Topics (203k) Articles (205k) Users (298) Discussions (237) Comments (383) Files (715) New article
A lone pair refers to a pair of valence electrons that are not shared with another atom and remain localized on a single atom. These electrons are often found in the outermost shell of an atom and can influence the atom's chemical behavior, including bond angles and molecular geometry. Lone pairs are important in the formation of molecular shapes, as they can repel other electron pairs (both bonding and lone pairs) according to the principles of VSEPR (Valence Shell Electron Pair Repulsion) theory.
London dispersion forces, also known as dispersion forces or van der Waals forces, are a type of weak intermolecular force that arise from temporary fluctuations in the electron distribution within molecules or atoms. These fluctuations lead to the creation of temporary dipoles, which can induce dipoles in neighboring molecules, resulting in an attractive force between them.
Linnett double-quartet theory refers to a theoretical model in chemistry that describes the electronic structure of certain types of molecular systems, specifically focusing on the behavior of electrons in larger, complex molecules. While there is limited information available on this specific term, it generally relates to concepts in molecular orbital theory and may involve discussions of resonance, electron coupling, and the stability of certain arrangements of atoms in molecules.
Linkage isomerism is a type of isomerism found in coordination compounds. It arises when a ligand can coordinate to a metal center in more than one way, leading to different structural arrangements. In linkage isomerism, the position of the binding site of a ligand changes. For example, some ligands contain multiple donor atoms, where only one of those atoms binds to the metal ion at a time.
Ligand field theory (LFT) is a theoretical framework used in coordination chemistry to describe the electronic structure and properties of transition metal complexes. It builds upon and extends the concepts of crystal field theory (CFT), which focuses on the impact of surrounding ligands (molecules or ions that coordinate to a metal center) on the d-orbital energies of transition metals.
A ligand-dependent pathway refers to a signaling mechanism in which the binding of a specific ligand (usually a molecule such as a hormone, neurotransmitter, or other signaling substance) to its corresponding receptor triggers a cascade of biological responses within a cell. This pathway is characterized by the requirement for the ligand to bind to the receptor in order for the signaling event to occur.
The term "ligand bond number" isn't standard terminology in chemistry. However, it may relate to the coordination of ligands to a central metal atom in coordination chemistry. In this context, the term "bond number" might refer to the number of bonds that a ligand forms with a central metal atom or ion in a coordination complex.
A ligand binding assay is a laboratory technique used to study the interaction between a ligand (a molecule that binds to another molecule, typically a protein) and its target, often a receptor or enzyme. These assays are crucial in drug development and pharmacology as they help to understand the binding affinity, specificity, and kinetics of ligands, which can include small molecules, peptides, or antibodies.
In biochemistry, a ligand is a molecule that binds to a specific site on a target protein, which is often a receptor or an enzyme, to form a complex. This interaction can lead to various biological responses and plays a crucial role in many biochemical processes. Ligands can be diverse in nature and can include small molecules, ions, or larger biomolecules such as peptides, proteins, or nucleic acids.
A ligand is a molecule or ion that binds to a central metal atom to form a coordination complex. Ligands can be either simple ions, such as chloride (Cl⁻) or hydroxide (OH⁻), or larger molecules such as ammonia (NH₃) or ethylenediamine. They typically have one or more pairs of electrons that can be donated to the metal atom, forming coordinate covalent bonds.
A Lewis structure, also known as a Lewis dot structure, is a diagram that depicts the bonding between atoms in a molecule and the lone pairs of electrons that may exist. It was developed by the American chemist Gilbert N. Lewis in 1916. In a Lewis structure: 1. **Atoms** are represented by their chemical symbols (e.g., H for hydrogen, O for oxygen, C for carbon). 2. **Valence electrons** are represented as dots around the atomic symbols.
Lanthanide contraction refers to the phenomenon where the atomic and ionic radii of the lanthanide series elements (the 15 elements from lanthanum (La) to lutetium (Lu) in the periodic table) decrease progressively with increasing atomic number, despite the addition of electrons to the 4f subshell. This contraction is primarily caused by the ineffective shielding of the increasing nuclear charge by the 4f electrons.
The Keating Model, often referred to in educational contexts, is associated with the work of Dr. John Keating, a fictional character from the movie "Dead Poets Society" portrayed by Robin Williams. This character embodies a teaching philosophy that emphasizes the importance of individual thought, creativity, and the pursuit of passion in education.
Isovalent hybridization is a concept in chemistry that refers to the mixing of atomic orbitals of equal energy to form new hybrid orbitals that can participate in chemical bonding. The term "isovalent" indicates that the hybrid orbitals formed have similar energy levels and characteristics, which allows them to effectively engage in bonding with other atoms. In isovalent hybridization, the orbitals involved in the hybridization process typically belong to the same type or category (e.g.
An isopeptide bond is a type of covalent bond that forms between the carboxyl group of one amino acid and the amino group of another amino acid, specifically when the bond occurs between the side chain of one amino acid (usually one possessing a reactive group such as lysine or aspartic acid) and the backbone or side chain of another amino acid.
Ionic bonding is a type of chemical bond that occurs when atoms transfer electrons from one to another, resulting in the formation of charged particles known as ions. This transfer typically occurs between atoms of significantly different electronegativities, such as metals and non-metals.
Ioliomics is a term that refers to the study and analysis of the interactions and relationships between the various ionic species in biological systems. This field typically involves understanding how different ions, such as sodium, potassium, calcium, magnesium, and others, influence cellular processes, physiological functions, and overall health. The term "ioliomics" can also encompass the study of ionic changes in response to environmental factors, disease states, or therapeutic interventions.
Inverted ligand field theory (ILFT) is a theoretical framework used to understand the electronic structure and behavior of transition metal complexes, particularly in the context of their crystal field environments. It is a modification of traditional ligand field theory (LFT), which focuses on the effects of the surrounding ligands on the energy levels of metal d-orbitals.
Intramolecular forces are the forces that hold the atoms within a molecule together. These forces are essential for the stability and integrity of molecules and are responsible for the chemical properties of substances. There are three primary types of intramolecular forces: 1. **Covalent Bonds**: These occur when atoms share pairs of electrons. For example, in a water molecule (H₂O), the hydrogen and oxygen atoms are held together by covalent bonds.
An intimate ion pair refers to a specific type of ion pair formed in solution, particularly in polar solvents like water. It is characterized by the close association of a cation and an anion that are not fully separated by solvent molecules. In this context, "intimate" indicates that the ions are in close proximity, potentially influencing each other’s properties and reactivity.
Pinned article: Introduction to the OurBigBook Project
Welcome to the OurBigBook Project! Our goal is to create the perfect publishing platform for STEM subjects, and get university-level students to write the best free STEM tutorials ever.
Everyone is welcome to create an account and play with the site: ourbigbook.com/go/register. We belive that students themselves can write amazing tutorials, but teachers are welcome too. You can write about anything you want, it doesn't have to be STEM or even educational. Silly test content is very welcome and you won't be penalized in any way. Just keep it legal!
Intro to OurBigBook
. Source. We have two killer features:
- topics: topics group articles by different users with the same title, e.g. here is the topic for the "Fundamental Theorem of Calculus" ourbigbook.com/go/topic/fundamental-theorem-of-calculusArticles of different users are sorted by upvote within each article page. This feature is a bit like:
- a Wikipedia where each user can have their own version of each article
- a Q&A website like Stack Overflow, where multiple people can give their views on a given topic, and the best ones are sorted by upvote. Except you don't need to wait for someone to ask first, and any topic goes, no matter how narrow or broad
This feature makes it possible for readers to find better explanations of any topic created by other writers. And it allows writers to create an explanation in a place that readers might actually find it.Figure 1. Screenshot of the "Derivative" topic page. View it live at: ourbigbook.com/go/topic/derivativeVideo 2. OurBigBook Web topics demo. Source. - local editing: you can store all your personal knowledge base content locally in a plaintext markup format that can be edited locally and published either:This way you can be sure that even if OurBigBook.com were to go down one day (which we have no plans to do as it is quite cheap to host!), your content will still be perfectly readable as a static site.
- to OurBigBook.com to get awesome multi-user features like topics and likes
- as HTML files to a static website, which you can host yourself for free on many external providers like GitHub Pages, and remain in full control
Figure 2. You can publish local OurBigBook lightweight markup files to either OurBigBook.com or as a static website.Figure 3. Visual Studio Code extension installation.Figure 5. . You can also edit articles on the Web editor without installing anything locally. Video 3. Edit locally and publish demo. Source. This shows editing OurBigBook Markup and publishing it using the Visual Studio Code extension. - Infinitely deep tables of contents:
All our software is open source and hosted at: github.com/ourbigbook/ourbigbook
Further documentation can be found at: docs.ourbigbook.com
Feel free to reach our to us for any help or suggestions: docs.ourbigbook.com/#contact





