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The baryon asymmetry is an excess of baryons over antibaryons. Here $n_B-n_{\bar{B}}$ counts net baryon number per unit volume, including the baryons bound in atomic nuclei. It is dynamically generated by baryogenesis. Once the antibaryon abundance is negligible, its photon-normalized value agrees with the usual baryon-to-photon ratio.

Starting from a matter-antimatter symmetric ensemble, exact charge conjugation would pair every baryon-producing process with an equally probable antibaryon-producing process. Their contributions to the net baryon number cancel. Thus C violation is necessary. Violating charge conjugation alone is insufficient: if CP symmetry is exact, the parity-reflected conjugate channels still have equal probabilities and cancel in a CP symmetry invariant ensemble. One needs CP violation as well.

The remaining Sakharov conditions are baryon number violation and departure from thermal equilibrium. Conserving baryon number cannot turn an initially zero value into a nonzero one. In thermal equilibrium, under the usual CPT theorem hypotheses and with no imposed chemical potentials for charges odd under CPT symmetry, states and their conjugates have equal thermal weights, so the equilibrium expectation of net baryon number vanishes and thermal stationarity prevents its sustained production. A nonequilibrium history allows different forward and reverse populations to generate an asymmetry. These are the standard necessary conditions for dynamical baryogenesis from symmetric initial conditions, not a guarantee of a sufficiently large asymmetry.

The classical baryon current is anomalous under $SU(2{)}_L$:An electroweak instanton or electroweak sphaleron changes the topological charge and producesfor three generations. At zero temperature, instanton-induced baryon violation is exponentially tiny and irrelevant to proton decay. Above the electroweak scale, thermal sphaleron transitions are rapid; they can erase a pre-existing $B+L$ asymmetry or convert a $B-L$ asymmetry into the observed baryon asymmetry, making the anomaly central to baryogenesis.

The standard conditions for baryogenesis from a symmetric initial ensemble are baryon number violation, both C violation and CP violation, and departure from thermal equilibrium. Conserved baryon number cannot develop a net value from zero; an exact conjugation symmetry pairs production with equal antiproduction. In thermal equilibrium, CPT symmetry makes the equilibrium expectation of net baryon number vanish for zero imposed chemical potentials for charges odd under CPT symmetry. These conditions assume the usual local quantum-field framework and do not alone guarantee a large asymmetry.