to ${\alpha }_{\nu }{I}_{\nu }d\Omega$ therefore givesReplacing ${\nu }_{12}$ by $\nu$ across the narrow spectral line profile gives the printed expressions. The negative sign is essential: an inverted population can amplify the incident specific intensity. Thermal equilibrium and the Planck function imply $g_1{B}_{12}=g_2{B}_{21}$ and $A_{21}/B_{21}=8\pi h{\nu }_{12}^3/c^3$, where $g_i$ is the state degeneracy. A convention using mean intensity instead changes both $B$ coefficients by $4\pi /c$.

Specify the radiation normalization first. Let $u_{\nu }$ be radiation energy density per ordinary frequency, with SI units $\mathrm{J}{\mathrm{m}}^{-3}\mathrm{H}{\mathrm{z}}^{-1}$. Then $A_{21}$ is the spontaneous emission rate per upper-state chemical atom, while $B_{12}{u}_{\nu }$ and $B_{21}{u}_{\nu }$ are the induced absorption and stimulated emission rates, evaluated at a sharp transition frequency. For a finite spectral line profile, replace $u_{\nu }$ by its profile-weighted average.

The Einstein coefficients obeyHere $g_i$ are the statistical weights of the two energy levels, and the field is unpolarized and isotropic. The units and physical dimensions areThe apparently time-independent dimension of $B$ follows because a per-hertz density includes an extra unit of time. If instead $B$ multiplies the mean intensity $J_{\nu }$, use $B^{(J)}=(4\pi /c)B$ and $A/B^{(J)}=2h{\nu }_0^3/c^2$. These distinct normalizations must not be mixed in the radiative transfer equation.

Use the energy-density convention of part (a), a normalized common spectral line profile $\int \varphi (\nu )d\nu =1$, and isotropic spontaneous emission. For a narrow spectral line centered at ${\nu }_0$,The factor $1/c$ follows from $u_{\nu }=4\pi J_{\nu }/c$: angle-integrated absorption removes $c{\kappa }_{\nu }{u}_{\nu }$ of energy per volume and time. The emission coefficient is per solid angle, whereas the absorption coefficient has units of inverse length.

The Boltzmann distribution in thermal equilibrium gives $n_2/n_1=(g_2/g_1)e^{-h{\nu }_0/(k_{B}T)}$. Dividing the two expressions and using the relations between Einstein coefficients,Thus the source function equals the Planck function at the transition frequency, and in the usual narrow-line approximationWith an exactly common finite-width $\varphi$ and constant line-center Einstein coefficients, their ratio is constant across the profile; exact equality to a varying $B_{\nu }$ at every frequency is only a narrow-line approximation. Exact thermal radiative transfer requires frequency-resolved detailed balance, which supplies the corresponding small profile corrections. This distinction does not alter the intended equilibrium result.

Let $m$ be the absorber mass path along a ray. If the spectral line profile is independent of position, Beer-Lambert law gives ${\mathfrak{T}}_{\nu }(m)=e^{-m{\kappa }_{\nu }}$. A finite-band mean and the line's equivalent width are respectivelyWhen the band contains all significant absorption, ${\int }_{\mathcal{B}}{\mathfrak{T}}_{\nu }d\nu \simeq \Delta {\nu }_{\mathcal{B}}-E$. An unqualified integral of transmission over the entire infinite line domain diverges because transmission tends to one far from line centre; $E$ is the finite and physically useful line deficit.

This is nonexponential band transmission: each monochromatic transmission is exponential, but their average generally is not. Differentiating with respect to mass path givesMore decisively, define the absorption coefficient averaged over the transmitted spectrum byThen $\boxed{a_{\mathrm{eff}}^{\prime }(m)=-{\mathrm{Var}}_m(\kappa )\le 0}$. The core saturates first and the surviving radiation increasingly samples weakly absorbing wings. The effective attenuation per additional mass therefore decreases. Jensen's inequality also gives $\overline{\mathfrak{T}}\ge e^{-m⟨\kappa ⟩}$, with equality for a spectrally constant coefficient. Thus the band transmission decays more slowly than the exponential with its initial mean attenuation.

The corresponding curve of growth has $E(m)\simeq mS$ for an optically weak line, and sublinear growth after saturation. For the Gaussian profile, with ${\tau }_0=mS/(\sqrt{\pi }{\Delta }_D)\gg 1$, absorption extends to $|\delta \nu |\simeq {\Delta }_D\sqrt{\log {\tau }_0}$, so $E\sim 2{\Delta }_D\sqrt{\log {\tau }_0}$. For a strongly saturated pure Lorentz profile the wings instead give $E\sim 2\sqrt{mS{\Delta }_L}$. These asymptotes apply while the line remains isolated and its important wings remain within the range where the assumed profile and nearly constant Planck function are appropriate. The integrated absorption is not an exponential either: $E^{\prime }>0$ and $E^{\prime \prime }\le 0$.

Take a weak line in the radiative sense: the integrated slant optical depth is small wherever absorption materially contributes, not merely a small greenhouse-gas mass mixing ratio. Normalize every local spectral line profile so that $\int {\kappa }_{\nu }(p)d\nu =S$, with the line strength independent of pressure and, as stipulated, temperature. Keep a finite Doppler or natural core, or a Voigt profile, so that a pressure-only zero-width core at the top does not invalidate a uniform optical-depth expansion. The line must also be narrow enough to use $B_{{\nu }_0}$ across it.

To first order,Thus the detailed normalized line shape drops out, even if its width varies with pressure. Substituting in the deficit in c givesThe neglected term is second order when the relevant squared optical depths are integrable and uniformly small. A very narrow saturated line need not be weak simply because $q\ll 1$. More generally the displayed first-order integrated limit follows from the finite integrated opacity even if an idealized line centre makes a pointwise expansion nonuniform; a finite physical core is the straightforward sufficient assumption.

For an explicitly perturbative temperature estimate, evaluate the bracket at $T_{\mathrm{bare}}$:At fixed $p_s,g,q,S$ and radiative conditions, increasing $\kappa =R_b/c_{p,b}$ makes every level $0<r<1$ cooler relative to the surface, enlarging the bracket and the warming. Increasing $c_{p,b}$ at fixed $R_b$ has the opposite effect. The limit $\kappa \to 0$ is isothermal and gives zero line-induced deficit. A change of background molecular mass alone need not change this leading result: for ideal gases with the same active degrees of freedom, $R_b$ and $c_{p,b}$ scale together and their ratio is unchanged. Comparing only the height-coordinate lapse rate $g/c_{p,b}$ would miss that the absorber column is naturally a pressure-coordinate quantity.

A useful plot must keep three different times separate: source emission $t_e$, atomic absorption or re-emission $t$, and return reception $t_R$. For the cloud centroid,Let $q=f_0/f<1$. Resonant excitation requires $q{D}_{\mathrm{in}}(t)=1$. Since $D_{\mathrm{in}}$ decreases from $\gamma (1+\beta )$ to $\gamma (1-\beta )$, its zero-width resonance first becomes possible atAt equality the line centre is reached only at infinite approach distance, where illumination vanishes. A finite source start time further limits how closely that ideal threshold is approached. For $\beta >{\beta }_{\min }$ the line-centre event satisfiesThere is a second useful critical speed,for which excitation is centred on closest approach, $t_{\ast }=0$. For ${\beta }_{\min }<\beta <{\beta }_{\perp }$ it occurs on approach; for $\beta >{\beta }_{\perp }$ it occurs after closest approach. Even a receding ultra-relativistic atom can see the incident light blueshifted because $\gamma$ is large.

A photon emitted toward the origin near the atomic rest-frame frequency $f$ has return Doppler factorThe sign differs from that in $D_{\mathrm{in}}$ because the returning ray travels in the opposite direction. The returning line centre decreases from $\gamma (1+\beta )f$ on early approach to $\gamma (1-\beta )f$ on late recession, and is $f/\gamma$ at closest-approach emission. The origin receives that closest-approach radiation at $t_R=L/c$, not at zero. Prompt re-emission at exact resonance would giveIt is above $f_0$ below ${\beta }_{\perp }$, equal at ${\beta }_{\perp }$, and below $f_0$ above it. A finite fluorescence lifetime shifts emission later along the orbit and therefore usually toward a lower return frequency.

The following plots adopt a compact, optically thin cloud, weak excitation, isotropic incoherent spontaneous emission in the atomic rest frame, and negligible velocity dispersion. They show an intensity envelope as the observable amplitude; its rms electric-field amplitude is proportional to the square root of this intensity. An incoherent fluorescence signal has no fixed optical phase. The four rows include a nonrelativistic speed, both critical speeds, and an ultra-relativistic speed. All rows share one intensity normalization, so off-resonant signals remain visibly weak.

A model for fluorescence from a uniformly moving cloud generating the plotted envelopes iswhere $\mathcal{L}(\Delta )=[1+4{\Delta }^2/{\Gamma }^2{]}^{-1}$ is a Lorentz line shape of full width $\Gamma$. The factor $1-\beta s$ is the incident photon-flux correction per source-frame time. The population is an exponential memory of earlier absorption events, not an instantaneous resonance indicator. For a detector of fixed small area at the origin, its received bolometric intensity scales asTwo powers of $D_{\mathrm{out}}$ come from aberration of light, one from photon energy, and one from arrival-rate compression. Finite lifetime is dilated to $\gamma \tau$ in the source frame; over an interval with slowly changing geometry its observed decay time is $\tau /D_{\mathrm{out}}$. Thus approach can compress and amplify a pulse, while recession stretches and redshifts it. Illumination and collection each supply an inverse-square geometric factor in the prompt weak-excitation limit. Strong forward beaming can even make a detuned approaching precursor brighter than the later line-centre feature, as in the ultra-relativistic row; the intensity maximum need not occur at exact resonance.

Absolute amplitude and a unique detailed spectral line profile cannot be inferred from $f,\tau ,v$ alone: cloud size, atom number, source power, optical depth, angular emission pattern and saturation were not specified. Finite cloud size convolves these point-centroid curves with additional delays. The plots describe incoherent, frequency-redistributed emission near $f$; a coherent Rayleigh scattering component would instead retain the driving frequency in the atom frame and add a different spectral component. These qualifications do not change the kinematic resonance thresholds or return-time relations.

A normalized spectral line profile distributes a transition's emission or absorption over frequency, with $\int \phi (\nu )d\nu =1$ and units $\mathrm{H}{\mathrm{z}}^{-1}$. Thermal motion, finite excited-state lifetime and collisions can give different contributions to the shape. Normalization lets an optically thin integrated line measure the relevant column density without requiring the detailed profile.