A chi-squared test compares residuals with the random scatter predicted by a model. For independent measurements with known Gaussian standard deviations and predictions , form
If the mean model and error assumptions are correct, a full-rank linear fit of parameters gives a chi-squared distribution with statistical degrees of freedom. With a fully specified prediction and no fitted parameters, . Nonlinear fits usually make this an approximation. Independent external calibration is not the same as fitting a parameter to these test data.
Under the reference distribution, the mean statistic is and its variance is . The upper-tail p-value quantifies how unusual a discrepancy at least this large would be under the assumed model. A small value suggests model failure or incorrect uncertainties; it is not the probability that the model is true. An unusually small statistic can also reveal inflated uncertainties or correlations. A rejection threshold should be specified in advance.
For independent Poisson distribution counts, the model variance is its expected count . The Pearson chi-squared statistic is . The estimated-error alternative is common for large counts but can differ substantially when counts are small. In that regime the Poisson deviance or a direct likelihood calculation is preferable, with simulation if an accurately calibrated goodness-of-fit probability is required.
An exponential count rate appears as a straight line on a semilogarithmic plot:
The early points decrease by roughly a factor per added sheet. Keeping the supplied fixed, a simple unweighted straight-line estimate from the first four logarithms is
so the early trend is consistent with near one. This logarithmic estimate is illustrative; the final statistical comparison should use the count uncertainties rather than treating the logarithms as equally precise.
Figure 1.
Attenuation data: early exponential behavior and a late background contribution
. Details.
The pure exponential gives a useful approximate description through about the first four or five sheets. The first four observations are the clean high-count range; the fifth remains compatible with within its counting scatter. At the measurements are roughly constant at a few counts per second, so a single straight line no longer describes the whole pattern. Agreement of the sixth point with one exponential prediction by itself does not remove the systematic late flattening. There is no sharply determined physical cutoff from eight noisy measurements; the range used for a formal test should be stated explicitly.
Assume independent radioactive detections with negligible dead-time loss, so accumulated counts have a Poisson distribution. The reference measurement has total count over . Since a Poisson count has variance equal to its mean, the rate uncertainty is
Its relative uncertainty is , or . For each one-second measurement, , giving the estimated count and rate uncertainties
in counts, numerically the same in counts per second for these one-second exposures. Their fractional uncertainties range from about at the first sheet to – for the smallest counts. The long, high-rate reference is therefore much more precise. These are statistical errors; a longer exposure does not automatically remove calibration errors, source drift or background bias.
For a candidate attenuation coefficient, the one-second expected count is . The model predictions are
Use first the conservative signal-dominated range , where the count approximation is reliable and background is a small correction. Using the estimated errors from part (c), the weighted residual statistic is
It gives . Since both candidates are fixed and was calibrated independently, neither was fitted to these four counts: the approximate reference has , not three. The upper-tail probabilities are approximately and , respectively. Thus is compatible with the scatter, whereas is disfavored at the usual level in this approximate test.
A Pearson chi-squared statistic, using model variances instead of estimated observed variances, gives the same preference:
Including the fifth point also leaves the decision unchanged: the estimated-error statistics are and on five degrees of freedom, with approximate upper-tail probabilities and ; the Pearson statistics are and . Hence
The small uncertainty in contributes correlated prediction uncertainty, as in chi-squared comparison of a calibrated attenuation model, but is negligible compared with the one-second counting errors here. Choosing the test range after inspecting the observations limits a strict interpretation of its nominal significance; the numerical comparison and its stated range are the relevant evidence.
If all eight observations are inserted into the estimated-error formula, the totals are and . Their nominal eight-degree-of-freedom calibration is unreliable because the final expected counts are much smaller than one for some predictions. In fact the full-range Pearson statistics are and , exposing the late excess much more strongly. The full Poisson deviance values are and , again favoring but signaling that a background-free exponential is inadequate over the complete range. These sparse-count comparisons should not be used to claim that either unmodified model explains all eight measurements.
Introduce an additive background rate , from ambient radiation, detector dark counts or another weakly attenuated contribution. If denotes the unattenuated signal alone, the attenuation count model with an additive background is
It approaches a nonzero constant as the transmitted signal becomes small. The source-off background should ideally be measured in a separate long exposure and its uncertainty included in the fit; otherwise estimate jointly using a Poisson count likelihood.
There is a normalization detail: the given was itself obtained from an count measurement. If that measurement included the same background, then it measures , and the attenuation fit normalized to a total reference rate is
Writing instead treats as a background-subtracted signal calibration. The difference is small here because the background is a few counts per second while is about two thousand, but the distinction prevents double-counting background. The last three observations alone do not give an exact value of , because residual transmitted signal and sizeable counting fluctuations remain.
Bayes' theorem updates prior knowledge using the likelihood of new observations. For alternative hypotheses ,
The prior describes information before the data ; is the sampling likelihood, and the posterior describes the updated probabilities. Posterior odds equal prior odds times the likelihood ratio. A likelihood is a probability model for data at specified parameters, not automatically a normalized probability distribution over those parameters.
For a continuous parameter , the same rule uses densities: . Priors can encode positivity, physical limits, previous independent measurements or calibration knowledge. Their parameterization matters: a density uniform in a rate is not uniform in its logarithm. Proper priors make model evidences well defined; an arbitrary normalization in an improper prior is especially problematic for comparing models.
A counting example uses Poisson-gamma conjugacy. If a detector registers events in exposure with constant rate , . A gamma prior with shape and rate parameter , , gives
The posterior mean combines the prior rate with the observed rate , weighted by the prior and actual exposures. The parameters must use a consistent shape-rate convention. Small counts can leave substantial prior sensitivity; abundant informative data usually reduce it for regular identifiable models.
Independent old data can become the prior for a new experiment, giving the same result as joint updating under a consistent model. The new data must not also have been used to construct that prior, or the evidence is counted twice. A credible interval has a specified posterior probability under the chosen model and prior; this interpretation differs from repeated-sampling coverage of a confidence interval. Predictions for a future observation average its sampling distribution over the posterior, incorporating parameter uncertainty. Prior sensitivity checks and a defensible likelihood are therefore part of the inference, rather than Bayes' theorem itself supplying missing physical knowledge.
A systematic error is a reproducible bias in the measurement model or procedure, such as a zero offset, incorrect gain, background contamination, misalignment, loading or temperature-dependent calibration. Repeating the same biased procedure more often reduces independent random scatter but does not remove the bias. An unknown correction also has a measurement uncertainty, even when the mechanism is systematic.
A simple instrument model is , with gain error , offset , drift and random noise . Comparison with calibrated standards at several input values separates an offset from a scale error and can test nonlinearity. Use standards that cover the operating range, verify units and reference values, and propagate uncertainty in the standards into the corrected result. Calibration changes the model; it does not make the corrected measurement exact.
A blank or source-off measurement estimates additive background. For independent source-plus-background count in time and background count in time , the net-rate estimate and its counting variance are
Subtracting a measured background removes its estimated mean, not its fluctuations or its uncertainty. A long background exposure can reduce the latter, while drifting backgrounds require monitoring or a joint model.
Reversal can distinguish a wanted signal from an unchanged offset. For example, and give when the thermoelectric offset is stable between readings. Interchanging sample and reference, reversing field direction or reversing an apparatus orientation can similarly expose sign-dependent biases, but only if the wanted and unwanted contributions transform differently.
Track slow instrumental drift using frequent references, interleaved readings or an ABBA measurement sequence. Equal-time readings in the order A, B, B, A cancel a common linear drift in the difference estimator . Nonlinear drift or unequal sample conditions can survive. Randomizing run order helps prevent a time drift from imitating dependence on a controlled experimental variable.
Control physical couplings directly: stabilize temperature, minimize gradients, shield unwanted fields, align geometry, and use high input impedance when loading is the concern. Differential and bridge measurements suppress common changes when their channels are well matched. Varying an apparatus parameter or using an independent method can reveal an unsuspected bias. Report residual corrections, their uncertainties and correlations; adding more identical readings cannot justify discarding a shared calibration uncertainty.
Johnson-Nyquist noise is equilibrium electrical fluctuation caused by thermal agitation of charge carriers. A resistor can generate a fluctuating terminal voltage even when its mean current is zero. In the classical frequency range , the Fluctuation-dissipation theorem relates this noise to dissipative resistance. The one-sided voltage power spectral density of an unloaded resistor is
Equivalently its short-circuit current spectrum is . Over a flat bandwidth the rms voltage is . A real measurement instead integrates over positive frequency, with loading and the filter's effective noise bandwidth included. A flat spectrum does not imply an infinite physically measurable variance; the circuit and the quantum high-frequency regime limit the ideal white-noise model.
Cooling or narrowing the accepted bandwidth reduces thermal noise. Reducing resistance lowers its open-circuit voltage noise but raises its short-circuit current noise, so the appropriate choice depends on source impedance and amplifier loading. Thermal agitation is not a fluctuating externally applied voltage that can be removed by perfect shielding alone.
Shot noise arises from discrete transfer events. In the simplest shot noise counting model, equal charges arrive independently at constant rate . A gate of duration contains a Poisson number , with mean and variance . Therefore mean current is , and the averaged-current variance is . The corresponding one-sided low-frequency spectrum is
for a flat accepted bandwidth. Electron current has . Vacuum emission or photodetection can approximate independent arrivals; correlations in a conductor can suppress or enhance the fluctuations. Discreteness by itself does not guarantee Poisson statistics.
For a fixed mean current the ideal shot-noise formula is not proportional to temperature, whereas Johnson noise is. Increasing current raises absolute shot noise but lowers its fractional size, since . Both can appear approximately white within a useful frequency band, and independent noise powers add after referring them to a common measurement point. Their spectra must use the same convention: two-sided densities are half these one-sided values. A real low-current experiment can also contain amplifier noise, low-frequency drift and correlated transfer noise, so a mean current or resistance alone does not specify its complete noise budget.

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