Blume–Capel model Created 2026-09-28 Updated 2026-10-03
The Blume–Capel model is a spin model with and Hamiltonian
Competition between the Ising interaction and the single-ion anisotropy produces a tricritical point in its phase diagram.
A tricritical point is the meeting of a line of continuous phase transitions and a line of first-order phase transitions. In the symmetric scalar Landau free energy, it occurs at with . Two independent controls are needed to tune both coefficients. The continuous transition lies at , and the tricritical three-phase line found above has ; both approach the tricritical point. At zero conjugate field the three coexisting states on this first-order line are the disordered state and the two opposite ordered states.
Setting makes the leading stabilizing interaction sextic. The nonzero minimum obeys , so the order-parameter critical exponent along this tuned direction is . Substitution gives
and two temperature derivatives give the heat-capacity critical exponent . At , the equation of state is , giving the critical-isotherm exponent .
For magnetic susceptibility, differentiating gives . This is above the transition and below, hence . The quadratic fluctuation kernel still has a mass proportional to , giving and . Thus the mean-field tricritical exponent calculation yields
Detuning gives tricritical crossover scaling; one must specify the approach to the tricritical point when quoting these critical exponents. The sextic interaction has upper critical dimension three, so sufficiently strong long-distance fluctuations change these mean-field predictions below three dimensions.
The relevant boundary here is the upper critical dimension: above it the critical interactions become negligible at long distances and the ordinary mean-field critical exponents apply; at it there can be logarithmic corrections. This differs from the lower critical dimension, below which a particular kind of ordering may fail to exist.
Normalize the coefficient of in the Landau-Ginzburg theory. Under a change of length scale , its invariance gives the engineering dimension . The quartic interaction then scales as
It is a relevant operator below four dimensions and an irrelevant operator above four. Thus the ordinary scalar transition has upper critical dimension . At a tricritical point, where the quartic interaction is tuned away, the sextic coupling scales as , giving the tricritical upper critical dimension . This is the upper critical dimension of an even scalar interaction applied to powers four and six.
The Ginzburg criterion makes the reason for failure of the Landau approximation quantitative. In the ordered quartic theory, , and . The fluctuation of the order parameter averaged over a correlation volume has the scale
Compared with the squared mean order parameter, the Ginzburg criterion therefore gives
For this ratio grows without bound as the correlation length diverges. The assumption that fluctuations are small relative to the ordered value fails arbitrarily near the transition, and the interacting renormalization-group fixed point determines the critical exponents. For the ratio tends to zero. At scale counting is marginal, and the running quartic coupling produces logarithms.
Similarly, at the tricritical point , so the multicritical Ginzburg ratio scales as . The Landau-Ginzburg theory remains a useful effective description below its upper critical dimension; it is its fluctuation-free exponent calculation that fails, not the possibility of including fluctuations in the theory.
At the tricritical point, both the quadratic and quartic even coefficients vanish, while the sextic coefficient remains positive. Two even control parameters must therefore be tuned, in addition to setting the symmetry-breaking conjugate field to zero. The continuous phase transition line and first-order phase transition line meet, the coexistence order parameter jump shrinks to zero, and the tricritical wings end there. The balance governing the equation of state changes from quartic to sextic stabilization.
Along the tricritical thermal path , , , minimizing gives on the ordered side. At , the equation of state is . Consequently
These mean-field critical exponents require the tuned tricritical path; a path with fixed instead has the ordinary exponents derived above. The corresponding equilibrium Landau free energy is below the transition. Its first thermal derivative is continuous but its second derivative diverges, giving the tricritical mean-field approximation a heat-capacity exponent . Fluctuations are negligible asymptotically only above the tricritical upper critical dimension three; at three dimensions logarithmic corrections can accompany these powers.
A phase diagram divides a space of control parameters into equilibrium thermodynamic phases, marking phase coexistence boundaries and thermodynamic critical points. Its dimension counts independently variable controls, not spatial dimensions. An explicit three-dimensional example uses the controls of a sextic even Landau potential:
Here is a scalar order parameter, its conjugate field, and a thermal control. The equilibrium magnetization minimizes globally. At , , the boundary is a continuous phase transition. At , , the boundary is a first-order phase transition between and . The two boundaries meet at the tricritical point . A fixed strictly positive quartic coupling alone cannot produce this tricritical point; the stabilizing sextic term is essential when the quartic coefficient is tuned through zero.
The full phase diagram also contains the phase coexistence sheet between positive and negative ordered phases. Crossing it changes the sign of discontinuously. For , the three-phase line is the junction of this sheet and two tricritical wings, on which two unequal same-sign equilibrium magnetizations coexist at nonzero . The tricritical wing critical edges are lines of ordinary thermodynamic critical points; they terminate the first-order sheets and meet at the tricritical point. Away from these boundaries, varying produces a smooth crossover.
For an explicit construction of the tricritical wings, write their two coexisting order parameters as and , with and . Equality of their Landau free energies and first derivatives gives
Indeed, for these controls the tricritical wing coexistence factorization is
The last factor is , proving that both specified minima are global. The reflected wing has negative and negative . Letting gives the tricritical wing critical edge , , ; there and . Letting recovers the three-phase line. This supplies the first-order sheets and their continuous boundary curves, rather than only a zero-field section.
Figure 1.
Zero-field section and three-dimensional coexistence wings of a sextic Landau phase diagram
. Details.
Changing the ultraviolet cutoff changes which fluctuations remain explicit. Integrating out a shell of Fourier modes shifts the coefficients of all symmetry-allowed operators and a field-independent constant. Hence the cutoff-dependent coefficients are chosen so that the remaining partition function and long-distance observables reproduce the same microscopic system. This is the Wilsonian coarse-grained statistical Hamiltonian; retaining only the printed operators is a local derivative expansion, not an exact closure.
In a massive symmetric phase, the quadratic long-wavelength inverse two-point function has the form . Its Landau scalar correlation length satisfies in this approximation. For canonical normalization of a scalar gradient term, set ; then the mass and quartic coefficients become and . With this normalization the infrared mass is the inverse correlation length, , within the massive quadratic or one-loop approximation. More generally the decay rate is a pole mass, whereas the zero-momentum inverse magnetic susceptibility is a curvature mass; an anomalous dimension or nontrivial momentum dependence can distinguish them. In the ordered phase one must first expand about a selected stable equilibrium magnetization, rather than identify a negative quadratic coefficient at the unstable origin with a squared inverse correlation length. Thus the intended mass identification includes a field normalization and a stable-phase qualification.
For momentum-shell renormalization group, split , retaining and eliminating . Define
Taking a logarithm gives the cumulant expansion of a coarse-grained free energy. For a centered fast Gaussian measure with , the first quartic cumulant is
The Wick contractions give a mass shift and an identity-operator contribution, while leaving the quartic term at this order. The second cumulant produces higher interactions and a quartic correction. After the length and field rescalings and , the gradient coefficient remains one, and
The one-loop shell mass renormalization in scalar quartic theory explicitly shows why the critical bare mass is shifted by fluctuations.
Assume short-range interactions, an analytic even local potential, a positive gradient coefficient, and a weak-coupling trajectory in the basin of the Gaussian fixed point. Above four dimensions the quartic interaction has negative engineering dimension and its dimensionless strength decreases under coarse graining; higher local powers and higher derivative terms also decrease. After absorbing analytic short-distance shifts into the coefficients, long-wavelength fluctuations are small compared with the ordered order parameter. The remaining coarse Landau free energy can therefore be evaluated at its stable saddle:
The quartic stabilizer must still be retained for the ordered minimum even though it is dangerously irrelevant. Stationarity, , gives the ordinary Landau-Ginzburg theory and its mean-field critical exponents. This derives the saddle approximation from decreasing fluctuation strength under the stated RG assumptions; it does not assume that every exact coarse-grained functional becomes a quartic polynomial. Below four dimensions the quartic coupling grows, long-wavelength loop corrections cease to be small, and the argument fails. At four dimensions the interaction is marginal and generates logarithmic corrections. The tuned sextic theory has the analogous boundary at three dimensions.
Use a consistent Fourier transform pair for the connected correlation function:
The printed forward-transform expression integrates over while leaving free; that integration variable is an error. The above convention resolves it and produces the loop measure used below. At zero magnetization, ; otherwise the disconnected product of expectations must be subtracted.
In the inverse-propagator identity used here, the truncated two-point function means the full one-particle-irreducible two-point vertex, including its free quadratic part. This convention differs from using “truncated” for a connected cumulant. To derive the inverse relation, introduce , and the effective action . Then and the chain rule gives . Since is the connected correlation function, translation invariance gives .
Now use canonically normalized coefficients, denoting the cutoff mass by and the renormalized infrared mass by . Choose the free propagator and put in the interaction as a quadratic counterterm. With the Euclidean self-energy convention in which an insertion changes the connected propagator by , the perturbative series begins
The self-energy sums one-particle-irreducible loop insertions; the explicit mass counterterm is kept separate. Repeated insertions generate the geometric Dyson resummation, which explains why reducible chains occur in but not as independent terms in its inverse. Beyond one loop a momentum-dependent self-energy and wave-function renormalization must also be included.
At one loop the only quartic two-point graph is the tadpole diagram. At a vertex, attaching the two labeled external fields uses choices and contracts the remaining two fields together. The factor is . Equivalently this is the same quadratic term in the shell cumulant expansion above. Thus
It is positive for and independent of external momentum, so there is no one-loop gradient renormalization. The condition implies , hence
The cutoff is necessary: the unregulated integral is ultraviolet divergent for . Using the renormalized mass internally is a self-consistent one-loop organization, not an exact resummation of all critical fluctuations. With nonunit , this formula instead applies to , after canonical normalization of a scalar gradient term.
To test a linear thermal mass, approach the ordinary transition from the symmetric side and set . For the massless tadpole is infrared finite. Subtract its critical value, absorb regular temperature dependence of the coupling into a nonzero thermal coefficient , and write . The one-loop critical-mass subtraction gives
where
For , is finite, so the bracket tends to a finite constant and is self-consistent. At ,
and the growing logarithm obstructs an asymptotically constant linear coefficient at nonzero coupling. For , put to obtain
The divergent bracket then invalidates the assumed linear thermal mass. The radial critical-mass subtraction in dimensions three to five gives explicit checks of all three behaviors. For , the massless tadpole subtraction itself is infrared divergent; that failure of the Gaussian expansion does not prove absence of an interacting transition. Therefore the ordinary upper critical dimension is , with the unmodified Landau-Ginzburg theory asymptotically justified by this test only for . Exponents inferred by solving the self-consistent one-loop equation below four dimensions would not be exact interacting exponents.
For a tricritical point the renormalized quartic coefficient must be tuned to zero, and a positive sextic interaction stabilizes the order parameter. The gradient term gives the scalar field engineering dimension . A coefficient of therefore has dimension , which becomes marginal at . This gives . A direct Ginzburg criterion reaches the same result: long-wavelength variance in a correlation volume is
while the tricritical saddle has . Their ratio scales as , vanishing only above three dimensions. At three dimensions it is marginal; below three it grows. In contrast the ordinary saddle gives a ratio . Both calculations assume the thermal mass is measured relative to its shifted critical value. A sextic interaction generates quartic terms under coarse graining, so tricriticality requires tuning the renormalized quartic scaling field as well as the mass.
A tricritical point occurs when a first-order boundary meets a continuous-transition boundary. In the spin-inversion-symmetric sextic Landau free energy, two independent parameters must tune , while keeps the potential stable. In the plane, the continuous boundary is , and the first-order boundary is . They meet at the tricritical point; the order-parameter jump on the first-order side tends to zero as . The first panel shows this phase diagram, including the metastability limits derived above.
Along the tuned line , the equation of state is . Thus on a selected ordered branch, rather than the ordinary square-root behavior. Differentiation gives inverse magnetic susceptibility above and below, while at criticality . Hence the mean-field tricritical exponent calculation yields , , ; the minimized potential also gives . These tricritical powers require tuning the quartic coefficient, not merely varying a generic temperature path. The ordinary scalar exponents requested separately are calculated next.
Figure 1.
Scalar sextic Landau phase diagram with a tricritical point, and quartic metastable hysteresis branches
. Details.
Diagonalizing the linearized blocking map gives perturbations . A relevant operator has , equivalently for a discrete scaling multiplier: its perturbation grows under repeated coarse-graining and must be tuned to reach the critical fixed point. An irrelevant operator has and decays, usually contributing corrections to scaling. A marginal operator has , so linearization alone is insufficient; nonlinear flow can make it marginally relevant or irrelevant, or exactly marginal.
For an ordinary spin-inversion-symmetric critical point the temperature and magnetic field are relevant. Fixing by symmetry leaves the temperature to tune. At a tricritical point the quartic coupling is another relevant tuning direction. A dangerously irrelevant coupling is an exception to simply discarding small variables: setting it to zero can destabilize the ordered potential or make its scaling function singular, even though it flows toward zero.
Critical exponents describe leading singular powers as the reduced temperature or conjugate field approaches zero. With used for the order-parameter critical exponent to avoid confusion with inverse temperature, the definitions include
At criticality the connected correlation function behaves as . These definitions refer to the singular part and allow additional logarithms at marginal dimensions.
For an ordinary scalar Landau free energy, the equation of state is . Below the transition , giving . Differentiating the equation of state gives : it equals above and below the transition, so . The quadratic fluctuation kernel is in the symmetric phase, giving correlation length and . At zero mass the momentum-space correlation function is proportional to , so . The minimized free energy and critical equation of state give and , as calculated in the root solution.
At the tricritical point, and . Then , and is above and below the transition. The gradient kernel still gives and . Therefore
These are mean-field critical exponents. A systematic derivation incorporating fluctuations uses the renormalization group, extracts the relevant scaling eigenvalues, and differentiates the singular free-energy density, as in Question 3.
A tricritical point requires two independent even coefficients in the Landau free energy to vanish: , with providing stability. At , the ordinary critical line meets the tricritical three-phase line . The order parameter discontinuity along the first-order line is , which goes to zero at their meeting.
The positive sextic coefficient makes this a different leading local potential from an ordinary quartic critical point. Consequently its mean-field critical exponents, crossover behavior and upper critical dimension differ. There are two relevant even tuning directions near the tricritical point, in addition to the conjugate odd field. The root solution and labelled phase diagram display the three controls and the tricritical wings; varying can give a first-order reversal within the ordered coexistence sheet, a first-order weak/strong transition on a wing, or a continuous transition at a wing's ordinary critical edge.
A phase diagram partitions a space of thermodynamic controls into regions with distinct equilibrium phases. Its boundaries indicate phase coexistence or continuous phase transitions; a critical point is a termination of coexistence where the distinction between phases disappears. A concrete three-dimensional control space is for the Blume–Capel model: a spin can be or , the exchange favors aligned nonzero spins, and controls the energetic cost of nonzero spins. Varying changes the balance between a continuous ordering transition and a first-order phase transition. Their meeting is a tricritical point.
Locally, the same structure is displayed by the Landau free energy
with three controls . For , the line consists of ordinary critical points. For , equal free energies of and a nonzero stationary point require
Eliminating gives the tricritical three-phase line
Here and both signs of coexist, with a discontinuous order parameter. Below this line, or below when , the plane is an ordered phase coexistence sheet: crossing it reverses the sign of . Two tricritical wings also extend to nonzero , separating weakly and strongly magnetized states of the same sign. Their ordinary critical points satisfy . Since , their tricritical wing critical edges are
At these edges , giving an ordinary quartic critical expansion around . All these structures end at the tricritical point . The diagrams show both the zero-field section and the genuinely three-dimensional coexistence structure.
Figure 1.
Scalar Landau phase diagram: zero-field transitions, tricritical wings and ordinary critical edges
. Details.
For the final critical exponent calculation, take with , , and hold the other controls fixed. At an ordinary critical point, the quartic term dominates the sextic term. For and ,
whereas on the disordered side the singular contribution is zero. Two temperature derivatives give a finite jump in heat capacity, so . At , the equation of state is , so .
Along the tricritical trajectory , the nonzero minimum obeys and
Thus two temperature derivatives produce . At , . Therefore the mean-field critical exponents are
With the thermodynamic free energy, the physical sign is , rather than the positive sign printed in the paper. This correction affects the sign of the heat capacity, not its critical exponent. The tricritical result assumes that the independent quartic control is tuned to zero; a generic trajectory through nearby ordinary critical points need not have these exponents.
A tricritical point occurs when the continuous and first-order transition lines meet. In the symmetric sextic Landau free energy this requires tuning two coefficients, , while stabilizes the potential. For , the zero-field transition lies on and is continuous. For , the coexistence curve is . The order-parameter jump satisfies and shrinks to zero as the tricritical point is approached. The labelled phase diagram below uses as local coordinates; two independent physical controls, such as temperature and composition, can provide these coordinates.
Along the tricritical tuning , the equation of state is . At zero field the ordered solution is , and the critical isotherm has . The inverse magnetic susceptibility is above and below. The minimized singular potential is below, so differentiating twice thermally gives a singularity. These calculations give
The correlation-length and correlation-function exponents follow from the same quadratic gradient term. A generic path with a nonzero positive quartic coefficient instead has ordinary critical behaviour; observing tricritical powers requires the extra tuning. The sextic coupling is marginal in three dimensions, giving tricritical upper critical dimension three and logarithmic corrections there.
Figure 1.
Zero-field sextic Landau phase diagram with continuous and first-order boundaries meeting at the tricritical point, and dashed spinodal limits
. Details.
At a tricritical point, both and vanish, while stabilizes the Landau free energy. It separates ordinary continuous transitions for from first-order coexistence for . The zero-field order-parameter jump shrinks to zero as , and the tricritical wings terminate there in the full diagram. For , , minimizing gives and
Two thermal derivatives give the heat-capacity critical exponent , compared with the finite mean-field heat-capacity jump, , at an ordinary quartic transition. The remaining tricritical mean-field critical exponents are , and the mean-field correlation-length critical exponent is . To observe tricritical scaling one must tune the quartic scaling field as well as the thermal field: a generic path with fixed instead has ordinary critical behavior. Its upper critical dimension is three, as the multicritical Ginzburg ratio shows.