Write , and . The requested model neglects density differences and uses the same thermal transport coefficients in the interfacial balances. Let and . With no imposed heat gradient in the fresh liquid, its temperature remains . The prescribed linear temperature in the ice is
The salt and temperature fields in the lower liquid satisfy diffusion equations, and . For constant interfacial values and the proposed similarity solution, their decaying solutions are
These follow by substituting a variable into the diffusion equation, which gives ; integrating gives the complementary error function. Their values at and at infinity give the required boundary data.
For the upward-moving fresh-water/ice boundary, the Stefan condition is : negative means fresh water freezes. At the lower boundary the signed heat balance is
Salt cannot enter the pure ice. With no bulk liquid motion its interfacial conservation law is
The derivatives and interface velocities are
Define . Substitution into all three balances gives
Together with , these determine the interfacial constants. In particular .
The physical branch has . Since is negative at negative arguments, the salt relation gives : lower-surface melting dilutes the brine. Combining the two heat balances eliminates the ice gradient and gives
Thus . The interface is at local liquidus equilibrium with diluted brine, while the undiluted far-field brine remains above its own liquidus. The similarity model describes a layer starting with zero thickness, or the long-time limit when an initial finite thickness no longer sets the dominant scale.
For the small-diffusivity-ratio limit, put and , keeping and the imposed concentrations fixed. Seek and . Then and . The upper heat balance gives
In the lower balance the two terms of order must cancel, giving
Consequently
and . Adding the two temperature differences yields . The negative root is
The resulting lies strictly between zero and . The salt relation therefore determines a finite negative , confirming its scaling. The top interface travels on the thermal scale , whereas the lower melting interface travels on the shorter solutal scale . This is the brine-ice sandwich with disparate diffusion scales; is the latent-to-sensible heat ratio, the reciprocal of the usual sensible-to-latent Stefan number convention.
Figure 1.
Similarity temperature and concentration profiles, local liquidus and ice-brine phase-diagram path
. Details.
The sketches show constant fresh-water temperature, a declining linear ice temperature, and a much broader thermal than solutal boundary layer in the brine. Concentration is zero in freshwater and pure ice, jumps to across the lower interface, and rises to . Accordingly the local liquidus is on the salt-free side, jumps to and falls rapidly to . In the phase diagram, the brine starts on the liquidus at and ends above it at ; the pure ice has concentration zero, and the interface tie-line joins it to the diluted brine.
Physically, the cold saline liquid permits freshwater to freeze above, but salt lowers the liquidus and allows the existing ice to melt into brine below even though that brine is colder than . Dilution raises the lower interfacial freezing temperature. Heat released by upper freezing supplies the lower melting and the conductive loss to the colder deep brine. With , upper freezing exceeds lower melting and the ice layer thickens as .
Use , and , with . Equal reference densities and constant material properties are implicit in these diffusion balances. Put and . The four similarity fields are
Here the same letters on the right denote their far-field values. Substitution into the heat and solute diffusion equations verifies the fields; their interface values and far-field limits verify every boundary condition. The concentration has an equilibrium jump from to , whereas temperature is continuous.
The interfacial conservation laws are
For example,
Since , dividing the two jump conditions by gives, for nonzero ,
where . At , use the undivided flux conditions or the continuous limit, rather than divide by zero. The liquidus relation and the segregation coefficient also give the solidus .
For the thermal expansion, write and use
Keeping the constant terms in these reciprocals is essential for the full first-order answer. The result is
The remainder has this form for bounded ; a looser statement is also valid in the distinguished scaling . Dropping the temperature-difference term while claiming first-order accuracy for fixed would be incorrect.
Solving the solute balance algebraically gives
For fixed positive , , and , with a positive exponentially small correction. For fixed negative , , and
It falls from as to zero as . The outer positive branch is zero. For finite the transition is rounded over ; the exact zero-speed limit is , not an actual concentration discontinuity.
To count speeds, take the leading distinguished thermal balance, set and , and combine with the thermal result:
This is the intended leading approximation when and . The full first-order expression instead replaces by . Thus the printed threshold is asymptotic, not an exact criterion for finite .
For , put . The small-solid-diffusivity melting concentration is , so
The second term decreases strictly from to zero. One can check the strict decrease without guessing its shape. Set , so , , and . Direct differentiation gives
The bracket increases with on . Substituting its lower bound yields a polynomial with constant coefficient and all other coefficients positive. Hence , as claimed.
If , then and increases from zero to infinity. The freezing branch has and is also monotone. Together these give one speed for each imposed sum within the approximation. If , the melting branch initially decreases, has exactly one minimum and then increases to infinity. For sums between that minimum and zero there are two melting speeds plus one freezing speed: three solutions. At the lower fold there are two distinct speeds, one being a double solution. At zero the limiting outer branches join; finite solid diffusivity rounds the join into a nearby fold. Away from the fold values the other sums have one solution. At the threshold itself the initial slope vanishes; it is the transition between these cases.
Figure 1.
Interfacial concentration and the three-speed region in the leading binary-alloy similarity model
. Details.
For , the solution is on the melting branch . Its thermal layers have scale , much larger than the liquid-solute scale . Because the front is retreating, the solid solute layer is thinner still:
This follows by expanding the large-positive-argument complementary error function ratio on the solid side: near , its decay length is . Using simply would miss the retreating-front compression of that layer.
Across this narrow layer, solid concentration drops from almost to , while temperature stays almost . At the interface . Moving slightly into the solid increases its concentration toward , lowering its solidus to , whereas the temperature has barely changed. Since and , . Thus an adjacent region can satisfy : constitutional superheating. Its existence is especially clear when far-field solid is initially stable but heat diffuses across the narrow composition layer.
The phase-diagram path goes from through a broad thermal rise, then nearly horizontally toward across the thin solid diffusion layer. At the interface it traverses the isothermal equilibrium tie line to . On the liquid side concentration falls to zero over the liquid-solute layer, while the remaining thermal adjustment to takes place over the much wider heat layer. The path of the depleted solid approaches the solidus from its superheated side. That region should melt at additional sites or develop a two-phase mushy layer; the original single-boundary similarity construction is then a mathematical branch rather than a physically stable description of the entire sample.
Figure 2.
Melting-branch temperature and solute layers and their trajectory through the alloy phase diagram
. Details.
Take upward from the unperturbed interface in the apparatus frame, with liquid at and pulling velocity . The primary ice contains no salt. We use the dilute, equal-density approximation and neglect fluid motion relative to the mould. The initial salt inventory per unit horizontal area, with a common density factor suppressed, is . Its conservation is essential: the far liquid has zero concentration, so an imposed nonzero far-field composition would describe a different experiment.
The steady advection-diffusion equation is . Decay into the pure water and interfacial salt rejection give
Since , the finite-inventory directional salt rejection solution is
The decay length is . Local liquidus equilibrium gives
Thus the thermal apparatus selects the interface position at this isotherm. The stated speed inequality is precisely , so the interface is warmer than the eutectic temperature, . These are steady values after the initial finite saline layer has rearranged; the final exponential distribution is not confined to the original depth .
For , a steady pure-ice front would require an interfacial composition beyond the eutectic composition. That branch is unavailable. During the transient, rejected brine concentrates until it reaches ; secondary salt-bearing crystals can then form and the residual brine freezes as an eutectic system. Salt is incorporated into the product rather than remaining indefinitely in a super-eutectic exponential layer. The detailed pattern can include brine pockets and a nonplanar freezing region; it depends on the thermal history and the morphological stability. The speed inequality alone does not decide that latter stability.
For the stability calculation use an interface displacement and a liquid perturbation . Here is the wavenumber, is the temporal rate and gives spatial decay. The frozen thermal field is . Define , where is solid-liquid surface energy, is absolute pure-solvent melting temperature, is mass density and is specific latent heat. For a solid protrusion into liquid the curvature is , and the Gibbs-Thomson effect gives local equilibrium . We assume isotropic surface energy and instantaneous interface kinetics, so no kinetic undercooling term is present.
Linearizing the equilibrium condition at the displaced interface gives
The perturbation advection-diffusion equation gives
The local solute balance at a moving graph, to first order, is
Its perturbation is , because the terms and cancel. Consequently the full frozen-temperature solutal interface dispersion is
No quasistatic approximation to solute diffusion was made here. For a growing mode the unique admissible liquid root is
Writing and eliminating gives . The root continuously connected to the growing interface branch is therefore
In particular, unstable wavelengths exist exactly when , and their band is
This is the constitutional supercooling criterion: immediately above the plane, the local liquidus rises at rate , so it overtakes the imposed thermal gradient when that rate exceeds . The Gibbs-Thomson effect cuts off short waves. At long wavelength for positive . The exactly uniform inventory-changing displacement is not an instability of a fixed-inventory experiment. On stable branches the full diffusion problem also admits relaxation transients; the root selection above is sufficient to identify every exponentially growing interface mode.
If one additionally neglects the perturbation time derivative in the liquid diffusion equation, the alternative reduced rate is
It has the same onset and cutoff, but need not have the same rate away from the slow-growth regime. The frozen-temperature approximation by itself does not justify this extra reduction.
After onset, protrusions reach more weakly saline liquid and advance faster, while grooves accumulate rejected brine. The planar interface develops cells and, as growth becomes sufficiently strong, crystal dendrites with concentrated liquid between them. Nonlinear competition changes the selected spacing; linear rates alone cannot fix the final geometry. The interdendritic liquid forms a mushy layer, concentrates toward the eutectic composition, and ultimately freezes into a salt-bearing eutectic product when it reaches . This replaces the pure planar salt-rejection picture with trapping and freezing of brine between crystals.
Work in the frame of the steadily advancing mush, so the rigid primary-crystal skeleton moves with . Let be solid fraction, the pore-liquid concentration, the Darcy flux relative to that skeleton, and the common thermal conductivity. Set , the thermal diffusivity. The actual pore velocity is . Primary crystals are taken to exclude solute; the residual pore liquid freezes into a two-solid eutectic product at the bottom. These are the standard binary mushy layer assumptions implicit in using a single liquidus and an eutectic floor.
It is convenient to use hydraulic pressure , absorbing the constant-density gravitational term. With equal phase properties, no solute diffusion, negligible fluid inertia and local liquidus equilibrium, a complete mush model is
The last equation follows from conservation of energy with mixture specific enthalpy . Sensible heat is transported by the total volume flux ; the primary solid carries the latent-enthalpy flux . In particular the sign of the latent-heat term is fixed by the downward-moving skeleton.
At the liquid roof, impose
Here . The gradient condition matches heat flux into the imposed liquid field, since there is no phase-fraction jump at this roof and the phase conductivities are equal. The pore velocity there equals the relative Darcy velocity. At the floor,
There is no liquid penetration into fully solid material. The unspecified solid fraction at the floor is determined by the solute balance, not set to one: remaining eutectic liquid freezes as it crosses the floor. If denotes the bulk concentration of the final solid product, the floor solute balance and Stefan condition are
Maintaining the floor at permits the solid-side bath to remove this final latent heat. Equivalently its required gradient is . No additional imposed solid-side gradient is specified. Laterally we take the quadratic-pressure strain solution, without sidewalls; finite sidewalls would require additional flow conditions and generally break this horizontal invariance.
For uniform permeability of a porous medium, incompressible flow gives . The roof pressure and zero normal flow at the floor are satisfied by
Horizontal outflow is balanced by downward inflow. The parameter is an inverse time; in the printed pressure condition already has dimensions of pressure divided by length squared, so no extra density factor belongs in this definition.
With , and , the -dependence disappears from both scalar balances. Although is nonzero, its horizontal divergence cancels in . The exact strain-driven steady mush equations become
Together with , , and , they determine the scalar fields and the unknown thickness. This reduction proves that the equations admit horizontally invariant scalar solutions despite the imposed straining flow. An equivalent useful form, obtained by differentiating the solute equation, is
This exact form also shows why one must not silently discard latent heat in an arbitrary strong-flow calculation.
Define , and . For the stated regular ordering , strain transport dominates skeleton transport and the bounded phase-change enthalpy contribution. More precisely, at fixed finite thermal strain number , the dimensionless energy equation is
so its skeleton and integrated latent-heat corrections are small in and respectively. The leading strain-dominated mush temperature profile obeys . Put and . Integrating first for and then for gives
The error function profile follows from integrating a Gaussian, with . Matching the roof gradient gives the requested transcendental thickness relation
For prescribed and the right side decreases continuously from infinity to zero as increases, so it fixes one positive leading-order thickness. The resulting must still satisfy the assumed ordering and the phase-fraction constraints.
To find the product composition, integrate the exact solute balance from the roof to an arbitrary depth. With ,
At , the exact floor composition is therefore
The minus sign has a direct physical meaning: the horizontal outflow removes more salt than arrives at the same depth from a uniform- liquid, leaving a depleted solid product. Using the leading error function profile and
yields
The full solid fraction follows by substituting this same profile into the preceding integral formula for . It has and . A physical branch requires and . In this monotone profile, ensures a nonnegative liquid fraction everywhere; it is not permissible to interpret a negative formal result as a material composition.
The error-function reduction is a regular leading approximation, not a uniform statement for every possible scaling of the thermal strain number. If becomes singularly large along the ordering limit, a thin basal layer can amplify the discarded terms. The printed two inequalities alone do not specify that extra scaling. In such a regime the displayed exact scalar equations and boundary conditions, rather than an unqualified zero-latent-heat profile, provide the appropriate thickness and composition calculation.
Use a one-sided top-hat plume model with Boussinesq approximation and neglect the solid/liquid density difference in the interfacial volume source. Define the positive ablation speed , volume flux per unit wall span , and kinematic momentum flux . Let ambient entrainment per height be , with entrainment coefficient , and take for the salinity contribution to density. Conservation of volume and vertical momentum, with negligible wall stress and negligible vertical momentum of entering fluid, gives
Only the ocean-facing edge entrains. Using two edges would change the entrainment coefficient in these formulas.
To derive the heat balance, choose liquid specific enthalpy and solid specific enthalpy . A horizontal slab receives ambient volume with enthalpy , and solid mass-equivalent volume with enthalpy . Thus
Subtract and divide by :
Similarly, the incoming salt flux is , so . Subtracting proves
Both anomalies are negative for fresh, cold melt entering the ocean. These balances account for the heat needed to melt the entering ice, rather than treating it as already-liquid water at .
Now use , the large latent-to-sensible heat ratio convention of the paper. Put . The stated small plume-deficit limits allow us to replace plume by their ambient values in the diffusive interfacial fluxes. The Stefan condition and interfacial salt balance are then
For the compositional Péclet number , solve the second equation and impose the liquidus:
Substitution in the heat balance gives the diffusive glacier-ablation interface law
Here is the liquidus slope, unrelated to the surface-energy parameter of the previous question. If , and , the physical root is
It is positive when , exactly the condition that the ocean is warmer than its own liquidus. Since and ambient properties are fixed, is constant with height in this approximation.
For the melting-driven saline wall plume, measure height from a virtual origin. The integrated anomaly balances are
In the specified small-deficit regime the meltwater volume is negligible compared with entrainment. Indeed, the solution below gives , so a small compositional plume deficit implies . Thus retain for the leading power laws, although remains essential in the salt and heat sources. Try , . The salt deficit is proportional to , and the momentum balance has powers , hence . The volume balance gives , and the momentum coefficient gives . Therefore
These are entrainment-dominated power laws, not an exact solution with the term retained in the volume equation. They fail close to the virtual origin, where the formal temperature and salinity deficits diverge. Their buoyancy source is distributed melting along the wall, unlike a line plume with a constant buoyancy flux from a localized source.
Figure 1.
Temperature and salinity from the ice interface through the wall layer and plume
. Details.
The profiles rise from across the laminar boundary layer to the almost-ambient plume values , then approach across the entraining edge. The sketch uses the linear-gradient approximation implicit in the prescribed diffusive fluxes; it is not an exact normal advection–diffusion profile at large .
For ,
The last formula retains both first-order terms and is appropriate near the no-ablation threshold. Salt diffusion keeps the interface saline, and freezing-point depression allows ice dissolution in saline water even when . Latent heat is still needed, but the thermodynamic permission to ablate comes from the depressed liquidus; small does not mean a negligible energy cost.
For , and . Rapid production of fresh melt dilutes the interface, so its temperature approaches the pure-ice melting point. In the usual thermally driven regime and ,
This is predominantly thermal melting. More generally the retained large- balance is . For example, gives , which can be large while the driving term is still saline freezing-point depression. Thus the melting/dissolution interpretation must also consider the ocean's temperature relative to , not the compositional Péclet number alone.
Take and , with the liquidus referenced to the pure-water melting point. The solid-liquid segregation coefficient means that newly formed ice contains no salt. A steady sharp front producing only pure ice cannot remove the incoming solute flux. More explicitly, in the liquid the steady solute flux is , whereas in pure solid it is zero. Interfacial salt conservation would require , a contradiction. An equilibrium mushy layer avoids this by carrying concentrated pore liquid down to the eutectic region, where a salt-bearing solid assemblage can form.
Use equal densities and common downward translation velocity . Write for the liquid fraction; here is the solid fraction. Local liquidus equilibrium in the mush requires
Above a stationary roof , the liquid advection-diffusion equation is , with solution
The marginal equilibrium at a mush-liquid boundary condition is , hence . Matching the temperature and liquidus at the roof gives
A positive equilibrium mush requires ; otherwise this positive-thickness construction does not apply.
Including solute diffusion in the liquid pore space, the steady solute flux in the mush is
Thus . Inserting and the value of yields
This is the diffusive steadily pulled equilibrium mush. Omitting the diffusive contribution would give a different solid-fraction distribution.
The imposed temperature and local liquidus coincide throughout the mush. In the liquid put . Their difference is
with equality and matching first derivatives at the roof. The inequality follows because the derivative of is . Thus the liquid is not constitutionally supercooled. In the phase diagram, the pore-liquid trajectory follows the liquidus from the eutectic composition to , then curves into the liquid region and approaches as height increases. Pure-ice crystals have composition zero; the trajectory denotes the liquid composition, not the bulk mush composition.
Figure 1.
Steady pulled mush: thermal fields and liquid-composition trajectory
. Details.
After pulling stops, the imposed temperature keeps the pore-liquid composition fixed wherever the material remains mush. Solute conservation becomes
Because , this reduces to
The method of characteristics uses and . Hence
These are the solute-diffusion characteristics in a fixed-temperature mush; their validity is local to the coexisting solid–liquid region.
For an explicit initial-data solution, define , and , so . A characteristic through has initial foot
While that foot lies in the original mush and no phase boundary has removed the point,
This recovers the initial distribution and shows that interior ice fraction increases as salt diffuses upward from colder, more concentrated pore liquid.
If one simply transports the initial zero-solid-fraction level, implies the printed formal law
On the physical concentration branch , this is , so . It starts moving above immediately.
This formal continuation cannot be the physical mush–liquid roof of a column sealed to salt by the membrane. The no-flux constraint in a fixed-temperature mush is at the membrane. At a smooth zero-fraction equilibrium roof, however, and , giving . Moreover the formal roof has left the membrane-bounded domain. The printed interface law is incompatible with a salt-impermeable membrane when interpreted as the physical roof. Its derivation above is a characteristic extrapolation; it does not enforce the stated boundary condition. If “impermeable” were intended to block bulk flow but allow salt diffusion, a different boundary condition would need to be specified.
The closed-column physical sketch is consequently different. Salt transported upward accumulates below the membrane and produces a liquid brine cap; the cap composition need not lie on the liquidus at every height. Its lower boundary can have a finite jump in solid fraction, so it need not follow the initial zero-fraction characteristic. Near the cold solid base, zero salt supply from below requires the liquid fraction to vanish, and a pure-ice region develops. In the surviving mush, the characteristic formula increases relative to its initial value. An intermediate profile therefore has pure ice at the bottom, a remaining mush with elevated solid fraction, and liquid at the top. The plotted intermediate roof is schematic, not claimed to obey the inconsistent formal law.
Figure 2.
Initial, intermediate and final solid fractions in a salt-sealed column
. Details.
One can characterize the final state quantitatively if the solid base also admits no salt diffusion, as in the usual pure-solid/no-solid-diffusion closure. In a stationary column, solute flux is constant and is zero at the sealed roof. A finite-width equilibrium mush would have , forcing everywhere in that region; it therefore cannot remain mush. The final state is pure ice for and a uniform-composition liquid cap for . At their boundary,
The cap is liquid because above its base. The fixed external thermal field can supply or remove the heat involved; this is a solute-budget determination rather than an isolated enthalpy budget.
The final salt budget of a sealed mush column determines . Initially
since . Conservation requires . Writing the final cap depth , the equation and its unique positive root are
The initial salt integral is less than , so and ; the resulting remains on the ice–brine branch above the eutectic. If the basal eutectic region is instead allowed to exchange solute with the column, this salt budget must include that flux and the numerical final height is not fixed by the printed data alone. No universal physical follows from the interior characteristic equation without the cap and basal boundary conditions.
Use a planar saline Stefan problem with upward coordinate , the initial contact at , and phase boundaries and enclosing pure ice, where . Fresh liquid occupies and brine occupies . We assume negligible bulk flow, equal constant mass density , specific heat capacity and thermal diffusivity in all regions, and zero salt content and salt transport in the ice. Equal densities remove phase-change volume flow; suppressing convection isolates the molecular-transport mechanism. Different material properties would change the numerical coefficients. Set for the common thermal conductivity and . Denote the brine salt diffusion coefficient by .
Use a linear ice liquidus, , with and the salt mass fraction. Assume the initial brine is a stable liquid, , and all concentrations considered are below the eutectic composition. Thus . These assumptions exclude independent nucleation in a supercooled brine or an eutectic system event, neither of which is specified by the initial data alone. Start with a negligible seed of ice and use local phase equilibrium without interfacial kinetics or curvature. Temperature differences may be in Celsius, since only differences enter this calculation.
Write
The paper calls a Stefan number; it is the latent-to-sensible heat ratio, reciprocal to another common Stefan number convention. At the lower phase boundary, define and let
The liquidus relation is .
A similarity solution gives an explicit calculation of the two positions. Put
and use , . The temperatures and salinities are
These error function and complementary error function profiles satisfy the heat equation and the salt diffusion equation, their far-field conditions, and the interfacial temperature conditions. The fresh-water temperature is constant because the interface and the far field are both at .
Salt conservation at the moving lower phase boundary requires
For upward motion this is dilution by melting salt-free ice, rather than salt rejection by freezing brine. Substitution gives the dilution function for a melting saline Stefan front:
For , , so the interfacial brine is fresher than the remote liquid.
The Stefan condition at the upper boundary is , since the fresh liquid has no temperature gradient. At the lower boundary it is
These signs follow from the jump in enthalpy: the upper front freezes liquid while a positive melts solid. With , they reduce to
Together with , these equations determine , and hence both positions, without discarding the salt-diffusion correction.
For the stated large latent-to-sensible heat ratio, the layer is thin relative to the thermal diffusion length. Expanding the thermal equations for gives
Consequently a useful leading calculation is
where the positive is obtained from
The left side decreases with while the right side increases, and their values at zero and infinity guarantee a unique positive root for large . Thus this leading calculation includes the translation of the lower boundary as well as the increasing thickness.
If the scale separation also obeys , the familiar simpler result is
with
This last simplification needs the logarithmic refinement . The algebraic ordering alone should not be used to discard an arbitrarily large logarithmic correction; the preceding coupled equations remain the appropriate calculation when that refinement is unavailable. This distinction is captured by large latent heat in a freezing and melting ice layer.
Figure 1.
Fresh-water freezing and basal ice melting with the temperature and salinity profiles on their distinct diffusion scales
. Details.
The illustration uses , and . Solving the full equations gives , and . It shows the ice layer between freshwater and cold brine, with both fronts advancing upward and a strongly diluted lower liquid boundary.
Figure 2.
Temperature-salinity trajectory from cold bulk brine to the ice liquidus and through salt-free ice to fresh water
. Details.
The phase diagram shows the spatial path from remote brine to the lower interface: temperature first changes over at almost unchanged salinity, then salinity changes over its much smaller diffusion scale at nearly constant temperature. The liquid path ends on the liquidus at ; the solid has and its temperature rises from to . The eutectic position is schematic, with in the illustration, and is not used in the calculation. A point initially in the fresh layer freezes when reaches it, cools in the ice, and later melts when reaches it. The inset indicates this temporal path in the opposite direction through the solid branch and into the liquid.
The mechanism is simultaneous upper freezing and lower melting, with net growth of the ice thickness. Cold brine accepts most of the latent heat released by upper freezing. Salt reaching the lower contact lowers its equilibrium melting temperature, and melting freshens that liquid until its liquidus is close to . The heat delivered through the ice supplies the much smaller melting demand there. The remote brine remains liquid even though it is below the pure-water melting temperature, because it lies above its own saline liquidus. Thus “cold” does not by itself decide which phase is stable. These conclusions apply while the layers remain effectively deep and the stated no-convection, pure-ice and phase-equilibrium assumptions hold.
Take positive downwards from the roof. Write , , and . The cooled magma follows the decreasing liquidus from towards ; the initially superheated liquid starts at above that liquidus. The solid has zero solute concentration. At each temperature in the mushy layer, a horizontal tie line joins the pure solid to the residual liquid on the liquidus. The lever rule gives the liquid fraction from the bulk concentration. Since , this path stops before the eutectic temperature and does not cross the eutectic composition.
Figure 1.
Liquid cooling, residual-liquid enrichment and a solid–liquid tie line in the stagnant magma mush
. Details.
The porosity denotes the liquid fraction, so is the solid fraction. Equal phase mass densities remove volume-change flow; the stable density stratification suppresses convection. In the stagnant mushy-layer model, define bulk specific enthalpy and bulk solute concentration by
The arbitrary reference of specific enthalpy has been omitted. The two conservation laws in are
Here is the thermal diffusivity, with the thermal conductivity. The positive term records increased specific enthalpy on melting; during freezing it supplies latent heat. In the liquid , the heat equation and solute diffusion equation are
where is the solutal diffusivity. Neglecting solute diffusion inside the mushy layer does not permit dropping in the liquid at this stage.
Use , liquid and as , and initially , , for . These are the half-space boundary conditions appropriate before cooling reaches the bottom of the chamber. For a closed chamber of finite depth , replace the far-field conditions by the specified bottom conditions, for example at an insulated impermeable floor; the half-space similarity solution then ceases to apply when the thermal penetration depth approaches .
At , let and be the common liquid concentration and temperature, and let be the limiting porosity on the mush side. Continuity of , the Rankine-Hugoniot condition for solute, and the interfacial conservation of energy give
The first condition has the sign of solute rejection into the liquid. For the sharp-edge stagnant mushy-layer model with nonzero liquid solutal diffusivity, close the free-boundary problem by marginal equilibrium at a mush-liquid boundary:
This prevents constitutional supercooling immediately ahead of the mushy layer. A small solid fraction jump at its edge is allowed: imposing as well as these finite- conditions would generally overdetermine the reduced model. At the roof, follows from the liquidus, and no additional solute-flux boundary condition is needed in the diffusion-free mush.
To obtain the large-concentration similarity solution, put
The positive superheat specifies the physically intended liquid initial state. On a similarity solution, are constant, so every newly incorporated level leaves the same constant . Write and . Then throughout the mushy layer
For , , and , the effective heat capacity is constant to relative error . Thus set
Integration of the similarity solution ordinary differential equation gives the leading analytical profiles
The temperature is . In the mushy layer, the concentration and porosity are the displayed ; in the liquid,
These retain the liquid solutal boundary layer. For completeness, finite- values of are determined analytically, to the same large- order, by setting
and solving
The solute jump gives exactly; replacing by on the right of the last equation retains that jump's next-order factor, but does not make the linearized thermal profiles exact at finite . The branch has , . All these profiles are leading asymptotic expressions, not exact solutions of the nonlinear finite- heat equation.
For at fixed positive , the complementary error function asymptotic gives , hence , , , and . The result simplifies to
In particular, and . There is no finite interfacial latent heat jump in this limit: the latent heat is released continuously throughout the mushy layer. Matching the two temperature gradients gives
The printed final equation is missing the square on in the exponential. The corrected exponent follows directly from differentiating and is consistent with . The positive root is unique: the mush-side gradient decreases from infinity to zero with , whereas increases. The zero-superheat limit is singular and is not described by a finite positive in this two-region construction.